Contact angles in CO2-water-coal systems at elevated pressures

Injection of carbon dioxide into coal seams is considered to be a potential method for its sequestration away from the atmosphere. However, water present in coals may retard injection: especially if carbon dioxide does not wet the coal as well as water. Thus contact angles in the coal-water-CO₂ system were measured using CO₂ bubbles in water/coal systems at 40 °C and pressures up to 15 MPa using five bituminous coals. At low pressures, in this CO₂/water/coal system, receding contact angles for the coals ranged between 80° to 100°; except for one coal that had both high ash yield and low rank, with a contact angle of 115°, indicating that it was hydrophilic. With increasing pressure, the receding contact angles for the different coals decreased, indicating that they became more CO₂-wetting. The relationship between contact angle and pressure was approximately linear. For low ash or high rank coals, at high pressure the contact angle was reduced to 30-50°, indicating the coals became strongly CO₂-wetting; that is CO₂ fluids will spontaneously penetrate these wet coals. In the case of the coal that was both high ash and hydrophilic, the contact angle did not drop to 90° even at the highest pressures used. These results suggest that CO₂ will not be efficiently adsorbed by all wet coals equally well, even at high pressure. It was found that at high pressures (> 2 MPa) the rate of penetration of carbon dioxide into the coals increased rapidly with decreasing contact angle, independently of pressure. Injecting CO₂ into wet coals that have both low rank and high ash will not trap CO₂ as well as injecting it into high rank or low ash coals.     

Melt-Solid Dihedral Angles of Common Minerals in Natural Rocks

The melt–solid dihedral angle has been measured in a rangeof igneous rock types, ranging in composition from picrite,through basalt, phonolite, andesite and rhyolite, for the mineralsquartz, leucite, plagioclase, olivine, amphibole and clinopyroxene.Populations of up to 104 true 3-D angles were measured in eachsample using a universal stage mounted on an optical microscope.The median and standard deviation of the angle populations foreach mineral are distinct (plagioclase 25°, with standarddeviation (SD) 11°; clinopyroxene 38°, with SD 14°;olivine 29°, with SD 13°; quartz 18°, with SD 9°;leucite 20°, with SD 11°), with no control by eithermelt composition or degree of approach of the grains to theirequilibrium shapes. KEY WORDS: dihedral angle; textural equilibrium; universal stage     

反倾岩质边坡变形特征的三维数值模拟研究--以龙滩水电站工程边坡为例进行三维变形特征分析

以龙滩水电站工程边坡三维变形为例,分析了层状反倾岩质边坡当边坡与岩层夹角变化时,边坡的变形特征。并通过数值模拟根据变形曲线对不同范围边坡与岩层走向夹角的变形特征进行了定性描述。     

双重孔隙介质中P1波在自由边界上的反射

对双重孔隙介质波动中的体波及P1波在半空间自由透水和不透水边界上的反射问题进行了详细的理论求解。通过数值计算,对双重孔隙介质中4种体波的弥散和衰减特性,以及不同边界上反射波振幅反射系数随P1波入射角和频率的变化进行了分析。结果表明：（1）P1、P2、P3和S波均具有弥散和衰减特性,P1波传播最快而衰减最慢,P3波传播最慢而衰减最快;（2）随着入射角的增大,反射P2、P3和S波的振幅反射系数均先增大后减小,反射P1波则先减小后增大,且边界透水条件对反射P2和P3波的振幅反射系数影响显著,对P1和S波的影响较小,但透水和不透水边界下振幅反射系数随入射角的变化趋势一致;（3）反射P2、P3波的振幅反射系数均随频率的增大而增大,且不透水边界下反射P2波的振幅反射系数大于透水边界下的反射系数,而反射P3波则相反;（4）随着频率增大,透水边界下反射P1波的振幅反射系数先增大后减小,不透水边界下先减小后增大再减小,反射S波的振幅反射系数随频率变化情况则与P1波相反。     

TECTONIC TRANSFER ON THE EASTERN EDGE OF PAMIR

TECTONIC TRANSFER ON THE EASTERN EDGE OF PAMIR     

“醉汉林”作为滑坡和边坡变形特征标志的意义——以陕西陇县地区为例

“醉汉林”一般被当做滑坡存在的一种标志。在陕西宝鸡地区进行地质灾害详细调查的过程中,发现变形边坡也有“醉汉林”分布。对陕西陇县郭家庄变形边坡“醉汉林”的树木倾斜角与边坡的倾角进行了测量,并结合几何学分析,认为树木倾斜角反映了边坡倾角的变化,并得出边坡倾角不断变陡是该地区边坡变形的一种主要方式的结论。研究结果表明,“醉汉林”有着多样而具体的指示意义:“醉汉林”记录了边坡变形的历史,可以作为区分滑坡与变形边坡的标志,“醉汉林”可以指示滑坡及边坡的状态,还可以判断滑坡剪出口是否存在。     

Fe3+纳米胶体颗粒的光吸收边蓝移与溶液中Al/Fe比的关系

合成了n（Al）／n（Fe）和碱化度不同的45个聚合氯化铝铁（PAFC）样品,进行了光谱分析,结果显示光吸收边蓝移或红移以及Fe（Ⅲ）羟基氧化物和Al-Fe共聚体纳米胶体颗粒大小分布与溶液的Al／Fe比和碱化度（B=[OH]／[Al＋Fe]）密切相关。电镜观察和电子衍射分析表明：Al（Ⅲ）的加入使Fe（Ⅲ）羟基氧化物和Al-Fe共聚体纳米胶体颗粒变小、有序度降低是造成PAFE光吸收边蓝移和保持胶体颗粒在亚稳定状态下存在的重要原因。当n（Al）／n（Fe）〉8：2后,PAFC溶液中Fe（Ⅲ）羟基氧化物和Al-Fe共聚体胶体主要以〈10m的纳米颗粒形态存在,对应的光谱能级提高到26000cm^-1以上,且各种曰值下Fe^3＋的光谱能级趋于一致。这表明,在大量Al（Ⅲ）存在条件下,PAFE中Fe3^＋的所处的化学环境相似。点能谱分析显示,n（Al）／n（Fe）=4：6的样品中颗粒物的化学计量比最接近AlOOH,FeOOH,溶液的稳定性最差。     

基于平面应变试验的非饱和膨胀土强度分析

介绍了非饱和土强度理论的研究现状,总结了FREDLUND提出的吸力内摩擦角 的性质与规律研究,根据FREDLUND非饱和土强度理论和吸力内摩擦角 的计算方法,利用原状膨胀土的平面应变等应力比卸荷试验,分析得到土样破坏时应力状态下得到的吸力内摩擦角 > ,与FREDLUND提出的吸力内摩擦角 的变化规律不一致,分析认为,是由于卸荷试验过程导致微裂隙的张开,引起基质吸力的降低,有待于继续深入研究。     

结构面粗糙度系数Barton直边法的简明公式

JRC是反映爬坡角力学效应的岩体结构面表面形态等效描述指标。本文在Barton直边法的研究基础上,利用直边图的几何性质,推导出结构面粗糙度系数Barton直边法的简明公式,并通过实例检验了JRC简明公式的合理性和实用性。     

垦71区块井间地震资料处理研究与应用

由于避开了地表低降速带和风化层的影响,井间地震能够采集到高频地震信号,经过资料处理可以得到较高分辨率的速度和上行反射波成像剖面.2004~2005年,胜利油田在垦71 区块实施了8对井间地震资料采集.针对原始资料特点,研究了以层析成像、管波衰减、VSP-CDP技术和有限角度叠加成像等关键处理技术,较好地完成了该区块的井间地震资料处理.初步分析解释表明,井间地震可以识别低序级断层、小幅度构造和薄储层.