New LA-ICPMS U–Pb ages of detrital zircons from the Highland Complex: insights into late Cryogenian to early Cambrian (ca. 665–535 Ma) linkage between Sri Lanka and India

ABSTRACT

Here we report new LA-ICPMS U–Pb zircon geochronology of ultrahigh temperature (UHT) metasedimentary rocks and associated crystallized melt patches, from the central Highland Complex (HC), Sri Lanka. The detrital zircon ²⁰⁶Pb/²³⁸U age spectra range between 2834 ± 12 and 722 ± 14 Ma, evidencing new and younger depositional ages of sedimentary protoliths than those known so far in the HC. The overgrowth domains of zircons in these UHT granulites yield weighted mean ²⁰⁶Pb/²³⁸U age clusters from 665.5 ± 5.9 to 534 ± 10 Ma, identified as new metamorphic ages of the metasediments in the HC. The zircon ages of crystallized in situ melt patches associated with UHT granulites yield tight clusters of weighted mean ²⁰⁶Pb/²³⁸U ages from 558 ± 1.6 to 534 ± 2.4 Ma. Thus, using our results coupled with recently published geochronological data, we suggest a new geochronological framework for the evolutionary history of the metasedimentary package of the HC. The Neoarchean to Neoproterozoic ages of detrital zircons indicate that the metasedimentary package of the HC has derived from ancient multiple age provenances and deposited during the Neoproterozoic Era. Hence, previously reported upper intercept ages of ca. 2000–1800 Ma from metaigneous rocks should be considered as geochronological evidence for existence of a Palaeoproterozoic igneous basement which possibly served as a platform for the deposition of younger supracrustal rocks, rather than timing of magmatic intrusions into the already deposited ancient sediments, as has been conventionally interpreted. The intense reworking of entire Palaeoproterozoic basement rocks in the Gondwana Supercontinent assembly may have caused sediments of multiple ages and provenances to incorporate within supra-crustal sequences of the HC. Further, our data supports a convincing geochronological correlation between the HC of Sri Lanka and the Trivandrum Block of Southern India, disclosing the Gondwanian linkage between the HC of Sri Lanka and Southern Granulite Terrain of India.     

Petrogenesis of Late Silurian volcanism in SW Yunnan (China) and implications for the tectonic reconstruction of northern Gondwana

ABSTRACT

Early Palaeozoic magmatic records and tectonic reconstructions along the northern margin of Gondwana are still pending problems. In this paper, Late Silurian Dawazi and Dazhonghe volcanics in SW Yunnan Province (China) were studied. The Dazhonghe volcanics (419 Ma) have variable chemical compositions with SiO₂ ranging between 49.8 and 79.5 wt.%, whereas, the Dawazi volcanics (417–429 Ma) form a bimodal volcanic suite consisting mainly of silicic rocks and subordinate basaltic rocks with a SiO₂ content gap of ca. 15 wt.%. The Dazhonghe volcanics display calc-alkaline elemental compositions with enrichment in light rare earth elements (LREEs), and depletion in high field strength elements (HFSEs) (e.g. Nb, Ta and Ti) and positive ε_Nd(t) values (+ 4.0 to + 5.5). The Dawazi basaltic rocks are calc-alkaline, depleted in HFSEs, enriched in large ion lithophile elements (LILEs) (e.g. Cs, Rb, U and K), and have high ε_Nd(t) values of ?1.7 to + 5.4. The Dawazi silicic rocks have high Na₂O/K₂O ratios and positive ε_Nd(t) values of + 2.4 to + 5.0, which are equivalents of calc-alkaline I-type granites. The Dazhonghe volcanics are dominated by fractional crystallization (FC) from a calc-alkaline primary magma which originated from an enriched mantle source metasomatized by subduction-related, sediment-derived fluid. The Dawazi basaltic rocks were derived from partial melting of an enriched mantle source metasomatized by subducted oceanic sediment/slab-derived fluids; the Dawazi silicic rocks originated from partial melting of the juvenile mafic lower crust with extensive FC. Both the Dazhonghe and Dawazi volcanics were generated in a continental back-arc extension setting. Combined with previous geological observations, a Late Silurian Prototethyan arc and back-arc extension system is proposed along the northern margin of Gondwana in SW China.     

Structural and geochronological relationships of metamorphic soles of eastern Mediterrranean ophiolites to surrounding units: indicators of intra‐oceanic subduction and emplacement

This paper is a synthesis of structural and geochronological data from eastern Mediterranean ophiolitic metamorphic rocks and surrounding units to interpret the intra‐oceanic subduction and ophiolite emplacement mechanism.

Metamorphic rocks occur as discontinuous tectonic slices at the base of the ophiolites, generally between the peridotite tectonites and volcanic‐sedimentary units, and locally in fault zones in the overlying peridotites. They consist essentially of amphibolite, and in lesser quantities, micaschist, quartzite, epidotite and marble.

Geological and geochronological data indicate that recrystallization of the metamorphic rocks occurred in the oceanic environment. The contact between the metamorphic rocks and the hanging‐wall is parallel to the foliation of the metamorphic rocks, and is interpreted as the fossil plane of intra‐oceanic subduction. Structural relationships suggest that intra‐oceanic subduction was situated between two lithospheric blocks separated by an oceanic fracture zone. Therefore the Neotethyan ophiolites with metamorphic soles represent the remnants of the overriding oceanic lithosphere's training slices of the metamorphic rocks at the base.

In the Anatolian region, radiometric dating of metamorphic rocks from the Taurus and Izmir‐Ankara‐Erzincan zone ophiolites yield nearly identical ages. Besides, palaeontological and structural data indicate coeval opening and similar oceanic ridge orientation. Consequently it is highly probable that Taurus and Izmir‐Ankara‐Erzincan zone ophiolites represent fragments of the same oceanic lithosphere derived from a single spreading zone. Palaeontological data from underlying volcanic and sedimentary units point out that the opening of the Neotethyan ocean occurred during Late Permian‐Middle Triassic time in the Iranian‐Oman region, during Middle Triassic in Dinaro‐Hellenic area, and finally during Late Triassic in the Anatolian region.

Radiometric dating of the metamorphic rocks exhibit that the intra‐oceanic thrusting occurred during late Lower‐early Late Jurassic for Dinaro‐Hellenic ophiolites, late Lower‐early Late Cretaceous for Anatolian, Iranian and Oman ophiolites well before their obduction on the Gondwanian continent. Neotethyan ophiolites were obducted onto various sections of the Gondwanian continent from late Upper Jurassic to Palaeocene time, Dinaro‐Hellenic ophiolites during late Upper Jurassic‐early Lower Cretaceous onto the Adriatic promontory, Anatolian, Iranian and Oman ophiolites from late Lower Cretaceous to Palaeocene onto the Aegean, Anatolian and Arabic promontories.     

U–Pb zircon ages,geochemical and Sr–Nd–Pb isotopic constraints on the dating and origin of intrusive complexes in the Sulu orogen,eastern China

TPost-orogenic intrusive complexes from the Sulu belt of eastern China consist of pyroxene monzonites and dioritic porphyrites. We report new U–Pb zircon ages, geochemical data, and Sr–Nd–Pb isotopic data for these rocks. Laser ablation-inductively coupled plasma-mass spectrometry U–Pb zircon analyses yielded a weighted mean ²⁰⁶Pb/²³⁸U age of 127.4 ± 1.2 Ma for dioritic porphyrites, consistent with crystallization ages (126 Ma) of the associated pyroxene monzonites. The intrusive complexes are characterized by enrichment in light rare earth elements and large ion lithophile elements (i.e. Rb, Ba, Pb, and Th) and depletion in heavy rare earth elements and high field strength elements (i.e. Nb, Ta, P, and Ti), high (⁸⁷Sr/⁸⁶Sr)_i ranging from 0.7083 to 0.7093, low ?_Nd(t) values from ?14.6 to ? 19.2, ²⁰⁶Pb/²⁰⁴Pb = 16.65–17.18, ²⁰⁷Pb/²⁰⁴Pb = 15.33–15.54, and ²⁰⁸Pb/²⁰⁴Pb = 36.83–38.29. Results suggest that these intermediate plutons were derived from different sources. The primary magma-derived pyroxene monzonites resulted from partial melting of enriched mantle hybridized by melts of foundered lower crustal eclogitic materials before magma generation. In contrast, the parental magma of the dioritic porphyrites was derived from partial melting of mafic lower crust beneath the Wulian region induced by the underplating of basaltic magmas. The intrusive complexes may have been generated by subsequent fractionation of clinopyroxene, potassium feldspar, plagioclase, biotite, hornblende, ilmenite, and rutile. Neither was affected by crustal contamination. Combined with previous studies, these findings provide evidence that a Neoproterozoic batholith lies beneath the Wulian region.     

Geochronologic-petrochemical studies of the Hongshishan mafic–ultramafic intrusion,Beishan area,Xinjiang (NW China): petrogenesis and tectonic implications

The Hongshishan mafic–ultramafic intrusion (SIMS zircon U–Pb age 286.4 ± 2.8 Ma) consists of dunite, clinopyroxene peridotite, troctolite, and gabbro. Major elements display systematic correlations. Trace elements have identical distribution patterns, including flat rare-earth element (REE) patterns with positive Eu anomalies and enrichments in large ion lithophile elements (LILE) but depletions in Nb and Ta, indicating fractional crystallization as a key factor in magmatic evolution. Petrologic and geochemical variations in drill core samples demonstrate that minor assimilation and progressive magma injections were closely associated with Ni–Cu mineralization. Mass balance estimates and Sr–Nd isotopes reveal that the Hongshishan parental magmas were high-Mg and low-Ti tholeiitic basalts and were derived from a lithospheric mantle source that had been modified by subducted slab metasomatism before partial melting.

Southward subduction of the Palaeo-Tianshan–Junggar Ocean is further constrained by a compilation of inferred, subduction-induced modifications of mantle sources in mafic–ultramafic intrusions distributed in the eastern Tianshan–Beishan area. Integrating the regional positive ?_Nd(t) granites, high-Mg and low-Ti basaltic magmas (mafic–ultramafic intrusions), and slightly later high-Ti basalts in NW China suggests that their petrogenesis could be attributed to Permian mantle plume activities.     

Geochemical and isotopic constraints on the age and origin of mafic dikes from eastern Shandong Province,eastern North China Craton

Post-orogenic mafic dikes are widespread across eastern Shandong Province, North China Craton, eastern China. We here report new U–Pb zircon ages and bulk-rock geochemical and Sr–Nd–Pb isotopic data for representative samples of these rocks. LA-ICP-MS U–Pb zircon analysis of two mafic dike samples yields consistent ages of 118.7 ± 0.25 million years and 122.4 ± 0.21 million years. These Mesozoic mafic dikes are characterized by high (⁸⁷Sr/⁸⁶Sr) _i ranging from 0.7082 to 0.7087, low ?_Nd(t) values from??17.0 to??17.5, ²⁰⁶Pb/²⁰⁴Pb from 17.14 to 17.18, ²⁰⁷Pb/²⁰⁴Pb from 15.44 to 15.55, and ²⁰⁸Pb/²⁰⁴Pb from 37.47 to 38.20. Our results suggest that the parental magmas of these dikes were derived from an ancient, enriched lithospheric mantle source that was metasomatized by foundered lower crustal eclogitic materials prior to magma generation. The mafic dikes underwent minor fractionation during ascent and negligible crustal contamination. Combined with previous studies, these findings provide additional evidence that intense lithospheric thinning beneath eastern Shandong occurred at ～120 Ma, and that this condition was caused by the removal/foundering of the lithospheric mantle and lower crust.     

Mineralization and fluid evolution of the Jiyuan polymetallic Cu–Ag–Pb–Zn–Au deposit,eastern Tianshan,NW China

The newly discovered Jiyuan Cu–Ag–(Pb–Zn–Au) deposit is located in the southern section of the eastern Tianshan orogenic belt, Xinjiang, northwestern China. It is the first documented deposit in the large Aqikekuduke Ag–Cu–Au belt in the eastern Tianshan orogen. Detailed field observations, parageneses, and fluid inclusion studies suggest an epithermal ore genesis for the main Cu–Ag mineralization, accompanied by a complicated hydrothermal alteration history most likely associated with the multi-stage tectonic evolution of the eastern Tianshan. The Jiyuan Cu–Ag ore bodies are located along the EW-striking, south-dipping Aqikekuduke fault and are hosted by Precambrian marble and intercalated siliceous rocks. Early-stage skarn alteration occurred along the contact zone between the marble layers and Early Carboniferous diorite–granodiorite and monzogranite intrusions; the skarns are characterized by diopside–tremolite–andradite–pyrite–(magnetite) assemblages. Local REE-enriched synchysite–rutile–arsenopyrite–(clinochlorite–microcline–albite) assemblages are related to K–Na alteration associated with the monzogranite intrusions and formed under conditions of high temperature (310°C) and high salinity (19.9 wt.% NaCl). Subsequent hydrothermal alteration produced a series of quartz and calcite veins that precipitated from medium- to low-temperature saline fluids. These include early ‘smoky’ quartz veins (190°C; 3.0 wt.% NaCl) that are commonly barren, coarse-grained Cu–Ag mineralized quartz veins (210°C; 2.4 wt.% NaCl), and late-stage unmineralized calcite veins (140°C; 1.1 wt.% NaCl). Tremolite and Ca-rich scapolite veins formed at an interval between early and mineralized quartz veins, indicating a high-temperature, high-salinity (>500°C; 9.5 wt.% NaCl) Ca alteration stage. Fluid mixing may have played an important role during Cu–Ag mineralization and an external low-temperature Ca-rich fluid is inferred to have evolved in the ore-forming system. The Jiyuan auriferous quartz veins possess fluid characteristics distinct from those of the Cu–Ag mineralized quartz veins. CO₂-rich fluid inclusions, fluid boiling, and mixing all demonstrate that these auriferous quartz veins acted as hosts for the orogenic-type gold mineralization, a common feature in the Tianshan orogenic belt.     

Large-scale gold mineralization in eastern China induced by an Early Cretaceous clockwise change in Pacific plate motions

Orogenic gold (Au) deposits are the most important type, accounting for more than half of the world's proven Au reserves. They are mainly controlled by three key factors: (1) abundant andesitic rocks (SiO₂ of 55–60 wt.%) at depth, which have systematically higher Au contents than other rock types; (2) a pervasive transition from greenschist facies to amphibolite facies metamorphism within a short period, which releases S^2?-rich fluids that may scavenge Au from host rocks; and (3) deformation and fracturing under a compressive/transpressive tectonic regime. Orogenic belts at convergent margins are the best places for such mineralization because convergent margins are rich in andesites; the transition from greenschist to amphibolite facies recrystallization commonly occurs as a result of collision, compression, and thickening at convergent margins, forming large amounts of Au-rich fluids within a short period of time; and strong deformation and fracturing during orogenic processes provide channels for fluid transportation. Moreover, the overlying plate is injected and enriched by auriferous fluids released during amphibolite facies metamorphism of the subducting plate. The Pacific plate changed course by ～80° (from SW to NW) at approximately 125–122 Ma, reflecting an altered thermal structure and the elevation of the South Pacific plate attending the appearance of the plume head that formed the Ontong Java large igneous province. Consequently, the tectonic regime changed from extension to compressive/transpressive in eastern China, causing deformation, thickening, and metamorphism of the overriding plate, especially along weak crustal belts (e.g. overlying plates of palaeosutures), which resulted in world-class mineralization of orogenic Au deposits. During this process, pyrite changed to pyrrhotite during the transition from greenschist to amphibolite facies, releasing sulphur. Sulphur mobilized and scavenged Au and other chalcophile elements into metamorphic ore-forming fluids. A series of NE-trending compressive faults were formed at ?120 Ma as a result of continuous compression of the subducting Pacific plate, releasing these ore-forming fluids. Auriferous carbonate-rich quartz veins and/or metasomatized Au-bearing wall rocks were formed due to the decompression of the ascending ore-forming fluids. Orogenic belts along the margins of the North China craton and the Jiangnan block were the most favourable regions for mineralization. Compared with the former, the latter has much smaller proven Au reserves. However, more exploration is needed along the margins of the Jiangnan block. Promising targets include accessory faults and kink points of large, NE-trending Cretaceous faults that transect greenschist facies metamorphic rocks of the Niuwu and Jingtan Groups, etc.     

Geochronological evidence and tectonic significance of Carboniferous magmatism in the southwest Trabzon area,eastern Pontides,Turkey

The northern and southern zones of the eastern Pontides (northeast Turkey) contain numerous plutons of varying ages and compositions. Geochemical and isotopic results on two Hercynian granitoid bodies located in the northern zone of the eastern Pontides allow a proper reconstruction of their origin for the first time. The intrusive rocks comprise four distinct bodies, two of which we investigated in detail. Based on LA–ICP–MS U–Pb zircon dating, the Derinoba and Kayadibi granites have similar ²⁰⁶Pb/²³⁸U versus ²⁰⁷Pb/²³⁵U Concordia ages of 311.1 ± 2.0 and 317.2 ± 3.5 million years for the former and 303.8 ± 1.5 million years for the latter. Aluminium saturation index values of both granites are between 0.95 and 1.35, indicating dominant peraluminous melt compositions. Both intrusions have high SiO₂ (74–77 wt.%) contents and show high-K calc-alkaline and I- to S-type characteristics. Primitive mantle-normalized element diagrams display enrichment in K, Rb, Th, and U, and depletion in Ba, Nb, Ta, Sr, P, and Ti. Chondrite-normalized rare earth element patterns are characterized by concave-upward shapes and pronounced negative Eu anomalies with La_cn/Yb_cn?=?4.6–9.7 and Eu_cn/Eu*?=?0.11–0.59 (Derinoba), and La_cn/Yb_cn?=?2.7–5.5 and Eu_cn/Eu*?=?0.31–0.37 (Kayadibi). These features imply crystal-melt fractionation of plagioclase and K-feldspar without significant involvement of garnet. The Derinoba samples have initial ?Nd values between –6.1 and –7.1 with Nd model ages and T _DM between 1.56 and 2.15 thousand million years. The Kayadibi samples show higher initial ?Nd_(I) values, –4.5 to –6.2, with Nd model ages between 1.50 and 1.72 thousand million years. This study demonstrates that the Sr isotope ratios generally display negative correlation with Nd isotopes; Sr isotope ratios were lowered in some samples by hydrothermal interaction or alteration. Isotopic and petrological data suggest that both granites were produced by the partial melting of early Palaeozoic lower crustal rocks, with minor contribution from the mantle. Collectively, these rocks represent a late stage of Hercynian magmatism in the eastern Pontides.     

Irregular western margin of the Yangtze block as a cause of variation in tectonic activity along the Longmen Shan fault zone,eastern Tibet

On 12 May 2008 and 20 April 2013, respectively, the devastating magnitude 7.9 (Wenchuan) and magnitude 7.0 (Ya’an) earthquakes struck the southwestern Longmen Shan fault zone (LMSFZ), the eastern margin of the Tibetan Plateau. These events were notable because they occurred in a heavily populated area and resulted in severe damage and loss of life. Here we present an integrated analysis of potential field anomalies and a crustal-scale seismic reflection image to investigate the crustal structure and some tectonic relationships associated with these devastating events. Our results show that the western margin of the Yangtze crustal block possesses an irregular margin that extends westward beyond the LMSFZ to the northeast and merges gradually with the LMSFZ to the southwest. We interpret this variation in deep structure to create a lateral heterogeneity in the local stress regime that explains the observed variations in fault geometry and slip distribution, as well as seismicity, of the LMSFZ. This structural complexity results in a differential build-up of stress as the Tibetan Plateau is being extruded eastward. Thus, the results of this research can help identify potential natural hazard zones and focus efforts on hazard mitigation.