东太平洋Juan de Fuca板块的磁变研究

作为EMSLAB电磁感应国际合作计划的一部分,通过对海底观测的三分量变化地磁场的分析,构制了横跨Juan de Fuca洋脊、Juan de Fuca板块到板块俯冲带的三条地磁转换函数剖面,计算了各个测点的地磁场感应矢量。结果表明,Juan de Fuca板块的东、西两部分的浅部电性结构是有差异的,近海岸线的东区更导电;而深部电性结构是相对均匀的。这一结果与由大地电磁资料计算得到的二维模型剖面是一致的。     

Une Microflore du Barrémien dans la Province de Valencia,Espagne

A Barremian microflora is recorded in the terrigenous facies (Weald) of the Lower Cretaceous in the northern region of the Province of Valencia (Spain), these beds have been poorly dated up to now due to the absence of fossils. The Villar del Arzobispo microflora correspond unquestionably to the Barremian-Aptien period, but the numerical importance of derived forms from the Jurassic, the remarkable variety of forms of Cicatricosisporites, and the rareness of pollen of Angiosperms, indicate a Barremian age to be more likely.This discovery permits us to establish the stratigraphical relationship of this terrigenousfacies of Villar del Arzobispo with the dated “Weald” of other areas of the Iberian Chain and to give a complete chrono-stratigraphical interpretation to the different litho-stratigraphical units that constitute the Lower Cretaceous of this region.     

Origin of Dissolved Groundwater Sulphate in Coastal Plain Sediments of the Rio de la Plata, Eastern Argentina

Groundwater of the coastal plain of the Rio de La Plata, Argentina,contains up to 17 g L^-1 SO₄ and 37 gL^-1 TDS. Some of this SO₄ is from paleo-seawater intrusion; however, SO₄ : Cl ratios can be>2 : 1, and most of the SO₄ must, therefore, have another source. Three possible sources were investigated: gypsum, organic matter,and iron sulphides. Dissolved SO₄ showed δ³⁴S valuesfrom -7 to 0‰, typical values for S from iron sulphides or organicmatter, but distinct from that of seawater (+22‰). To test whetherthe SO₄ was derived from oxidation of reduced S, four 4-mcores were taken from marine sediments of the coastal plain. Two were takenfrom higher, drier areas where the highest dissolved SO₄values were encountered, and two were taken from lower, wetter areas thathad much lower SO₄ concentrations. Pore waterSO₄, Cl and alkalinity were determined; solids were analyzedfor SO₄, sulphide-S and organic-S. Sulphide-S was the dominant form of reduced S, averaging about0.5% S in the lower interval (2.5–4 m) of the cores. Sulphidewas absent in the upper 2.5 m in both topographically higher and lowerareas. Sulphate was present in the entire unit in the higher, drier areas,but almost absent in lower areas. Organic-S was insignificant. Our model for the origin of dissolved SO₄ is: fine-grainedpyrite was oxidized during hotter or drier periods. Some resulting dissolvedSO₄ was precipitated as gypsum. Iron from the pyriteprecipitated as FeOOH. Lower, wetter areas formed over time where recharginggroundwater dissolved most of the gypsum. In higher areas with low hydraulicgradients and high net evapotranspiration, SO₄ remained asgypsum and in the dissolved phase. This revised version was published online in July 2006 with corrections to the Cover Date.     

基于小波变换去除遥感图像非高斯条纹噪音方法探讨

遥感图像的条纹噪音,不但影响图像的判读,而且时图像的后续处理影响较大.利用常规处理软件去噪,在去除条纹的同时,也去除了图像的细节纹理,相当于降低了图像的几何分辨率;使用小波阈值去噪方法,效果欠佳.文章使用小波反阈值方法,不仅去除了图像上的条纹噪音,而且对图像的细节纹理不产生目视效果上的影响,达到了较好的效果.     

Geomorphological evolution of the Tilcara alluvial fan (Jujuy Province, NW Argentina): Tectonic implications and palaeoenvironmental considerations

The development and evolution of the Tilcara alluvial fan, in the Quebrada de Humahuaca (Andean Eastern Cordillera, NW Argentina), has been analysed by using geomorphological mapping techniques, sedimentological characterisation of the deposits and OSL chronological methods. It is a complex segmented alluvial fan made up of five evolutionary stages (units Qf1, Qf2, Qf3, Qf4 and Qf5) developed under arid climatic environments as well as compressive tectonic conditions. Segmentation processes, including aggradation/entrenchment cycles and changes in the location of the depositional lobe, are mainly controlled by climatic and/or tectonic changes as well as channel piracy processes in the drainage system. Alluvial fan deposits include debris flows, sheet flows and braided channel facies associated with high water discharge events in an arid environment. The best mean OSL age estimated for stage Qf2 is 84.5 ± 7 ka BP. In addition, a thrust fault affecting these deposits has been recognized and, as a consequence, the compressive tectonics must date from the Upper Pleistocene in this area of the Andean Eastern Cordillera.     

The Granada ignimbrite: A compound pyroclastic unit and its relationship with Upper Miocene caldera volcanism in the northern Puna

The Granada ignimbrite, an Upper Miocene volcanic unit from the northern Puna, previously has been interpreted as an extensive ignimbrite (>2300 km²) associated with eruptions from the Vilama caldera (trap-door event). On the basis of new data, we revise its correlation and redefine the unit as a compound, high aspect ratio ignimbrite, erupted at approximately 9.8 Ma. Calculated volumes (100 km³) are only moderate in comparison with other large volume (>1000 km³) ignimbrites that erupted approximately 2–6 m.y. later in the region (e.g. Vilama, Panizos, Atana). Six new volcanic units are recognized from sequences previously correlated with Granada (only one sourced from the same center). Consequently, the area ascribed to the Granada ignimbrite is substantially reduced (630 km²), and links to the Vilama caldera are not supported. Transport directions suggest the volcanic source for the Granada ignimbrite corresponds to vents buried under younger (7.9–5 Ma) volcanic rocks of the Abra Granada volcanic complex. Episodes of caldera collapse at some stage of eruption are likely, though their nature and timing cannot be defined from available data. The eruption of the Granada ignimbrite marks the onset of a phase of large volume (caldera-sourced) volcanism in the northern Puna.     

滇桂边境地区跨境婚姻的现状、特征与原因

利用宏观县区政府统计资料和定性个案访谈资料,对滇桂边境地区跨境通婚进行调查分析,结果发现：滇桂边境地区跨境通婚数量在不断增长,地理通婚圈由边境向内地延伸,通婚辐射范围越来越广,一部分跨境婚姻即将演变为内地跨国婚姻;婚入人口性别结构严重失衡,边境国家女性嫁入中国的数量远远多于中国边境女性嫁到邻国;跨境婚姻中夫妇双方整体教育文化素质偏低,多以小学和初中为主,呈现出教育资源的弱弱结合;跨境通婚的结婚登记率较低,大多以“事实婚姻”的方式在中国组成家庭,并且这些家庭早婚多育现象比较严重,不利于中国计划生育的有序执行;夫妇年龄差偏大以及跨境通婚具有代际传承等特征。进一步分析发现：导致滇桂边境地区的跨境通婚不断增长的原因与地理空间的邻近性、跨境民族文化圈子的同源性、等级通婚圈的封闭性、边境邻国→中国边境→中国内地的二级经济阶梯推动性、中越两国人口性别结构的互补性、不同国家婚姻制度“错位性”和边境地区政治形势的不稳定性存在密切的关系。     

Secondary Ion Mass Spectrometry Bias on Isotope Ratios in Dolomite–Ankerite,Part I: δ18O Matrix Effects

We document the development of a suite of carbonate mineral reference materials for calibrating SIMS determinations of δ¹⁸O in samples with compositions along the dolomite–ankerite solid solution series [CaMg(CO₃)₂–CaFe(CO₃)₂]. Under routine operating conditions for the analysis of carbonates for δ¹⁸O with a CAMECA IMS 1280 instrument (at WiscSIMS, University of Wisconsin‐Madison), the magnitude of instrumental bias along the dolomite–ankerite series decreased exponentially by ~ 10‰ with increasing Fe content in the dolomite structure, but appeared insensitive to minor Mn substitution [< 2.6 mol% Mn/(Ca+Mg+Fe+Mn)]. The compositional dependence of bias (i.e., the sample matrix effect) was calibrated using the Hill equation, which relates bias to the Fe# of dolomite–ankerite [i.e., molar Fe/(Mg+Fe)] for thirteen reference materials (Fe# = 0.004–0.789); for calibrations employing either 10 or 3 μm diameter spot size measurements, this yielded residual values ≤ 0.3–0.4‰ relative to CRM NBS 19 for most reference materials in the suite. Analytical precision was ± 0.3‰ (2s, standard deviations) for 10‐μm spots and ± 0.7‰ (2s) for 3‐μm spots, based on the spot‐to‐spot repeatability of a drift monitor material that ‘bracketed’ each set of ten sample‐spot analyses. Analytical uncertainty for individual sample analyses was approximated by a combination of precision and calibration residual values (propagated in quadrature), suggesting an uncertainty of ± 0.5‰ (2s) for 10‐μm spots and ± 1‰ (2s) for 3‐μm spots.     

Determination of Platinum‐Group Elements in Geological Samples by Isotope Dilution‐Inductively Coupled Plasma‐Mass Spectrometry Combined with Sulfide Fire Assay Preconcentration

A method was developed for the determination of platinum‐group elements (PGE) in geological samples by isotope dilution‐inductively coupled plasma‐mass spectrometry combined with sulfide fire assay preconcentration. Samples were fused and PGE analytes were concentrated in sulfide buttons. The buttons were dissolved using HCl leaving PGE analytes in insoluble residues, which were digested in HNO₃ and simultaneously processed for the distillation of Os. The remaining solutions were further prepared for the purification of Ru, Rh, Pd, Ir and Pt using a tandem assembly of cation and Ln resin columns. The eluents were directly analysed by membrane desolvation‐ICP‐MS. Ruthenium, Pd, Os, Ir and Pt were determined by isotope dilution, whereas Rh was determined by conventional reference material calibration combined with ¹⁹³Ir as the internal standard element. The method was validated using a series of PGE reference materials, and the measurement data were consistent with the recommended and the literature values. The measurement precision was better than 10% RSD. The procedural blanks were 0.121 ng for Ru, 0.204 for Rh, 0.960 ng for Pd, 0.111 ng for Os, 0.045 ng for Ir and 0.661 ng for Pt, and the limits of detection (3s) were 0.011 ng g^?1 for Ru, 0.008 ng g^?1 for Rh, 0.045 ng g^?1 for Pd, 0.009 ng g^?1 for Os, 0.006 ng g^?1 for Ir and 0.016 ng g^?1 for Pt when a test portion mass of 10 g was used. This indicates that the proposed method can be used for the determination of trace amounts of PGE in geological samples.     

Zinc Isotopic Compositions of NIST SRM 683 and Whole‐Rock Reference Materials

In this study the homogeneity of the zinc isotopic composition in the NIST SRM 683 reference material was examined by measuring the Zn isotopic signature in microdrilled sample powders from two metal nuggets. Zinc was purified using AG MP‐1M resin and then measured by MC‐ICP‐MS. Instrumental mass bias was corrected using the “sample‐standard bracketing” method and empirical external normalisation with Cu doping. After evaluating the potential effects of varying acid mass fractions and different matrices, high‐precision Zn isotope data were obtained with an intermediate measurement precision better than ± 0.05‰ (δ⁶⁶Zn, 2s) over a period of 5 months. The δ⁶⁶Zn_JMC‐Lyon mean values of eighty‐four and fourteen drilled powders from two nuggets were 0.11 ± 0.02‰ and 0.12 ± 0.02‰, respectively, indicating that NIST SRM 683 is a good isotopic reference material with homogeneous Zn isotopes. The Zn isotopic compositions of seventeen rock reference materials were also determined, and their δ⁶⁶Zn values were in agreement with most previously published data within 2s. The δ⁶⁶Zn values of most of the rock reference materials analysed were in the range 0.22–0.36‰, except for GSP‐2 (1.07 ± 0.06‰, n = 12), NOD‐A‐1 (0.96 ± 0.03‰, n = 6) and NOD‐P‐1 (0.78 ± 0.03‰, n = 6). These comprehensive data should serve as reference values for quality assurance and interlaboratory calibration exercises.