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851.
Fatiha Laoufi Ahmed-Hafid Belbachir Noureddine Benabadji Abdelouahab Zanoun 《Comptes Rendus Geoscience》2011,343(10):653-663
We have mapped the region of Oran, Algeria, using multispectral remote sensing with different resolutions. For the identification of objects on the ground using their spectral signatures, two methods were applied to images from SPOT, LANDSAT, IRS-1 C and ASTER. The first one is called Base Rule method (BR method) and is based on a set of rules that must be met at each pixel in the different bands reflectance calibrated and henceforth it is assigned to a given class. The construction of these rules is based on the spectral profiles of popular classes in the scene studied. The second one is called Spectral Angle Mapper method (SAM method) and is based on the direct calculation of the spectral angle between the target vector representing the spectral profile of the desired class and the pixel vector whose components are numbered accounts in the different bands of the calibrated image reflectance. This new method was performed using PCSATWIN software developed by our own laboratory LAAR. After collecting a library of spectral signatures with multiple libraries, a detailed study of the principles and physical processes that can influence the spectral signature has been conducted. The final goal is to establish the range of variation of a spectral profile of a well-defined class and therefore to get precise bases for spectral rules. From the results we have obtained, we find that the supervised classification of these pixels by BR method derived from spectral signatures reduces the uncertainty associated with identifying objects by enhancing significantly the percentage of correct classification with very distinct classes. 相似文献
852.
Ming‐Yue Hu Xing‐Tao Fan Brigitte Stoll Dmitry Kuzmin Ying Liu Yongsheng Liu Weidong Sun Guang Wang Xiu‐Chun Zhan Klaus Peter Jochum 《Geostandards and Geoanalytical Research》2011,35(2):235-251
Four silicate glasses were prepared by the fusion of about 1 kg powder each of a basalt, syenite, soil and andesite to provide reference materials of natural composition for microanalytical work. These glasses are referred to as ‘Chinese Geological Standard Glasses’ (CGSG) ‐1, ‐2, ‐4 and ‐5. Micro and bulk analyses indicated that the glasses are well homogenised with respect to major and trace elements. Some siderophile/chalcophile elements (e.g., Sn, Pt, Pb) may be heterogeneously distributed in CGSG‐5. This paper provides the first analytical data for the CGSG reference glasses using a variety of analytical techniques (wet chemistry, XRF, EPMA, ICP‐AES, ICP‐MS, LA‐ICP‐MS) performed in nine laboratories. Most data agree within uncertainty limits of the analytical techniques used. Discrepancies in the data for some siderophile/chalcophile elements exist, mainly because of possible heterogeneities of these elements in the glasses and/or analytical problems. From the analytical data, preliminary reference and information values for fifty‐five elements were calculated. The analytical uncertainties [2 relative standard error (RSE)] were estimated to be between about 1% and 20%. 相似文献
853.
Kunchithapadam Gopalan 《Geostandards and Geoanalytical Research》2011,35(2):175-181
Two independent articles published more than a decade ago pointed to the potential of the somewhat neglected K‐Ca system for very precise K‐Ca dating and thermochronology, but have not been followed up since. In the first of these articles, highly precise determination of K and hence the K/Ca ratio in lunar granites showed the feasibility of K‐Ca dates of micas with an analytical precision known so far in only U‐Pb and Ar/Ar dating. In the second article, it was shown that responses of the K‐Ca and Rb‐Sr isotopic systems in micas subjected to a slow post‐metamorphic cooling could provide new insights into thermochronology. Crucial to the follow‐up of these two promising leads is the development of a simple and user‐friendly method for routine high precision K determination in real samples, such as the one described in this report. 相似文献
854.
855.
Akio Makishima Hiroshi Kitagawa Eizo Nakamura 《Geostandards and Geoanalytical Research》2011,35(1):57-67
A method for the simultaneous determination of Cd with In, Tl and Bi by isotope dilution‐internal standardisation (ID‐IS) ICP‐QMS using the same aliquot for rare earth element and other trace element determinations was developed. Samples mixed with an enriched 149Sm spike were decomposed using a HF‐HClO4 mixture, which was evaporated and then diluted with HNO3. After determination of Sm by ID‐ICP‐QMS and Cd, In, Tl and Bi concentrations were determined using the 149Sm intensity as an internal standard. The interference of MoO+ on Cd+ was corrected using the MoO+/Mo+ ratio separately measured using a Mo standard solution, and the validity of the externally determined oxide‐forming ratio correction was evaluated. The MoO+/Mo+ ratios measured using the standard solution and samples were ~ 0.0002 and < 0.002, respectively. Detection limits for Cd, In, Tl and Bi in silicate samples were at levels of < 1 ng g?1 with a total uncertainty of < 7%. Cadmium in the carbonaceous chondrites, Orgueil (CI1), Murchison (CM2) and Allende (CV3) as well as Cd, In, Tl and Bi in the reference materials, JB‐2, JB‐3, JA‐1, JA‐2, JA‐3, JP‐1 (GSJ), BHVO‐1, AGV‐1, PCC‐1 and DTS‐1 (USGS) and NIST SRM 610, 612, 614 and 616 were determined to show the applicability of this method. 相似文献
856.
Hans‐Eike Gäbler Frank Melcher Torsten Graupner Andreas Bahr Maria A. Sitnikova Friedhelm Henjes‐Kunst Thomas Oberthür Helene Brätz Axel Gerdes 《Geostandards and Geoanalytical Research》2011,35(4):431-448
Coltan (the African trade name for columbite‐tantalite, a tantalum ore) is one of several raw materials that finance the civil wars in the eastern provinces of the Democratic Republic of the Congo. To improve the transparency along the tantalum trade chain, a ‘certificate of origin’ for so‐called ‘conflict minerals’ has been recommended by the United Nations. Accordingly, the German Federal Institute for Geosciences and Natural Resources (BGR) has developed an analytical fingerprint procedure for coltan. Mineral formation age, modal mineralogy and chemical composition are important fingerprint parameters. The original workflow to obtain these parameters was streamlined and is now based on mineral liberation analysis and LA‐ICP‐MS. The use of an ICP‐MS instrument with a detector system covering an extended linear dynamic range and the application of an internal standard‐independent calibration strategy allowed data for major and trace element determination and mineral formation age estimates to be obtained simultaneously. The analytical results of this new approach were compared with analytical techniques of the original workflow and showed excellent agreement in terms of mineralogical and chemical characterisation and mineral formation age of coltan samples. Within a test, samples of different origin were allocated correctly and simple, binary mixtures were also identified successfully. 相似文献
857.
The Use of Reference Materials: A Tutorial 总被引:2,自引:1,他引:2
Jean S. Kane 《Geostandards and Geoanalytical Research》2001,25(1):7-22
Any review of the analytical literature shows that, while reference materials are routinely used in laboratories world-wide, not all uses follow ISO Guide 33 (1989), which outlines best practices. Analytical data quality can suffer as a result. This paper reviews the various uses that the geoanalytical community has made of reference materials from a historical perspective, and suggests improvements in practice that would more closely follow ISO Guide 33 recommendations. 相似文献
858.
Geoid heights measured by spatial altimetry must be corrected for systematic bias due to orbital error. This requires the solution of a very large overdetermined and underconstrained system of linear equations. We present a rigorous procedure of solution by successive iterations (block relaxation method) and define its validity on a synthetic example from the Mediterranean area. 相似文献
859.
Ana Casado Borbála Hortobágyi Erwan Roussel 《International journal of geographical information science》2018,32(12):2427-2446
The geometry of impounded surfaces is a key tool to reservoir storage management and projection. Yet topographic data and bathymetric surveys of average-aged reservoirs may be absent for many regions worldwide. This paper examines the potential of contour line interpolation (TOPO) and Structure from Motion (SfM) photogrammetry to reconstruct the topography of existing reservoirs prior to dam closure. The study centres on the Paso de las Piedras reservoir, Argentina, and assesses the accuracy and reliability of TOPO- and SfM- derived digital elevation models (DEMs) using different grid resolutions. All DEMs were of acceptable quality. However, different interpolation techniques produced different types of error, which increased (or decreased) with increasing (or decreasing) grid resolution as a function of their nature, and relative to the terrain complexity. In terms of DEM reliability to reproduce area–elevation relationships, processing-related disagreements between DEMs were markedly influenced by topography. Even though they produce intrinsic errors, it is concluded that both TOPO and SfM techniques hold great potential to reconstruct the bathymetry of existing reservoirs. For areas exhibiting similar terrain complexity, the implementation of one or another technique will depend ultimately on the need for preserving accurate elevation (TOPO) or topographic detail (SfM). 相似文献
860.
Hosna J. Shewly 《Singapore journal of tropical geography》2017,38(1):108-122
Drawing on conceptualization of statelessness and ethnographic research on crucial insights of rightessness, this paper investigates how the politico‐geographic‐legality constructs statelessness in the enclaves in India and Bangladesh. Following the decolonization process in 1947, both India and Pakistan/Bangladesh inherited more than 200 enclaves, which comprise 80 per cent of the world's enclaves. With improved bilateral relations, India and Bangladesh officially exchanged the enclaves on 1 August 2015, and the enclave dwellers will gradually be granted citizenship rights over the next few years. In this period of transition from statelessness to statehood, this paper can be read as contemporary history. This paper will draw attention to three aspects of statelessness. First, conceptualization of statelessness not only applies to the refugeehood or de‐territorialization of people but also relates to the process of constructing transterritorial stateless people. Second, this paper will discuss the condition of statelessness constructed in a politico‐geographic‐legal trap. And finally, the paper calls for a wider empirical and critical focus on the hidden geographies of de facto statelessness. 相似文献