全文获取类型
收费全文 | 6282篇 |
免费 | 1154篇 |
国内免费 | 2189篇 |
专业分类
测绘学 | 251篇 |
大气科学 | 378篇 |
地球物理 | 2105篇 |
地质学 | 4372篇 |
海洋学 | 947篇 |
天文学 | 706篇 |
综合类 | 338篇 |
自然地理 | 528篇 |
出版年
2024年 | 13篇 |
2023年 | 71篇 |
2022年 | 167篇 |
2021年 | 257篇 |
2020年 | 316篇 |
2019年 | 354篇 |
2018年 | 252篇 |
2017年 | 245篇 |
2016年 | 294篇 |
2015年 | 311篇 |
2014年 | 362篇 |
2013年 | 393篇 |
2012年 | 368篇 |
2011年 | 495篇 |
2010年 | 397篇 |
2009年 | 485篇 |
2008年 | 475篇 |
2007年 | 512篇 |
2006年 | 511篇 |
2005年 | 438篇 |
2004年 | 367篇 |
2003年 | 322篇 |
2002年 | 264篇 |
2001年 | 248篇 |
2000年 | 221篇 |
1999年 | 249篇 |
1998年 | 190篇 |
1997年 | 166篇 |
1996年 | 165篇 |
1995年 | 141篇 |
1994年 | 115篇 |
1993年 | 93篇 |
1992年 | 79篇 |
1991年 | 64篇 |
1990年 | 33篇 |
1989年 | 62篇 |
1988年 | 29篇 |
1987年 | 29篇 |
1986年 | 27篇 |
1985年 | 10篇 |
1984年 | 8篇 |
1983年 | 6篇 |
1982年 | 7篇 |
1981年 | 5篇 |
1978年 | 2篇 |
1977年 | 2篇 |
1974年 | 1篇 |
1954年 | 4篇 |
排序方式: 共有9625条查询结果,搜索用时 15 毫秒
31.
电感耦合等离子体发射光谱法同时测定玻璃中铝钙铁钾镁钠钛硫 总被引:2,自引:2,他引:0
通过选择分析谱线、处理样品方法和消除干扰因素等实验,建立了电感耦合等离子体发射光谱法同时测定玻璃中的Al2O3、CaO、Fe2O3、K2O、MgO、Na2O、TiO2和SO3的方法,克服了利用常规化学法测定玻璃中各氧化物步骤繁琐、耗时长、工作量大的不足。方法的回收率为95.0%~103.0%,精密度(RSD,n=10)为0.20%~1.72%。方法具有快速、简便、线性范围宽等优点,分析误差满足常规化学分析法的要求。用于钠钙硅玻璃及其制品的分析,结果令人满意。 相似文献
32.
氢化物发生-原子荧光光谱法直接测定地球化学样品中痕量碲 总被引:2,自引:1,他引:1
采用硝酸-氢氟酸-高氯酸溶解样品,以Fe3+作减缓剂,不需分离富集,用氢化物发生-原子荧光光谱法直接测定地球化学样品中痕量碲。对测定介质、KBH4浓度、铁盐的作用等条件进行试验。方法检出限为0.0031μg/g,精密度(RSD,n=11)<6.10%。方法用于国家一级地球化学标准物质中痕量碲的测定,结果与标准值一致。 相似文献
33.
34.
35.
碱消解-高效液相色谱-电感耦合等离子体质谱法测定生物样品中的甲基汞和乙基汞 总被引:7,自引:2,他引:5
建立了碱消解-高效液相色谱-电感耦合等离子体质谱联用系统测定生物样品中甲基汞(MeHg)与乙基汞(EtHg)的分析方法。为提高灵敏度,选用微流量的PFA雾化器,在优化的检测条件下,MeHg及EtHg检出限可达到0.036μg/L和0.03μg/L;线性范围达到4个数量级,两条工作曲线线性相关系数为1。对1.78μg/L MeHg、1.65μg/L EtHg的混合标准溶液重复测定7次,色谱峰面积的相对标准偏差(RSD)分别为1.79%和1.44%。对标准物质BCR 464(金枪鱼)的分析结果表明,测定值与标准值基本吻合,但略低于标准值;甲基汞和乙基汞的加标回收率分别为85.9%和84.5%。高效液相色谱与质谱联用技术的高灵敏度和低检出限能够满足生物样品中汞形态定量分析的要求。 相似文献
36.
37.
Paul R. Craddock Olivier J. Rouxel Lary A. Ball Wolfgang Bach 《Chemical Geology》2008,253(3-4):102-113
We have developed a technique for the accurate and precise determination of 34S/32S isotope ratios (δ34S) in sulfur-bearing minerals using solution and laser ablation multiple-collector inductively coupled plasma mass spectrometry (MC-ICP-MS). We have examined and determined rigorous corrections for analytical difficulties such as instrumental mass bias, unresolved isobaric interferences, blanks, and laser ablation- and matrix-induced isotopic fractionation. Use of high resolution sector-field mass spectrometry removes major isobaric interferences from O2+. Standard-sample bracketing is used to correct for the instrumental mass bias of unknown samples. Background on sulfur masses arising from memory effects and residual oxygen-tailing are typically minor (< 0.2‰, within analytical error), and are mathematically removed by on-peak zero subtraction and by bracketing of samples with standards determined at the same signal intensity (within 20%). Matrix effects are significant (up to 0.7‰) for matrix compositions relevant to many natural sulfur-bearing minerals. For solution analysis, sulfur isotope compositions are best determined using purified (matrix-clean) sulfur standards and sample solutions using the chemical purification protocol we present. For in situ analysis, where the complex matrix cannot be removed prior to analysis, appropriately matrix-matching standards and samples removes matrix artifacts and yields sulfur isotope ratios consistent with conventional techniques using matrix-clean analytes. Our method enables solid samples to be calibrated against aqueous standards; a consideration that is important when certified, isotopically-homogeneous and appropriately matrix-matched solid standards do not exist. Further, bulk and in situ analyses can be performed interchangeably in a single analytical session because the instrumental setup is identical for both. We validated the robustness of our analytical method through multiple isotope analyses of a range of reference materials and have compared these with isotope ratios determined using independent techniques. Long-term reproducibility of S isotope compositions is typically 0.20‰ and 0.45‰ (2σ) for solution and laser analysis, respectively. Our method affords the opportunity to make accurate and relatively precise S isotope measurement for a wide range of sulfur-bearing materials, and is particularly appropriate for geologic samples with complex matrix and for which high-resolution in situ analysis is critical. 相似文献
38.
Landslide susceptibility mapping for a landslide-prone area (Findikli,NE of Turkey) by likelihood-frequency ratio and weighted linear combination models 总被引:17,自引:0,他引:17
Landslides are very common natural problems in the Black Sea Region of Turkey due to the steep topography, improper use of
land cover and adverse climatic conditions for landslides. In the western part of region, many studies have been carried out
especially in the last decade for landslide susceptibility mapping using different evaluation methods such as deterministic
approach, landslide distribution, qualitative, statistical and distribution-free analyses. The purpose of this study is to
produce landslide susceptibility maps of a landslide-prone area (Findikli district, Rize) located at the eastern part of the
Black Sea Region of Turkey by likelihood frequency ratio (LRM) model and weighted linear combination (WLC) model and to compare
the results obtained. For this purpose, landslide inventory map of the area were prepared for the years of 1983 and 1995 by
detailed field surveys and aerial-photography studies. Slope angle, slope aspect, lithology, distance from drainage lines,
distance from roads and the land-cover of the study area are considered as the landslide-conditioning parameters. The differences
between the susceptibility maps derived by the LRM and the WLC models are relatively minor when broad-based classifications
are taken into account. However, the WLC map showed more details but the other map produced by LRM model produced weak results.
The reason for this result is considered to be the fact that the majority of pixels in the LRM map have high values than the
WLC-derived susceptibility map. In order to validate the two susceptibility maps, both of them were compared with the landslide
inventory map. Although the landslides do not exist in the very high susceptibility class of the both maps, 79% of the landslides
fall into the high and very high susceptibility zones of the WLC map while this is 49% for the LRM map. This shows that the
WLC model exhibited higher performance than the LRM model. 相似文献
39.
Estimating potential landslide sites of an upland sub-watershed in Western Ghat’s of Kerala (India) through frequency ratio and GIS 总被引:10,自引:0,他引:10
The purpose of this study is to assess the susceptibility of landslides in parts of Western Ghats, Kerala, India, using a
geographical information system (GIS). Landslide inventory of the area was made by detailed field surveys and the analysis
of the topographical maps. The landslide triggering factors are considered to be slope angle, slope aspect, slope curvature,
slope length, distance from drainage, distance from lineaments, lithology, land use and geomorphology. ArcGIS version 8.3
was used to manipulate and analyse all the collected data. Probabilistic-likelihood ratio was used to create a landslide susceptibility
map for the study area. The result was validated using the Area under Curve (AUC) method and temporal data of landslide occurrences.
The validation results showed satisfactory agreement between the susceptibility map and the existing data on landslide locations.
As the result, the success rate of the model was (84.46%) and the prediction rate of the model was (82.38%) shows high prediction
accuracy. In the reclassified final landslide susceptibility zone map, 5.68% of the total area is classified as critical in
nature. The landslide susceptibility map thus produced can be used to reduce hazards associated with landslides and to land
cover planning. 相似文献
40.
Gamma activity from the naturally occurring radionuclides namely, 226Ra, 232Th, the primordial radionuclide 40K was measured in the soil of Cuihua Mountain National Geological Park, China using γ-ray spectrometry technique. The mean
activity of 226Ra, 232Th and 40K were found to be 27.2 ± 6.5, 43.9 ± 6.2 and 653.1 ± 127.6 Bq kg−1, respectively. The concentrations of these radionuclides were compared with the typical world values and the average activities
of Chinese soil. The radium equivalent activity, the air absorbed dose rate, the annual effective dose rate, and the external
hazard index were evaluated and compared with the internationally approved values. All the soil samples have Raeq lower than the limit of 370 Bq kg−1 and H
ex less than unity. The overall mean outdoor terrestrial gamma dose rate is 66.3 nGy h−1 and the corresponding outdoor annual effective dose is 0.081 mSv. 相似文献