Variabilité spatiale du signal palynologique dans le bassin de Paris à la limite Dogger–Malm

The drilling of new cores performed for ANDRA in eastern France allowed us to compare palynological data between central and eastern parts of the Paris Basin. Such a comparison, which was also motivated by the existence of a set of geochemical data in contradiction with the first palynological results, showed a spatial differentiation in palynological record from the Oxfordian. Such a palynological signal could result from overlapping of both local and global signals, the latter being in connection with the contemporaneous opening of proto-Atlantic Ocean. It could also be of major palaeogeographic and palaeoclimatic interest. To cite this article: V. Huault et al., C. R. Geoscience 335 (2003).     

Uppermost Tortonian to Quaternary depocentre migration related with segmentation of the strike-slip Palomares Fault Zone,Vera Basin (SE Spain)

The Palomares Fault Zone (PFZ) is one of the main strike-slip brittle shear zones found in the Betics. It is segmented in several faults that have been active between the Upper Tortonian and present day. Data from drill cores in the Palomares area have permitted us to define the geometry and location of sedimentary depocentres related with the PFZ. These data show an eastward displacement between the Upper Tortonian to Messinian and the Pliocene–Quaternary sedimentary depocentres, towards the presently active Arteal fault, which bounds the western mountain front of Sierra Almagrera, showing that deformation along this fault zone has migrated towards the east, from the Palomares segment, with its main activity during the Upper Tortonian and Messinian, towards the Arteal fault, active during the Pliocene and Quaternary. To cite this article: G. Booth-Rea et al., C. R. Geoscience 335 (2003).     

L'évolution séculaire des températures de surface de la mer Méditerranée (1856–2000)

The mean sea surface temperature anomalies (SSTA) of the Mediterranean Sea during the past 150 years (1856–2000) are analysed. The first empirical orthogonal function (EOF) of the covariance matrix of the SSTA explains more than 45% of the variance, suggesting that the temporal variation of the Mediterranean Sea is largely in phase over the whole basin. The mean variability of Mediterranean SSTA from 1856 to 2000 superposes a main irregular oscillation (period of 60–70 years and mean amplitude of 0.4–0.5 °C) and a weak long-term positive trend (equivalent to an increase of +0.1 °C per century). The last warm phase, which is strongest in the western basin, is not warmer than the decade 1935–1945 or the ending part of the 1960s. The mean temporal evolution of the North Hemisphere is close to the variation of the Mediterranean Sea, except that the long-term increase is more intense in the North Hemisphere. To cite this article: V. Moron, C. R. Geoscience 335 (2003).     

Étude gravimétrique de la ceinture archéenne de roches vertes de Kuhmo (Finlande orientale)

The Kuhmo greenstone belt (Eastern Finland) is mainly formed by mafic volcanic rocks and metasediments. Although the geological observations indicate that this belt appears as a supracrustal synform overlying a gneissic basement, its deep structures are actually unknown. The present gravity study intends to provide a better understanding of these structures. Interpretation of gravity anomalies of the Kuhmo belt, using two-dimensional modelling suggests that the structures of the belt are controlled by granitoids diapirs. Most of the calculated models show that the belt displays in section pocket-like shapes (purses) terminated by a gully-shape close to the surface. This particular geometry corroborates the hypothesis of a gravitational formation with the heavy volcanic material sinking in a light sialic crust. To cite this article: M. Jaffal et al., C. R. Geoscience 335 (2003).     

Understanding solubilisation using principles of surfactant self-assembly as geometrical constraintsCompréhension de la solubilisation par utilisation des principes d'auto-association des tensioactifs à partir des contraintes géometriques

Our aim is to give a short introduction of the use of phase diagrams in order to rationalise general principles of surfactant self-assembly. These can be rationalised in terms of geometrical constraints: volume, surface and curvature. Binary (two components: surfactant and water) and ternary systems (surfactants, water, oil) are considered separately. Models for solubilisation, to be understood within the general principles and not as tabulated data, are presented. Finally, some examples of application of solubilisation in formulation are given. To cite this article: F. Testard, T. Zemb, C. R. Geoscience 334 (2002) 649–663.     

Les rhyolites hyperalcalines (pantellérites) du lac Tchad. Composition et signification tectonomagmatiqueThe peralkaline rhyolites (pantellerites) of the Lake Chad. Composition and tectonomagmatic significance

Remnants of rhyolite lava-dome and of alkaline microgranite extrusions emerge, as inselbergs, in the alluvial plain, south of Lake Chad. The peralkaline, arfvedsonite- and acmite-bearing rhyolites are determined as pantellerites. They can be related to a tectonomagmatic stage, dated of the Late Cretaceous, of the western central Africa rift system. They may constitute the NNE extension of a N50° to 30° elongated succession of small alkaline complexes, from the Gulf of Guinea to the North-Cameroon, which initiated the magmatic activity of the Cameroon Line. To cite this article: J.-P. Vicat et al., C. R. Geoscience 334 (2002) 885–891.     

Contribution des réseaux de neurones artificiels (RNA) à la caractérisation des pollutions de sol. Exemples des pollutions en hydrocarbures aromatiques polycycliques (HAP)Artificial Neural Networks (ANNs) characterisation of soil pollution: the Polycyclic Aromatic Hydrocarbons (PAHs) case study

We develop the ANNs (Artificial Neural Networks) method to explore contaminant concentration profiles observed in soils of polluted sites. ANNs are particularly efficient in simultaneous analysis of numerous parameters and in identification of complex relations involving field data. Applying the ANN models on a PAH (Polycyclic Aromatic Hydrocarbon) database, we extracted the most characteristic components of known contaminations and applied it to identify the source type of similar polluted sites. The performed tests prove the generalisation capability of the selected ANN model. To cite this article: A. Dan et al., C. R. Geoscience 334 (2002) 957–965.     

Ground Motion Zoning of Santiago de Cuba: An Approach by SH Waves Modelling

— The expected ground motion in Santiago de Cuba basin from earthquakes which occurred in the Oriente fault zone is studied. Synthetic SH-waves seismograms have been calculated along four profiles in the basin by the hybrid approach (modal summation for the path source-profile and finite differences for the profile) for a maximum frequency of 1 Hz. The response spectra ratio (RSR) has been determined in 49 sites, distributed along all considered profiles with a spacing of 900 m. The corresponding RSR versus frequency curves have been classified using a logical-combinatorial algorithm. The results of the classification, in combination with the uppermost geological setting (geotechnical information and geological geometry of the subsoil) are used for the seismic zoning of the city. Three different main zones are identified, and a small sector characterized by major resonance effects, due to the particular structural conditions. Each zone is characterized in terms of its expected ground motion parameters for the most probable strong earthquake (M_S=7), and for the maximum possible (M_S=8).     

Skarn textures and a case study: the Ocna de Fier-Dognecea orefield, Banat, Romania

We address the question of the predictability of skarn textures and their role in understanding the evolution of a skarn system. Recent models of skarn formation show that skarns are ideal for application of self-organisation theory, with self-patterning the rule in fluid-rock interaction systems rather than the exception. Zonation in skarn deposits, a consequence of infiltration-driven metasomatism, can also be treated in terms of self-organisation. Other less commonly described features, such as scalloping, fingering and mineral banding, can be understood by application of reactive infiltration and hydrodynamics at the skarn front. Devolatilisation may trigger formation of back-flow fluxes that overprint previously formed skarn. The range of textures formed from such events can be used to discriminate between prograde and retrograde stages. Refractory minerals, such as garnet, magnetite and pyrite, readily retain overprinting events. Skarns are also composed largely of minerals from solid solution series (garnet, pyroxene, pyroxenoids, etc.) and therefore skarn mineralogy helps to establish trends of zonation and evolution. The same minerals can act as ‘chemical oscillators’ and record metasomatic trends.The Ocna de Fier-Dognecea deposit was formed in a 10 km deep skarn system. Zonation and evolution trends therefore represent only the result of interaction between magmatically derived fluids emerging at the source and limestone. From the same reason, the transition from prograde to retrograde regime is not influenced by interaction with external fluids. Thirdly, the mineralisation comprises Fe, Cu and Zn-Pb ores, thus facilitating comparison with skarn deposits that commonly are formed in shallower magmatic-hydrothermal environment. Copper-iron ores (magnetite+Cu-Fe sulphides), hosted by magnesian (forsterite+diopside) skarn, occur in the deepest and central part of the orefield, at Simon Iuda. Their petrological character allows interpretation as the core of the skarn system formed from a unique source of fluids emerging from the subjacent granodiorite. It formed first as a consequence of the local setting, where a limestone indented in the granodiorite permitted strong reaction at 650 °C and focussed the up-streaming, buoyant fluids. The first sharp front of reaction is seen at the boundary between the Cu-Fe core and Fe ores hosted by calcic skarn (Di_70-90-And_70-90), where Cu-Fe sulphides disappear, and forsterite gives way to garnet in the presence of diopside (Di₉₀). Following formation of forsterite, devolatilisation and transient plume collapse is interpreted from a range of piercing clusters and trails. We presume lateral flow to have been initiated at the source, as the emerging fluids are in excess to the fluids driven into reaction by the plume. Formation of the other orebodies, up to 5 km laterally downstream in both directions, is interpreted as skarn fingering at the limestone side. The metasomatic front is perpendicular to the flow along the channel of schists placed between the limestone base and the granodiorite.A metal zonation centred onto the source is defined, based on metal distribution: Cu-Fe/Fe/Zn-Pb. The second front of reaction, at the boundary between the Fe and Zn-Pb zone, has a sulphidation/oxidation character, with diopside giving way to a Fe-Mn-rich pyroxene, (HedJoh)_>60+pyroxmangite±bustamite; garnet is minor. Johannsenite-rich pyroxene (Di_20-40Hed_20-40Joh₄₀) is found in proximal skarn at the upper part of Simon Iuda, stable with Zn_0.95Fe_0.05S, at an inferred 570 °C. In distal skarn from Dognecea and Paulus, Mn-hedenbergite (Di_<10Hed₇₀Joh_20-30) formed at 400 °C is stable with Zn_0.84Fe_0.16S. Extensive compositional fields, eutectic decomposition and lamellar intergrowths characterise pyroxene in the Zn-Pb zone, formed at the magnetite-hematite buffer in the presence of pyrite. Distal skarn has a reducing character, in comparison with the proximal. A drop in both fS₂ and O₂, with the zoned system moving closer to the pyrite-pyrrhotite buffer, is induced from the temperature gradient. Based on pyroxene mineralogy and calculated fS₂, the metal zonation is confirmed as being formed upwards and outwards from the source.The Fe and Zn-Pb zones both have a patterned side coexisting with the unpatterned one. Patterning is seen at scales from macroscopic (rhythmic banding, nodular, spotted, orbicular, mossy, mottled textures) to microscopic scales (oscillatory zonation in garnet and silica-bearing magnetite). Following plume updraft, the path of decarbonation reaction controlled the motion of the skarn front until, towards the end of the prograde stage, a multiple steady state regime developed and produced rhythmic patterns on all scales. The activation of powerful patterning operators, represented by Liesegang banding alone, or coupled with competitive particle growth, show that the skarn front had the characteristics of an unstable coarsening front of reaction.A second retrograde event, carbofracturing, triggered by erratic decarbonation after cessation of infiltration, can be interpreted from overprinting textures in the Fe and Zn-Pb zone. A major drop in fO₂ is inferred from extensive, pseudomorphous replacement of hematite by magnetite. Textures show progressive destruction of prograde assemblages, i.e., piercing clusters, shock-induced, fluid-pressure assisted brecciation and deformation, followed by healing of the disrupted assemblages. Release of trace elements accompanies both retrograde events, with a Bi-Te-Au-Ag association common to both. The importance of shock-induced textures is emphasised in the context of Au enrichment, especially when the retrograde fluids cross the main buffers in fO₂-fS₂ space.The presence of Bi-sulphosalt polysomes in the Fe zone indicates that patterning extends down to the nanoscale. The key role played by polysomatism in stabilising compositional trends that cannot otherwise be formed at equilibrium is a fertile ground yet to be adequately explored.