微波消解等离子体发射光谱和石墨炉原子吸收光谱法联合测定土壤中多元素

采用密闭式微波消解系统处理土壤样品,电感耦合等离子体发射光谱法或石墨炉原子吸收光谱法测定土壤样品中铜、砷、铅、锌、钴、铬、锰、镍、钒9个元素。分别从消解液的选择、用酸量及样品消解量等方面进行消解条件的优化,确定了一个最适合土壤消解的前处理体系。各元素的检出限为0.16～2.52μg/g,回收率为95.2%～106.6%,精密度为2.03%～9.79%(n=7)。方法简单快速,效率高,劳动强度低,是进行土壤中多元素测定的高效方法。     

Sources of pollution and distribution of Pb,Cd and Hg in Wrocław soils: Insight from chemical and Pb isotope composition

Human activities in cities affect properties of urban soils. In particular, urban soils often contain high contents of harmful metals even in deeper horizons added to them from diverse sources over centuries of the city development. This is reflected in complex distribution of metals in bulk soils with depth and the complex metal fractionation, but the exact sources of the metals are difficult to identify. This is also the situation in soils from Wroclaw, one of the largest cities in Poland. Potentially harmful elements Pb, Cd and Hg were examined in six profiles located along the major communication route and compared to two non-urban soils profiles located close to the same route. In all of the urban profiles, Pb and Cd exceeded the element contents observed in non-urban profiles and showed an erratic distribution compared to the more predictable one in non-urban soils. The differences between urban and non-urban profiles were explained as the result of contamination coming from more pollution sources in the case of urban soils, the conclusion supported by Pb isotope analyses. In fact, Pb isotopes showed that the contamination sources in urban soils included leaded petrol, coal combustion, smelting and possibly old pre-industrial ore processing, whereas leaded petrol and pre-industrial lead were the only possible anthropogenic sources in non-urban soils. The comparison of Wrocöaw soils with those from cities of comparable size Kraków and Poznań show similar ranges of metal contents with implication that urban pollution oversteps diverse geogenic chemical background. On the other hand, the comparison with other European cities show large variability in metal contents and suggest that urban soils contamination is time integrated and reflects long-term industrial evolution of each country.     

同步辐射软X射线吸收谱与发射谱测定天然针铁矿能带结构

天然半导体矿物由于成分、缺陷复杂,传统测试方法如紫外可见漫反射等难以准确测定其禁带宽度.本文以针铁矿为例,通过第一性原理计算得到纯针铁矿及掺Al针铁矿的电子结构.计算结果显示,纯针铁矿导带底与价带顶均由Fe3d与O2p轨道组成,而当含杂质Al时,Al2p与O2p发生杂化参与了价带组成.在此基础上,利用同步辐射X射线氧的K边吸收谱与发射谱对纯针铁矿及天然针铁矿的能带结构进行了测定.结果表明,天然含Al的针铁矿禁带宽度为2.30eV,小于纯针铁矿(2.57eV).本研究提供了一种测定天然氧化物矿物禁带宽度的新方法,为深入研究天然半导体可见光催化活性产生机制提供了理论依据.     

青藏高原南部及邻区深部碳释放规模与成因

不同构造背景下的深部碳释放通量与机制研究对于深刻理解长时间尺度的气候变化具有重要意义,以往的相关研究多集中在洋中脊、大洋俯冲带和大陆裂谷等地质单元,缺少对大陆碰撞带深部碳释放规模与机理的关注,从而制约了对大陆碰撞带深部碳循环过程及其气候环境效应的进一步认识。青藏高原起源于印度和欧亚大陆的碰撞,是研究大陆碰撞带深部碳循环的理想地区。为此,在近年来青藏高原温室气体释放野外观测与研究的基础上,本文估算了高原南部及邻区火山-地热区的CO₂释放规模并探讨了其释放模式。气体He-C同位素地球化学与温泉水热活动特征等显示,青藏高原南部及邻区的深部碳释放主要受深部岩浆房、断裂和浅部水热系统等因素的控制。依据深部流体源区和上升运移控制因素的差异,可以将青藏高原南部及邻区的深部碳释放划分为三大类:(1)以壳内水热系统脱碳为主的藏南地区;(2)深大断裂控制的以水热系统脱碳为主的川西地区;(3)深部岩浆房和浅部水热系统共同控制的滇西南地区。青藏高原南部土壤微渗漏CO₂释放通量介于18.7~52.3Mt/yr之间,温泉溶解无机碳释放通量约为0.13Mt/yr;高原邻区的川西、滇东南断裂带温泉CO₂释放规模为0.1Mt/yr;腾冲火山区CO₂释放通量介于4.5~7.1Mt/yr之间。本研究认为,青藏高原南部及邻区每年向大气圈释放CO₂的规模为23.4~59.6Mt,这一规模与全球其他构造背景(如洋中脊、大洋俯冲带、大陆裂谷等)火山区深部碳释放规模相当,表明以青藏高原为代表的大陆碰撞带是地质源CO₂释放的重要场所。     

基于能量理论的煤岩体破坏电磁辐射规律研究

为了给电磁辐射预测矿井冲击地压灾害提供理论依据,采用电磁波和损伤力学理论初步分析了电磁辐射能和加载机械能的关系;采用试验和能量理论研究了单轴压缩条件下煤体变形破坏产生电磁辐射能与受载煤体能量积聚、耗散的耦合关系。研究结果表明：加载机械能与煤体变形破坏产生的电磁辐射能成系数为m正线性关系,m与煤体的弹性模量成0.107 4的比例关系;受载煤体峰值弹性应变能与电磁辐射能成正对数关系,煤体的弹性能指数与峰值累积电磁辐射能、总累积电磁辐射能均成正线性关系,电磁辐射信号反映了能量聚集和耗散的状态,表征了煤体冲击破坏的难易程度。因此,电磁辐射能够预测矿井冲击地压灾害的发生。     

煤田火区碳排放量计算模型和关键参数研究

完善碳排放清单,是进行减排工作的基础,为了查明煤田火区对大气碳排放的贡献量,以煤氧复合作用学说为理论基础,从不同的研究思路出发,提出了烧失煤量法和排放通量法两种火区碳排放量计算模型。在明确模型中关键参数“释放因子”“排放系数α”“排放通量”“排放系数β”的具体含义的基础上,重点对各参数所对应的获取途径进行了研究论述：(1)释放因子通过在室内进行煤自燃模拟实验得出;(2)排放系数α通过煤岩吸附实验结合火区实地勘测得出;(3)排放通量通过对火区现场煤自燃气体排放及环境因素的实时监测得出;(4)排放系数β通过对遥感图像裂隙信息的提取得到。上述两种计算模型在我国乌达实验区进行了实际应用,并对其可实现性进行了检验。     

北极斯瓦尔巴特群岛及邻区天然气水合物分解对气候、海洋环境和生物的影响

天然气水合物是一种潜在的巨量能源,但其分解释放的甲烷可能对全球气候与海洋环境产生巨大影响。然而,人们目前对天然气水合物分解产生的环境和生物效应的了解还不够全面。北极地区的斯瓦尔巴特群岛及邻区的海底和冻土层中蕴含大量甲烷,对气候变化十分敏感,是人们研究天然气水合物对气候变化的响应机制和其分解对生态环境影响的绝佳场所。系统总结了斯瓦尔巴特群岛及邻区水合物分解的气候与环境效应,发现目前研究区水合物分解产生的甲烷进入大气的年际通量不大,对全球气候的影响可能有限;水合物分解对海底滑坡起到催化剂的作用,但不是首要因素;海底水合物分解释放的甲烷能打破原有的化学平衡、生产力分布规律与输送机制、生物耦合关系甚至不同栖息地间的连通性,进而影响底栖生物群落。这些认识对研究天然气水合物开采对生态环境可能造成的影响和采取相应防治措施具有一定的借鉴意义。     

局部重磁场源全方位成像理论概要(续)

作者近年来首创了"复杂条件下局部重磁场源全方位成像"理论体系。在本文中,概要阐述该理论体系中下延有限二度体复重磁场级数正演通式、复场模值全方位延拓和全方位反演等。     

Effects of calculation procedure and sampling site on trap method estimates of sediment resuspension in a shallow lake

Resuspension estimates given by two different trap methods in a shallow lake were compared. The sensitivity of the methods to errors in estimates of gross sedimentation and organic fraction of trapped material was explored. The methods were label method, in which resuspension is estimated by determining the organic fraction of surface sediment, suspended seston and trapped material, and SPIM/SPM method, where the relationship between settling particulate inorganic matter (SPIM) and total settling particulate matter (SPM) is used. During the whole 111 day study period, according to the label method, at a sheltered station 1949 g m⁻² dry weight of sediment was resuspended, whereas SPIM/SPM gave an estimate of 1815 g m⁻². The difference in the estimates was probably due to mineralization loss of organic material in the traps during the two week exposure periods. Sensitivity analysis showed that of the two methods, the label method was more sensitive to variations in the organic content of trapped material. At a wind-exposed station, the total amounts of resuspended matter given by the label method and by the SPIM/SPM method were 4966 g m⁻² and 4971 g m⁻², respectively. Due to wind effects, escape of trapped material took place, which caused underestimation of gross sedimentation and compensated the effects of mineralization loss to diminish the difference between the methods. Of the two methods, the SPIM/SPM method seems thus more suitable for lakes, where bacterial activity is high. If cyanobacterial blooms take place, the label method is probably more reliable, providing that the exposure time of sediment traps is kept adequately short.