A New Formation Mechanism of Coesite without the Plate Deeply-Subduction and Fast-Exhumation——Comment on the Article “Discussion on Some Problems of Quartz-Coesite Phase Transition”

本文分析评论了嵇少丞等(2010)发表的“石英—柯石英相变研究中若干问题讨论”一文.指出他们对柯石英非俯冲折返新机制的一些误解,对某些热力学、物理学概念,及其在地学问题中的解释理解的不同.分析了机械球磨的作用机制;论证了机械球磨作用本质与构造挤压剪切作用本质的同一性.分析了岩石糜棱岩化过程的两个阶段;讨论了地震波形成柯石英机制的可能性.围绕比较标准问题,论证了高能机械球磨(预处理)能大大降低α-石英转变成柯石英的压力、温度和合成时间,促进柯石英的形成.用小尺度不均匀局域高压微区模型解释了人工合成柯石英的规律性、南极洲天然矿物的行为,柯石英的寄生矿物、岩石——锆石、榴辉岩包裹体、非包裹体的形成.列举事例澄清了“球磨引进的Fe杂质提高柯石英形成压力迟缓合成”的说法;讨论了第二相存在对石英—柯石英转变的影响和“应变禁区”边界区的应力梯度相变驱动力可以形成柯石英问题.指出了机械球磨石英原料预处理和静高压合成柯石英后处理两步法,是一种实验室研究柯石英形成规律的有效物理方法;小尺度不均匀局域高压微区模型和无需板块深俯冲快折返的柯石英形成机制,是一种有希望的柯石英形成新机制.     

利用蒙特卡罗方法的剩余静校正及其应用

针对剩余静校正问题,讨论了统计方法中的蒙特卡罗法用于反射波能量最大化剩余静校正的方法。分别论述了反射波叠加能量最大化法和蒙特卡罗方法,以及蒙特卡罗方法如何应用于剩余静校正的计算中,并用实例说明了该方法的效果。通过实际应用蒙特卡罗剩余静校正方法,解决了经野外静校正后残留的剩余静校正问题,并通过与其他剩余静校正方法的实际应用对比,说明了蒙特卡罗剩余静校正方法的优势。对于大剩余量的静校正问题,蒙特卡罗剩余静校正方法仍然可以很好的解决,并且不会产生串相位问题,说明蒙特卡罗剩余静校正方法是可靠的。     

赣东北金矿矿源岩的区域岩石密度特征及找矿方向

对研究区内金矿岩双桥山群的4336件岩石密度数据的统计分布、空间制图分析。得到岩石密度参数的地质制图，发现双桥山群岩石密度为偏态分布，推测岩石密度的增高可能是变质作用或成矿作用增强的反映，区内主要岩金矿床均分布在密度高异常区内，因此认为高密度异常区或重力正异常区，是区内岩金矿床的找矿远景区。     

全球地球化学填图

作指出了1973年至今世界上50余项地球化学填图计划中普遍存在的缺陷大都涉及分析问题。1988－1992年实施的国际地质对比计划IGCP259项目旨在使全世界地球化学填图方法标准化。在此项目中对分析问题提出了若干规定，主要是要求今后的填图计划应统一分析71种元素，痕量及超痕量元素的检出限必须低于相应的地壳丰度值及采用中国的GSD和加拿大的STSD标样系列，以使全球数据可以对比，在其后开始延续至今的全球地球化学填图计划IGCP360，旨在用极低密度采样早日覆盖全球大陆，讨论了正在实行的两种极低密度采样方案，并提出通过极低密度采集地极少量样品示范性实现IGCP259项目对分析要求的具体建议。     

Global Correlations of Ocean Ridge Basalt Chemistry with Axial Depth: a New Perspective

The petrological parameters Na₈ and Fe₈, which are Na₂O andFeO contents in mid-ocean ridge basalt (MORB) melts correctedfor fractionation effects to MgO = 8 wt%, have been widely usedas indicators of the extent and pressure of mantle melting beneathocean ridges. We find that these parameters are unreliable.Fe₈ is used to compute the mantle solidus depth (P_o) and temperature(T_o), and it is the values and range of Fe₈ that have led tothe notion that mantle potential temperature variation of T_P= 250 K is required to explain the global ocean ridge systematics.This interpreted T_P = 250 K range applies to ocean ridges awayfrom ‘hotspots’. We find no convincing evidencethat calculated values for P_o, T_o, and T_P using Fe₈ have anysignificance. We correct for fractionation effect to Mg^# = 0·72,which reveals mostly signals of mantle processes because meltswith Mg^# = 0·72 are in equilibrium with mantle olivineof Fo_89·6 (vs evolved olivine of Fo_{88·1–79·6}in equilibrium with melts of Fe₈). To reveal first-order MORBchemical systematics as a function of ridge axial depth, weaverage out possible effects of spreading rate variation, local-scalemantle source heterogeneity, melting region geometry variation,and dynamic topography on regional and segment scales by usingactual sample depths, regardless of geographical location, withineach of 22 ridge depth intervals of 250 m on a global scale.These depth-interval averages give Fe₇₂ = 7·5–8·5,which would give T_P = 41 K (vs 250 K based on Fe₈) beneathglobal ocean ridges. The lack of Fe₇₂–Si₇₂ and Si₇₂–ridgedepth correlations provides no evidence that MORB melts preservepressure signatures as a function of ridge axial depth. We thusfind no convincing evidence for T_P > 50 K beneath globalocean ridges. The averages have also revealed significantcorrelations of MORB chemistry (e.g. Ti₇₂, Al₇₂, Fe₇₂,Mg₇₂, Ca₇₂, Na₇₂ and Ca₇₂/Al₇₂) with ridge axial depth. Thechemistry–depth correlation points to an intrinsic linkbetween the two. That is, the 5 km global ridge axial reliefand MORB chemistry both result from a common cause: subsolidusmantle compositional variation (vs T_P), which determines themineralogy, lithology and density variations that (1) isostaticallycompensate the 5 km ocean ridge relief and (2) determine thefirst-order MORB compositional variation on a global scale.A progressively more enriched (or less depleted) fertileperidotite source (i.e. high Al₂O₃ and Na₂O, and low CaO/Al₂O₃)beneath deep ridges ensures a greater amount of modal garnet(high Al₂O₃) and higher jadeite/diopside ratios in clinopyroxene(high Na₂O and Al₂O₃, and lower CaO), making a denser mantle,and thus deeper ridges. The dense fertile mantle beneath deepridges retards the rate and restricts the amplitude of the upwelling,reduces the rate and extent of decompression melting, givesway to conductive cooling to a deep level, forces melting tostop at such a deep level, leads to a short melting column,and thus produces less melt and probably a thin magmatic crustrelative to the less dense (more refractory) fertile mantlebeneath shallow ridges. Compositions of primitive MORB meltsresult from the combination of two different, but geneticallyrelated processes: (1) mantle source inheritance and (2) meltingprocess enhancement. The subsolidus mantle compositional variationneeded to explain MORB chemistry and ridge axial depth variationrequires a deep isostatic compensation depth, probably in thetransition zone. Therefore, although ocean ridges are of shalloworigin, their working is largely controlled by deep processesas well as the effect of plate spreading rate variation at shallowlevels. KEY WORDS: mid-ocean ridges; mantle melting; magma differentiation; petrogenesis; MORB chemistry variation; ridge depth variation; global correlations; mantle compositional variation; mantle source density variation; mantle potential temperature variation; isostatic compensation     

阿曼Daleel油田下白垩统Shuaiba组上段走滑正断裂带裂缝分布定量评价

在对阿曼Daleel油田下白垩统Shuaiba组上段的岩芯及成像测井裂缝特征进行分析的基础上,利用过断层的水平井成像测井资料,开展对断层两侧的裂缝发育情况研究,分析认为裂缝发育密度与离断层的距离相关,提出裂缝成因主要受区内走滑正断层所控制.研究建立的3类不同规模的走滑正断层带裂缝密度分布函数,实现了对阿曼Daleel油田下白垩统Shuaiba组上段断裂带裂缝分布的定量评价.     

CO_2 Density-Raman Shift Relation Derived from Synthetic Inclusions in Fused Silica Capillaries and Its Application

Abstract: The densities of CO2 inclusions in minerals are commonly used to determine the crystallizing conditions of the host minerals. However, conventional microthermometry is difficult to apply for inclusions of small size (< 5–10 μm) or low density. Raman analysis is an alternative method for determining CO2 density, provided that the CO2 density–Raman shift relation is known. This study aims to establish this CO2 density–Raman shift relation by using CO2 inclusions synthesized in fused silica capillaries. By using this newly-developed synthetic technique, we formed pure CO2 inclusions, and their densities were determined by microthermometry. The Raman analysis showed that the relation between CO2 density (D in g/cm3) and the separations (Δ in cm?1) between the two main bands (i.e. Fermi diad bands) in CO2 Raman spectra can be represented by a cubic equation: D (g/cm3)=0.74203(?0.019Δ3+5.90332Δ2?610.79472Δ+21050.30165)?3.54278 (r2=0.99920). Our calculated D value for a given Δ is between those obtained from two previously-reported equations, which were derived from different experimental methods. An example was given in this study to demonstrate that the densities of natural CO2 inclusions that could not be derived from microthermometry could be determined by using our method.     

Cathodoluminescence of authigenic albite

Authigenic albites in carbonate rocks typically grow in a high-grade diagenetic to low-grade metamorphic environment and often show Roc-Tourné-twinning sensu Füchtbauer. Based on an investigation of four Middle to South European occurrences, they show Mn²⁺- and Fe³⁺-activated cathodoluminescence (CL), as revealed by combined high resolution spectroscopy of cathodoluminescence emission (HRS-CL), electron paramagnetic resonance (EPR), and proton-induced X-ray emission (μPIXE).     

淮河息县站流量概率预报模型研究

应用美国天气局采用的由Roman Krzysztofowicz开发的贝叶斯统计理论建立概率水文预报理论框架，即以分布函数形式定量地描述水文预报不确定度，研究了淮河息县站流量概率预报模型。理论和经验表明，概率预报至少与确定性预报一样有价值，特别当预报不确定度较大时，概率预报比现行确定性预报具有更高的经济价值。     

煤炭地下气化区高密度三维地震勘探技术研究

地下煤层气化的燃烧范围,气化燃烧热力影响边界、形态、方向,气化区冒落带的发展高度及气化煤层裂隙发育程度,是开展煤炭地下气化工程迫切需要解决的问题。基于煤炭地下气化工程试验区地震地质情况,从地震响应入手,在分析煤炭地下气化后地震波场响应特征的基础上,提出了运用高密度三维地震采集技术结合全三维地震属性解释技术,高精度识别煤炭地下气化燃烧范围、气化热力影响边界的方法。实际勘探成果表明,本方法地震成像清晰,预测精度高,与钻探结果吻合较好。