Using Mesoproterozoic sedimentary geochemistry to reconstruct basin tectonic geography and link organic carbon productivity to nutrient flux from a Northern Australian large igneous Province

The Beetaloo Sub-basin, northern Australia, is considered the main depocentre of the 1,000-km scale Mesoproterozoic Wilton package of the greater McArthur Basin – the host to one of the oldest hydrocarbon global resources. The ca. 1.40–1.31 Ga upper Roper Group and the latest Mesoproterozoic to early Neoproterozoic unnamed group of the Beetaloo Sub-basin, together, record ca. 500 million years of depositional history within the North Australia Craton. Whole-rock shale Sm–Nd and Pb isotope data from these sediments reveal sedimentary provenance and their evolution from ca. 1.35 to 0.85 Ga. Furthermore, these data, together with shale major/trace elements data from this study and pyrolysis data from previous publications, are used to develop a dynamic tectonic geography model that links the organic carbon production and burial to an enhanced weathering of nutrients from a large igneous province. The ca. 1.35–1.31 Ga Kyalla Formation of the upper Roper Group is composed of isotopically evolved sedimentary detritus that passes up, into more isotopically juvenile Pb values towards the top of the formation. The increase in juvenile compositions coincides with elevated total organic carbon (TOC) contents of these sediments. The coherently enriched juvenile compositions and TOC the upper portions of the Kyalla Formation are interpreted to reflect an increase in nutrient supply associated with the weathering of basaltic sources (e.g. phosphorous). Possible, relatively juvenile, basaltic sources include the Wankanki Supersuite in the western Musgraves and the Derim Derim–Galiwinku large igneous province (LIP). The transition into juvenile, basaltic sources directly before a supersequence-bounding unconformity is here interpreted to reflect uplift and erosion of the Derim Derim–Galiwinku LIP, rather than an influx of southern Musgrave sources. A new baddeleyite crystallisation age of 1,312.9 ± 0.7 Ma provides both a tight constraint on the age of this LIP, along with its associated magmatic uplift, as well as providing a minimum age constraint for Roper Group deposition. The unconformably overlying lower and upper Jamison sandstones are at least 300 million years younger than the Kyalla Formation and were sourced from the Musgrave Province. An up-section increase in isotopically juvenile compositions seen in these rocks is interpreted to document the progressive exhumation of the western Musgrave Province. The overlying Hayfield mudstone received detritus from both the Musgrave and Arunta regions, and its isotopic geochemistry reveals affinities with other early Neoproterozoic basins (e.g. Amadeus, Victoria and Officer basins), indicating the potential for inter-basin correlations.     

两种造礁石珊瑚对海水酸化和溶解有机碳加富的响应*

文章选择鹿回头近岸海域常见的板叶角蜂巢珊瑚(Favites complanata)和十字牡丹珊瑚(Pavona decussata)为研究对象, 采用室内连续培养的方法, 探究两种不同造礁石珊瑚对酸化和溶解有机碳(DOC)加富的响应。结果表明: 酸化(pH 7.6)并不会影响两种珊瑚的钙化速率和生长速率; 但DOC加富(524.03±78.42μmol•L^-1)使两种珊瑚的钙化速率分别降低67%和47%、生长速率降低59%和40%。当二者共同作用时, 两种珊瑚的钙化速率降低30%和11%、生长速率降低46%和59%, 大多没有DOC单独作用时强烈, 表现出一定的拮抗作用。两种珊瑚共生虫黄藻叶绿素荧光指数(F_v/F_m)均升高后降低, 板叶角蜂巢珊瑚F_v/F_m最先降低。实验表明, 这两种珊瑚虽然对海洋酸化的敏感度不高, 但是对有机物加富有不同的响应, 板叶角蜂巢珊瑚更为敏感, 可能导致这两种珊瑚在未来环境变化中有不同命运。     

氧化钒晶体的半导体至金属相变的理论研究

本文利用第一性原理方法研究了金红石相和单斜相VO₂晶体的电子结构和热力学性质.在计算中采用局域密度近似结合Hubbard U模型(LDA+U)描述电子的局域强关联效应,同时也利用微扰密度泛函方法计算了两种相结构的声子谱.计算结果表明V原子3d电子轨道中x²-y²轨道能级分裂决定了VO₂晶体在不同相结构下的金属和绝缘体特性.零温状态方程计算揭示了在68 GPa时可以发生从单斜结构     

Analysis of the spatial variation of heavy metals in the Guadiana Estuary sediments (SW Iberian Peninsula) based on GIS-mapping techniques

This work reveals the usefulness of the GIS (Geographic Information Systems) mapping techniques to show the distribution of pollutants along an estuarine environment, as the final stage of a thorough study. In the case of study, the environmental quality of the sediments in the Guadiana river estuary was determined by means of a complete geochemical characterization consisting on the calculation of enrichment factors for the most important metals and metalloids (compared with the local background of non-contaminated sediments). The obtained results were depicted in “enrichment distribution maps” which evidenced a distribution of the elements in two groups: Group-I, elements with natural origin (Al, Fe, Mn, Co, and Cr) distributed homogeneously along the basin, and Group-II, elements associated to anthropic origin (As, Cd, Cu, Pb, Ni and Zn) with clear punctual sources besides a high concentration all over the estuary. The enrichment factors for the elements of Group-II are indicative of the existence of a noticeable diffuse historical mining pollution associated with the acid mine drainage generated in the internal zones of the basin, which could overlap minor pollution inputs from other human activities. The obtained results lead us to a reconsideration of the traditionally thought “unpolluted” environment when it was compared to nearby estuaries.     

徐闻南山镇红树林沉积物及红树植物中重金属的累积特征与迁移规律

为探究重金属在红树林沉积物及红树植物中的分布累积及迁移规律,选取了徐闻南山镇红树林为研究对象,通过测定红树林沉积物及红树植物不同部位（根、茎、叶）的重金属质量分数,运用富集因子、生物富集系数、转移系数及相关性分析等方法进行分析。结果表明：1）红树林沉积物重金属质量分数表现为铬（Cr）＞锌（Zn）＞镍（Ni）＞铜（Cu）＞铅（Pb）＞砷（As）＞汞（Hg）＞镉（Cd）,为中等变异程度;除了镍（Ni）元素外,其余7种重金属未超过国家一级标准,除了铅（Pb）元素外,其余7种重金属均超过广东省土壤环境背景值,说明研究区沉积物中重金属具有一定的积累效应。2）沉积物中砷（As）、铜（Cu）、锌（Zn）、汞（Hg）、镍（Ni）、铬（Cr）富集因子值均＞1.5,说明受到轻微人为活动影响;各站位镍（Ni）富集因子值均＞5,结合研究区背景,反映了镍（Ni）受到自然和人为输入的共同影响。3）白骨壤体内重金属主要集中在根部,而红海榄体内重金属在根茎叶中分布相对均匀。白骨壤根茎叶部位的大多数重金属质量分数远高于红海榄,说明白骨壤对重金属的吸附能力比红海榄强。汞（Hg）集中分布在植物的叶片部位,且与其他重金属之间相关性不明显;推测汞（Hg）主要通过叶片吸收进入植物体内,与交通运输污染有关。4）不同红树植物对不同重金属富集能力各异,白骨壤对重金属的富集能力表现为：镉（Cd）＞砷（As）＞铜（Cu）＞锌（Zn）＞汞（Hg）＞铅（Pb）＞镍（Ni）＞铬（Cr）,红海榄表现为：镉（Cd）＞铜（Cu）＞汞（Hg）＞锌（Zn）＞铅（Pb）＞砷（As）＞镍（Ni）＞铬（Cr）。白骨壤和红海榄对汞（Hg）的运移能力都较强;红海榄对镉（Cd）的富集能力和转运能力都较强,而白骨壤对镉（Cd）富集能力较强,转运能力却较弱,这说明红树植物对重金属元素的富集能力与转运能力不存在正比关系。     

曲线拟合法在山东流动重力资料处理中的应用

利用曲线拟合法对山东流动重力部分具有趋势性变化的异常测点进行了拟合改正,获取更可靠的重力变化信息,并对趋势性变化显著的测点进行了分析和讨论。     

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半参数估计与LS估计的有效性比较

建立半参数回归模型,将系统误差加入,推导出了模型正则化矩阵时参数平差的计算方法,并用直接法得到了参数、非参数的估计量,在MSE准则下与最小二乘估值(简称LS估值)进行比较,证明了半参数估值的有效性。     

基于主成分分析的ENVISAT ASAR数据在福建省漳州市香蕉园地提取中的应用(英文)

Banana is one of the main economic agrotypes in Zhangzhou, Fujian Province. The multi-temporal ENVISAT ASAR data with different polarization are used to classify the banana fields in this paper. Principal component analysis (PCA) was applied for six pairs of ASAR dual-polarization data. For its large leaves, banana has high backscatter. So the value of banana fields is high and shows very bright in the 1st component, which makes it much easier for banana fields extraction. Dual-polarization data provide more information, and the VV and VH backscatter of banana show different characters with other land covers. Based on the analysis of the radar signature of banana fields and other land covers and the 1st component, banana fields are classified using object-oriented classifier. Compared to the field survey data and ASTER data, the accuracy of banana fields in the study area is 83.5%. It shows that the principal component analysis provides the useful information in SAR images analysis and makes the extraction of banana fields easier. Supported by the Program for New Century Excellent Talents in University (NCET-05-0573), Fujian Science and Technology Project (No.2006I0018), the Science Project of the Education Department of Fujian Province(No. 2006F5022).     

公用机房的硬盘保护措施

在深入分析硬盘结构及硬盘工作原理的基础上,详细阐述了用软件实现对公用机房硬盘的保护原理和方法,并给出了编程思路。