氯化钡法在盐湖高锂卤水中高效分离硫酸根的研究

在生产碳酸锂的工艺中,尤其除硫过程中,锂会伴随其它盐类析出,造成锂的大量夹带损失.因此盐湖高锂卤水中硫酸根的脱除对锂的高效富集,提高锂的收率有重大意义.研究以盐湖高锂卤水为原料,通过加入氯化钡,采用化学沉淀法除去卤水中的SO2-4.详细考察了原料配比(SO2-4与Ba2+的摩尔比)、加料方式、加料时间、反应时间、搅拌速...     

Facies character and geochemical signature in the late Quaternary meteoric diagenetic carbonate succession at the Xisha Islands,South China Sea

The late Quaternary shallow-water carbonates have been altered by a variety of diagenetic processes, and further influenced by high-amplitude global and regional sea level changes. This study utilizes a new borehole drilled on the Yongxing Island, Xisha Islands to investigate meteoric diagenetic alteration in the late Quaternary shallowwater carbonates. Petrographic, mineralogical, stable isotopic and elemental data provide new insights into the meteoric diagenetic processes of the reef limestone. The results show the variation in the distribution of aragonite,high-Mg calcite(HMC) and low-Mg calcite(LMC) divides the shallow-water carbonates in Core SSZK1 into three intervals, which are Unit I(31.20–55.92 m, LMC), Unit II(18.39–31.20 m, aragonite and LMC) and Unit III(upper 18.39 m of core, aragonite, LMC and HMC). Various degrees of meteoric diagenesis exist in the identified three units. The lowermost Unit I has suffered almost complete freshwater diagenesis, whereas the overlying Units II and III have undergone incompletely meteoric diagenesis. The amount of time that limestone has been in the freshwater diagenetic environment has the largest impact on the degree of meteoric diagenesis. Approximately four intact facies/water depth cycles are recognized. The cumulative depletion of elements such as strontium(Sr),sodium(Na) and sulphur(S) caused by duplicated meteoric diagenesis in the older reef sequences are distinguished from the younger reef sequences. This study provides a new record of meteoric diagenesis, which is well reflected by whole-rock mineralogy and geochemistry.     

河口物质和水体长期输运分离的理论分析和观测验证Ⅰ.物质和水体长期输运分离的理论分析

基于单宽断面潮周期平均水体和物质对流输运通量,定义了二维水体和物质长期输运速度,它们分别描述单宽断面水体和物质长期输运的方向及快慢。通过二维水体和物质长期输运速度的对比分析,提出了物质和水体长期输运分离概念:受物质浓度影响,在物质和水体瞬时运动速度相同的情况下,物质和水体潮周期平均对流输运的方向和快慢可能存在差异。本文将二维物质长期输运速度分解为二维水体长期输运速度、二维潮泵输运速度和垂向切变输运速度,它们分别描述余流输运、潮泵输运和垂向切变输运,后两种输运造成单宽断面物质和水体长期输运分离。本文的分析表明,河口受地形、径流、潮流、密度梯度影响,存在有利于物质和水体长期输运分离的自然条件。     

基于Barnes滤波原理的降水场客观分析及尺度分离

基于Barnes滤波原理（又称高斯加权客观分析）,在进行网格点插值的同时,通过选择适当的滤波参数C、G滤去原始场中的短波噪音,使分析结果平稳光滑;另外可通过它构成一带通滤波器,根据实际需要分离出影响天气过程的各种次天气尺度,达到尺度分离的目的。以全国160个国家基准代表站1954—2006年共53a的年平均降水场为例作实例分析,并同用Grads内插函数（Oacres函数）、九点平滑函数（Smth9函数）的绘图结果进行对比分析,结果表明客观分析结果同Grads内插平滑分析结果基本相似,都能反映出我国53a年平均降水场从东南向西北逐渐递减的趋势且与实际情况相符,降水场高值中心位于长江流域及以南的华南等地区,低值中心位于黄河流域以北的广大西部地区。取不同的参数C和G得到的尺度分离后的带通滤波值,既抑止了长波,又抑制了短波,达到较好的尺度分离效果。     

黄淮海地区乡村人—地—业协调发展格局与机制

乡村在社会中占有重要地位,但乡村衰败目前已成为世界性问题,因此,乡村振兴需破解乡村病问题。现有乡村研究主要关注乡村单一系统、乡村转型或乡村特定问题的研究,对乡村系统自身、乡村各子系统之间关系及其驱动乡村发展逻辑的研究则显匮乏。基于黄淮海地区县域数据,选取乡村人—地—业3个子系统,利用耦合协调度模型刻画了乡村内部系统耦合协调度的空间格局,并对人—地—业驱动乡村发展的内在逻辑进行了探讨。结果发现：① 黄淮海地区大部分县域乡村人—地—业发展处于高水平耦合阶段,在空间格局上形成了4条明显的高值轴带,且乡村系统发展水平呈逐年上升趋势。② 黄淮海地区乡村耦合协调水平整体较高,但大部分处于勉强协调或初级协调阶段,耦合协调水平较高的县域主要集中在经济较发达地区。③ 黄淮海地区乡村耦合协同关系可分为低协调水平—土地发展领先型、中协调水平—人口发展领先型和高协调水平—人业发展引领型3种类型,其中产业在黄淮海地区乡村协调发展中至关重要。④ 乡村人—地—业的协调发展可有效激活“四力”,为乡村可持续发展奠定了基础。本研究为理解乡村系统自身、破解乡村问题及实现乡村可持续发展提供了参考。     

A two-dimensional analytical model of vertical water entry for asymmetric bodies with flow separation

The vertical water entry of asymmetric two-dimensional bodies with flow separation is considered. As long as there is no flow separation, linearised Wagner's theory combined with the modified Logvinovich model has been shown to provide computationally fast and reliable estimates of slamming loads during water entry. Tassin et al. [11] introduced the fictitious body continuation (FBC) concept as a way to extend the use of Wagner's model to separated flow configurations, but they only considered symmetric bodies. In the present study, we investigate the ability of the FBC concept to provide accurate estimates of slamming loads for asymmetric bodies. In this case, flow separation may not occur simultaneously on both sides of the body. During an intermediate phase, slamming loads are governed by a competition between the local drop in pressure due to partial flow separation and the ongoing expansion of the wetted area. As a first benchmark for the model, we consider the water entry of an inclined flat plate and compare the FBC estimates with the results of a nonlinear model. Then, we consider the case of a foil and compare the FBC results with computational fluid dynamics predictions. In both cases, we find that the FBC model is able to provide reliable estimates of the slamming loads.     

球面距离计算方法及精度比较

球面距离(角间距)计算是天文或地理学中极常用的计算之一,也是目标查找、锥形检索、交叉证认等方法的基础。数学上,通过球面几何可以直接计算出两点的距离,前人已经推导出了多个复杂程度不一的计算方法。但是由于计算机的精度有限,在进行数值计算时有舍入误差,导致公式计算结果出现偏差。对几个常用的球面距离计算公式进行了考察,测试并对比它们在不同计算环境下的精度与优缺点。此外还展示并比较了几种常用天文软件包、数据库的球面距离计算方法,以期有助于天文工作者选择适合自己当前需要的计算方法。     

银河系铝元素丰度研究

恒星的Al元素丰度可以为探索星团和星系的化学演化提供重要线索.通过系统分析银河系薄盘、厚盘、核球、银晕以及M4、M5等球状星团中恒星的[Al/Fe]随恒星金属丰度[Fe/H]的变化趋势,得出银河系薄盘、厚盘和核球恒星的[Al/Fe]随着[Fe/H]的增加而缓慢下降,而球状星团M4和M5恒星的[Al/Fe]随[Fe/H]增加没有下降趋势,这暗示Ia超新星对M4和M5恒星元素丰度的贡献比较小.详细研究了银河系恒星[Al/Fe]与[Mg/Fe]、[Na/Fe]的相关性,结果表明银河系场星的[Al/Fe]与[Mg/Fe]正相关,但在球状星团M4和M5恒星中未见此相关性;银河系盘星及M4和M5等球状星团恒星的[Al/Fe]与[Na/Fe]都存在正相关.     

酉阳河流域典型年汛期的基流分割研究

基流分割是水文学研究中的重难点问题之一,目前基流分割也存在许多方法.基于酉阳河典型年汛期实测日平均流量资料,分别采用Chapman-Maxwell改进方程数字滤波法一次滤波(参数N=1)以及二次滤波(参数N=2)、BFI(f)法、HYSEP固定步长法、HYSEP滑动步长法、HYSEP局部最小值法进行基流分割并对其结果进...     

巢湖沉积植硅体组合及中全新世以来的环境演变

尽管以前对眼虫进行过大量的形态发育研究和基于核糖体RNA基因的系统发育分析,但对于株系之间的关系仍然知之甚少．因其形态特征有限并且易变,很难鉴定眼虫的相似种和同种内不同的株．作者利用微卫星DNA指纹图谱,在七株眼虫中扩增了七个微卫星DNA位点,成功扩增的六个微卫星引物都得到了四到八个条带．从微卫星DNA指纹图谱计算得到的相似性系数范围从0．000到0．957．根据相似性系数得到的树状结构,七株眼虫在距离为0．9346处分为三支:E．mutabilis,E．intermedia和E．gracilis．其中,五株E．gracilis分为两组:来自日本的和美国的．不同地区的株得到不同的基因型,并初步分析了它们之间的关系．研究表明七株眼虫根据微卫星DNA指纹图谱被明显区分开．微卫星DNA指纹图谱具有很高的分辨率,是鉴定和区分原生动物相似种和同种内不同株的一种有用的新方法．