Temperature dependence of large-scale water-retention curves: a case study

A local-scale model for temperature-dependence of water-retention curves may be applicable to large scales. Consideration of this temperature dependence is important for modeling unsaturated flow and transport in the subsurface in numerous cases. Although significant progress has been made in understanding and modeling this temperature effect, almost all the previous studies have been limited to small scales (on the order of several centimeters). Numerical experiments were used to investigate the possibility of extending a local-scale model for the temperature-dependence of water retention curves to large scales (on the order of meters). Temperature effects on large-scale hydraulic properties are of interest in many practical applications. Numerical experiment results indicate that the local-scale model can indeed be applicable to large-scale problems for special porous media with high air entry values. A typical porous medium of this kind is the porous tuff matrix in the unsaturated zone of Yucca Mountain, Nevada, the proposed geologic disposal site for national high-level nuclear wastes. Whether this finding can approximately hold for general cases needs to be investigated in future studies.     

Initiation and development of pull-apart basins with Riedel shear mechanism: insights from scaled clay experiments

Typical pull-apart structures were created in scaled clay experiments with a pure strike-slip geometry (Riedel type experiments). A clay slab represents the sedimentary cover above a strike-slip fault in the rigid basement. At an early stage of the development of the deformation zone, synthetic shear fractures (Riedel shears) within the clay slab display dilatational behaviour. With increasing basal displacement the Riedel shears rotate and open further, developing into long, narrow and deep troughs. The shear displacement and the low angle with the prescribed principal basal fault set them apart from tension gashes. At a more evolved stage, synthetic segments (Y-shears) parallel to the basal principal fault develop and accommodate progressive strike-slip deformation. The Y-shears connect the tips of adjacent troughs developed from the earlier Riedel shears, resulting in the typical rhomb-shaped structures characteristic for pull-apart basins. The Strait of Sicily rift zone, with major strike-slip systems being active from the Miocene to the Present, comprises pull-apart basins at different length scales, for which the structural record suggests development by a mechanism similar to that observed in our experiments.     

Formation of iron-containing colloids by the weathering of phyllite

The formation of colloids during the weathering of phyllite was investigated by exposing ground phyllite to Milli-Q water. Secondary mineral colloids of 10¹–10² nm were detected in significant concentrations. At pH of about 8.5, the solution concentration of these colloids reached up to 10 mg/L (however, acidification to pH 4.0 prevented the formation of the colloids). The mineralogical composition of the secondary mineral colloids is assumed to be a mixture of ferrihydrite, manganese oxyhydroxides, aluminosilicates, amorphous Al(OH)₃ and gibbsite with possible additions of iron silicates and␣iron-alumino silicates. The colloids were stable over longer periods of time (at least several weeks), even in the presence of suspended ground rock. Direct formation of iron-containing secondary mineral colloids at the rock–water interface by the weathering of rock material is an alternative to the well-known mechanism of iron colloid formation in the bulk of water bodies by mixing of different waters or by aeration of anoxic waters. This direct mechanism is of relevance for colloid production during the weathering of freshly crushed rock in the unsaturated zone as for instance crushed rock in mine waste rock piles. Colloids produced by this mechanism, too, can influence the transport of contaminants such as actinides because these colloids have a large specific surface area and a high sorption affinity.     

Deformability characteristics of brazilian laterites

This paper summarizes the resilient and permanent deformation characteristics of laterite gravels, determined by cyclic loading in triaxial tests of compacted specimens. A study of laterite pavements was carried out on eight paved road sections in the state of Mato Grosso. Also reported is the influence of fine sand admixture, specimen size and soaking in two laterite samples from Roraima and Rondônia in the North of Brazil. The experimental relationships of resilient moduli against applied stresses are interpreted empirically for models what may be incorporated in a structural analysis of full depth of laterite pavement.     

采矿引起的边坡倾倒滑移变形机理与变形安全性分析研究—以抚顺西露天矿边坡为例

在矿山开发、水电建设过程中倾倒变形问题日渐突出。倾倒变形边坡一般具有反倾边坡结构,变形的过程和机理比较复杂、涉及的变形岩体范围较大、危害严重。论文以抚顺西露天矿边坡为例,通过岩体位移监测资料的跟踪分析、底面摩擦模拟试验,以岩体力学、松散介质力学原理为理论基础,探讨了采矿影响下边坡倾倒滑移体的变形机理,分析认为采矿引起的倾倒滑移变形问题是在特定的地质构造和采矿工程条件下产生的,并提出了岩体变形安全性分析方法。通过工程实例,验证了方法的实用性,并针对实际问题提出了变形整治对策。     

Synchrotron IR study of hydrous ringwoodite (γ-Mg2SiO4) up to 30 GPa

High-pressure synchrotron infrared (IR) absorption spectra were collected between 650 and 4,000 cm⁻¹ at ambient temperature for hydrous Mg-ringwoodite (γ-Mg₂SiO₄) up to 30 GPa. The main feature in the OH⁻ stretching region is an extremely broad band centred at 3,150 cm⁻¹. The hydrogen bond is strong for most protons and the most probable site for protonation is the tetrahedral edge. With increasing pressure, this band shifts downward while decreasing its integrated intensity until disappearance at a pressure of 25 GPa. Only one band at 2,450 cm⁻¹ and an absorption plateau persist with a maximum wavenumber of 3,800 cm⁻¹. This behaviour is reversible upon pressure release. We interpret this as a second-order phase transition occurring in hydrated Mg-ringwoodite at high pressure (beyond ∼ 25 GPa). This result is compatible with the observation by Kleppe et al. (Phys Chem Miner 29:473–476, 2002a) who suggested the presence of Si–O–Si linkages and/or partial increase in the coordination of Si. Beyond the phase transition, the protons are delocalized and their environment on the ringwoodite structure is probably quite different from that at low pressure. Data obtained in situ at high pressures and temperatures are needed to better understand the effect of protonation on the structure and to better constrain this phase transition.     

Faulted backfold versus reactivated backthrust: the role of inherited structures during late extension in the frontal Piémont nappes east of Pelvoux (Western Alps)

In the central part of the internal Western Alps, widespread multidirectional normal faulting resulted in an orogen-scale radial extension during the Neogene. We revisit the frontal Piémont units, between Doire and Ubaye, where contrasting lithologies allow analysing the interference with the N–S trending Oligocene compressive structures. A major extensional structure is the orogen-perpendicular Chenaillet graben, whose development was guided by an E–W trending transfer fault zone between the Chaberton backfold to the north and the Rochebrune backthrust to the south. The Chaberton hinge zone was passively crosscut by planar normal faults, resulting in a E–W trending step-type structure. Within the Rochebrune nappe, E–W trending listric normal faults bound tilted blocks that slipped northward along the basal backthrust surface reactivated as an extensional detachment. Gravity-driven gliding is suggested by the general northward tilting of the structure in relation with the collapse of the Chenaillet graben. The stress tensors computed from brittle deformation analysis confirm the predominance of orogen-parallel extension in the entire frontal Piémont zone. This can be compared with the nearby Briançonnnais nappe stack where the extensional reactivation of thrust surfaces locally resulted in prominent orogen-perpendicular extension. Such a contrasting situation illustrates how the main direction of the late-Alpine extension may be regionally governed by the nature and orientation of the pre-existing structures inherited from the main collision stage.