应用高分辨率透射电镜研究煤显微组分的结构

应用高分辨率透射电镜研究变质系列镜质体和丝质体以及热解碳的物理结构特征表明,随煤级增高,镜质体的基本结构单元(BSU)的平均长度及缩聚芳香层平均环数NC呈增加的趋势;衍射环数增多,环的弥散程度减小,最终出现弧状;表明镜质体的BSU在变质过程中长大,定向性增强,VRo,max=6.50％是阶跃点,当VRo,max>6.50％,BSU突然定向排列。获得了很难获得的低煤化烟煤(VRo,max=0.66％)的高分辨图像,它的BSU尺寸小,无序排列。对丝质体和热解碳高分辨图像的首次研究发现,前者有序性差,随煤级演化的速度较镜质体慢,后者有序性好。     

金矿床中环带状黄铁矿及其生长演化过程的研究

利用电子探针对黔南卡林型金矿床中环带状黄铁矿进行研究，把它划分成三种类型，并分别测定内外带中Ａｓ、Ｓｂ、Ａｕ、Ｈｇ和Ｔｌ等微量元素的含量，绘制了以步间距１μｍ，横穿环带的这五种元素的Ｘ射线强度变化曲线图，图中清楚显示出环带起因于微量元素含量的变化，这五种元素在微观尺度上呈正相关的振荡式变化，具有同源性。讨论黄铁矿经由胶体粒子的聚集、固结与结晶的生长演化过程，提供了低温热液可能是一种富含成矿质的多相     

电子探针能谱矿物定量分析

文章以不同类型矿物作为分析实例，说明电子探针能谱仪和谱仪在矿物分析中的作用。实验表明使用能谱各类矿物主元素进行定量分析，既满足精密要求又能缩短分析时间，提高工效约２０倍，对能谱用于定量分析过程中的若干技术问题进行了讨论，以期获得最佳精密度的分析结果。     

石英的电子—空穴心在金矿评价中的意义

石英的电子-空穴心在金矿找矿勘探中具有重要意义。阳离子不等价类质同象造成的晶体缺陷,是使其具有电子-空穴心的内在因素。石英中常见的空穴心有Al-O~-、Ti-O~-、Fe-O~-,电子心有Al~(3+)+M、Fe~(3+)+M、Ti~(3+)+M等。电子顺磁共振波谱和热发光是检测石英中电子-空穴心的有效方法。在金矿床中,石英Al-O~-顺磁空穴心浓度较大者,其含金量也比较高。石英热发光曲线的发光峰的数量和强度与金成矿阶段有着明显的关系:早期成矿阶段结晶的基本不含金石英,热发光曲线常为近对称的单峰型,发光强度较大;主成矿阶段形成的含金石英,热发光曲线为多峰型,常具最大的发光强度;晚期成矿阶段生成的含金性较差的右英,热发光曲线呈单峰-双峰型,发光强度亦较大。石英热发光性与金矿体的空间展布表现出一定的联系;在矿体横向上,矿体中石英热发光曲线多为双峰-多峰型,围岩中石英热发光曲线多呈单峰型;在矿体垂向上,随矿体埋深的增加,石英热发光强度有逐渐增大的趋势。含金石英通常具有多个热发光温度,曲线形态为多峰型,且主热发光峰多位于相对较低的温度区间;不含金石英常仅有一个热发光温度,曲线形态为不对称的较平缓的单峰型,或为一平缓的曲线,发光强度较弱。     

地磁场结构对静止轨道≥2 MeV高能电子分布的影响

基于AE8电子辐射带模式和各地磁场模式,本文系统分析了地磁场模式、太阳风、地磁扰动、地磁轴指向对静止轨道≥2 MeV高能电子分布的影响以及静止轨道不同经度位置≥2 MeV高能电子分布的差异,并与GOES系列卫星实测结果进行了对比分析.结果表明,AE8+IGRF+T96模式所得静止轨道≥2 MeV高能电子分布结果优于AE8+IGRF+OPQ77模式或AE8+IGRF+T89模式结果,其大部分定性结果与GOES系列卫星观测结果较为一致,AE8+IGRF+T96模式所得静止轨道≥2 MeV高能电子分布与磁壳参量Lm、局地磁场B分别呈较好的负和正相关性.基于AE8+IGRF+T96模式得到在相同太阳风及地磁扰动条件下2010年每分钟静止轨道≥2 MeV高能电子通量分布结果,经分析得到：1年内每个时刻静止轨道上≥2 MeV高能电子通量最大值和最小值比值变化范围为2.50~7.51,变化主周期为1天,每天比值变化量都超过3;1年内静止轨道各经度位置每天内≥2 MeV高能电子通量最大值和最小值比值变化范围为2.98~6.00,比值随着时间和经度位置而变化;1年内同一天静止轨道各经度位置≥2 MeV高能电子日积分通量最大值出现在170°W附近,最小值出现在70°W附近,最大值与最小值的比值分布在1.86~2.13之间.以上所得静止轨道≥2 MeV高能电子分布变化主要来自Lm变化,B/B₀的影响小于5%,其中B₀为磁力线上磁场最小值.因此,在构建≥2 MeV高能电子分布模式时,需要考虑地磁场结构的影响,特别是Lm参数.     

Strong magnetic linear dichroism in Fe <Emphasis Type="Italic">L</Emphasis><Subscript>23</Subscript> and O <Emphasis Type="Italic">K</Emphasis> electron energy-loss near-edge spectra of antiferromagnetic hematite α-Fe<Subscript>2</Subscript>O<Subscript>3</Subscript>

We report strong magnetic linear dichroism (MLD) at the Fe L₂₃ and O K edges of the antiferromagnetic compound hematite -Fe₂ O₃ in high-resolution orientation- and temperature-dependent electron energy-loss spectroscopy (EELS). Large intensity differences of corresponding spectral features are observed when the Fe L₂₃ and O K edges are measured with momentum transfer either parallel or perpendicular to the magnetization. The resultant difference spectra for the Fe L₂₃ edges is consistent with the MLD observed in X-ray absorption spectroscopy. For the first time we have observed MLD at the O K edge, where the magnetic origin of this dichroism is demonstrated by temperature-dependent investigations across the Morin transition temperature T_M= 263 K, at which the Fe electron spins, i.e. the magnetic moments, rotate by 90°. The O K edge MLD is interpreted in terms of superexchange between the spins of the Fe 3d and O 2p electrons through overlapping Fe 3d and O 2p orbitals. The experiments were performed in a transmission electron microscope (TEM), yielding information about the anisotropic electronic structure at nanoscale spatial resolution when operated with a focused electron probe. The effects of MLD at the Fe L₂₃ edges on the determination of Fe³⁺/Fe in hematite at submicrometre scale using different independent quantification methods are discussed.     

Ion probe dating of a migmatite in SW Sweden: the fate of zircon in crustal processes

A migmatitic orthogneiss in the Western Segment in the Sveconorwegian Province of the Baltic Shield was dated using the ion-probe U–Pb method on zircon grains, which were also analysed for rare earth elements. Mesosome zircons have 1.605±0.010 Ga magmatic cores, which places the gneiss protolith in the same 1.61–1.59 Ga time bracket as continental arc-related gneisses, abundant in this part of the Sveconorwegian Province. These cores show REE profiles with strong HREE enrichment, positive Ce- and negative Eu-anomalies, typical of magmatic zircon. Migmatite leucosomes are folded and parallel with or slightly discordant to the fabric. They contain a small population of zircon with cores and metamorphic rims, which are interpreted as xenocrysts incorporated in the leucosome during melting of the mesosome. CL-bright metamorphic embayments and rims on xenocrysts reflect 1.01±0.05 Ga Sveconorwegian metamorphic reworking. Ce-anomalies are nearly absent and Eu-anomalies are reduced relative to igneous spots. This is probably a feature of fluid controlled environments where Ce and Eu oxidation states are buffered by the metamorphic fluid. From this and discordant rims from the mesosome we also conclude that the rims formed by reworking of the older zircon where the Pb-loss was also fluid induced. In the leucosome veins, magmatic acicular zircon gives 0.92±0.01 Ga, ascribed to the crystallisation of the veins. They originated by local melting, probably augmented by magma that formed at a deeper level. Widespread granitic and noritic late-Sveconorwegian magmatism close to 0.92 Ga in other parts of the Western Segment has equivalents in the Norwegian sectors of the Sveconorwegian Province. Leucosome formation was therefore part of a regional event related to exhumation of the Sveconorwegian Eastern Segment. We also provide the first unequivocal evidence for ductile deformation related to late-Sveconorwegian magmatism.     

煤田地勘单位矿业权运作问题探讨

简述了我国矿业权市场建立和发展情况，提出了矿业权市场目前存在的诸多问题及对策建议；认为地勘单位必须树立矿业权经营理念，以此推动煤田地勘事业持续发展。     

Trace element fractionation during high-grade metamorphism and crustal melting—constraints from ion microprobe data of metapelitic, migmatitic and igneous garnets and implications for Sm–Nd garnet chronology

Rare earth element (REE) and other trace element (Y, Sr, Ti, Cr, V, Na) abundances in garnet from a garnet-bearing metapelite, a pelitic migmatite, a syn-tectonic granite and a post-tectonic leucogranite were measured by secondary ion mass spectrometry (SIMS) in order to identify the effective variables on the trace element distribution between garnet and the host rock. Garnet from the garnet-bearing metapelite, the pelitic migmatite and the syn-tectonic granite is zoned with respect to REE. The cores are enriched by a factor of 2–3 relative to the rims. For the garnets from the garnet-bearing metapelite equilibrium distribution following a simple Rayleigh fractionation is responsible for the decreasing concentrations in REE from core to rim. Garnet from the pelitic migmatite shows a more complex trace element pattern following distinct enrichment and depletion patterns for Ti, V, Cr and REE from core to rim. These features suggest disequilibrium between garnet and the associated melt in which the enrichment of trace elements probably correspond to a period of open-system behaviour in these rocks at a time when the garnet, originally nucleated in the metamorphic environment was incorporated into the melt. The garnet from the syn-tectonic granite shows stepwise decreasing concentrations in REE from core to rim: a REE-rich core can be distinguished from a broad REE-depleted rim. Notably, from core to rim an inflection of the Yb / Er and Yb / Dy ratios is visible. Whereas the decrease of HREE abundance in the core region of the garnet from the syn-tectonic granite may arise from equilibrium partitioning during garnet growth, the inflection can be interpreted as a result of partial melting. Garnet cores with high Yb / Er and Yb / Dy >  1 nucleated in the metamorphic environment without the presence of a melt whereas the rims with lower Yb / Er and Yb / Dy <  1 crystallized in the presence of a melt. Garnet from the leucogranite has lower REE abundances and is considered to be of igneous origin. In contrast to garnet from the other samples, its core has low trace element abundances, whereas its rim is significantly enriched in REE but depleted in Ti. These features suggest that only the outermost rim was in equilibrium with the melt. For this garnet, liquid diffusion controlled partitioning is more likely to explain the extreme trace element variation. An evaluation of Sm and Nd concentrations in garnet and a comparison of Sm–Nd and U–Pb garnet ages and U–Pb monazite ages form the terrane indicate that the observed LREE systematics in the different garnet species are a primary feature and are not homogenized by volume diffusion during high grade amphibolite facies conditions.