An experimental study of the grain-scale processes of peridotite melting: implications for major and trace element distribution during equilibrium and disequilibrium melting

The grain-scale processes of peridotite melting were examined at 1,340°C and 1.5 GPa using reaction couples formed by juxtaposing pre-synthesized clinopyroxenite against pre-synthesized orthopyroxenite or harzburgite in graphite and platinum-lined molybdenum capsules. Reaction between the clinopyroxene and orthopyroxene-rich aggregates produces a melt-enriched, orthopyroxene-free, olivine + clinopyroxene reactive boundary layer. Major and trace element abundance in clinopyroxene vary systematically across the reactive boundary layer with compositional trends similar to the published clinopyroxene core-to-rim compositional variations in the bulk lherzolite partial melting studies conducted at similar P–T conditions. The growth of the reactive boundary layer takes place at the expense of the orthopyroxenite or harzburgite and is consistent with grain-scale processes that involve dissolution, precipitation, reprecipitation, and diffusive exchange between the interstitial melt and surrounding crystals. An important consequence of dissolution–reprecipitation during crystal-melt interaction is the dramatic decrease in diffusive reequilibration time between coexisting minerals and melt. This effect is especially important for high charged, slow diffusing cations during peridotite melting and melt-rock reaction. Apparent clinopyroxene-melt partition coefficients for REE, Sr, Y, Ti, and Zr, measured from reprecipitated clinopyroxene and coexisting melt in the reactive boundary layer, approach their equilibrium values reported in the literature. Disequilibrium melting models based on volume diffusion in solid limited mechanism are likely to significantly underestimate the rates at which major and trace elements in residual minerals reequilibrate with their surrounding melt. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

基于群桩基础沉降估算确定压缩层厚度的探讨

在现行规范中,由于桩基沉降估算模式的不同,压缩层厚度的确定方法也不完全相同。对这些方法进行归纳、总结,并通过具体的工程实例,对由不同估算模式确定的压缩层厚度及沉降估算结果进行探讨与分析,认为对于工程场地地质资料掌握较为翔实的情况下,压缩层厚度可采用变形比法确定,否则,宜根据应力比法确定。     

川西前陆盆地中—新生代沉积迁移与构造转换

川西前陆盆地中—新生代各构造层的残余厚度展布和沉积特征分析发现,四川克拉通周缘的前陆盆地在晚三叠世时期发育于龙门山山前,明显属于龙门山褶皱逆冲构造载荷所形成的前渊凹陷;侏罗纪早期的沉积地层呈面状分布,没有表现出显著的挠曲沉降,指示了一个构造相对平静的阶段;中侏罗世早期前渊凹陷迁移至龙门山北段和米仓山山前,前渊沉积从晚三叠世的北东向转换为近东西向,广泛的湖泊相沉积预示了前陆盆地的欠充填状态;中侏罗世中晚期,川西盆地沉降中心又迁移到大巴山山前,相应的挠曲变形又从近东西向转化为北西向,构成了大巴山的前渊凹陷;晚侏罗世—早白垩世时期,沉降中心再次回到米仓山山前,巨厚的前渊凹陷沉积指示了米仓山冲断带的主要活动时期;白垩纪末—古近纪的前渊凹陷则跃迁至雅安—名山地区。川西前陆盆地的同造山沉降中心以四川盆地中心为核心在西部和北部呈弧形迁移,沉积序列不断更替和叠加。中生界各构造层底界构造图显示现今的构造低部位位于川西北地区和川西南地区,在川西北地区均有东西走向的等值线分布,而川西南地区等值线走向则为北东-南西向。因此分析认为,晚侏罗世至早白垩世的构造变形可能控制了川西盆地现今的地层变形,形成了川西北地区的南北向构造挤压结构,而晚期的新生代构造变形则主要体现在川西盆地的西南部,形成北东-南西向的地层展布特征。     

东菲律宾海深水铁锰结壳发育站位沉积物的粒度及黏土矿物学特征

大洋铁锰结壳是潜在的重要海洋资源,多年来世界各国对此已作了大量调查.传统意义上的铁锰结壳均分布于3000m水深以浅的海山基岩上.中国科学院海洋研究所在对东菲律宾海的地质调查中采集到大量褐黑色深水铁锰结壳.在300多个站位的取样中,在44个站位采集到结壳样品,可见结壳在研究区的分布较为广泛.该结壳发育于4000~5000m水深的致密至半固结沉积物的表层,厚度一般为2~3cm,最厚可达7cm.结壳为板(层)状.     

南海沉积岩芯的地球化学研究

本文对南海中部陆坡区和海盆区的5个岩芯中的 Si,Al,Fe,Mn,Ca,Mg 和 CaCO_3成分做了分析,并对其分布特征与有关影响因素进行了讨论。受沉积区环境差异的影响,元素的分布具有区域性特征;受海区特定地理位置的影响,元素的分布呈现出过渡性特征(浅海到大洋的过渡);受沉积过程中环境变化的影响,元素的分布展示了周期性变化或旋回性。根据岩芯中元素的分布特征,并参考有关古地磁,氧碳同位素和钙质超微化石的测试分析结果,将本区岩芯划分为14层地球化学层,并将本区划分为两个沉积地球化学区,揭示了早更新世以来本区沉积环境的变化和存在的两种沉积模式。     

中太平洋铁锰结壳铅同位素研究

已有研究表明大洋中溶解的铅(Pb)来源于陆源物质，但是，对Pb进入大洋的途径争议很大。为此分析了取自中太平洋两块铁锰结壳样品的Pb同位素组成，获得了整个新生代的中太平洋Pb同位素演化历史。结果表明这两块结壳的Pb同位素随时间的演化曲线与中北太平洋沉积物岩心LL44-GPC3中风成碎屑的Pb同位素演化曲线相似。证实该区深水中的天然溶解铅主要来自风成粉尘，并且50Ma之前中太平洋中溶解Pb同位素组成主要取决于源自美洲的风成粉尘的输入，40Ma之后主要取决于源自亚洲的风成粉尘的输入。     

Relationship between Salinity and Nutrients in the Subsurface Layer in the Suruga Bay

We investigated the water structure and nutrient distribution in the Suruga Bay from April 2000 to July 2002, especially the Offshore Water, which occupies a large part of the bay. The maximum salinity in the upper 200 m varied between 34.49 and 34.71, indicating a temporal change in the influence of Kuroshio Water on the Offshore Water. Seasonal variation in nutrient concentrations was largest from surface to 50 m. On the other hand, the variance in nutrient concentrations within each season was largest in the subsurface layer of 100–300 m in spring, summer and fall. In the Offshore Water, the change of nutrients was negatively correlated with that of salinity in each season. This suggests that an increasing intrusion of saline water brings about a lower nutrient concentration in the Offshore Water. Likewise, negative correlations were observed between the change of the maximum salinity and chlorophyll a (Δ [chl.a-int])/nutrients integrated in the upper 200 m. Δ[chl.a-int] was significantly correlated with the changes of nitrate and phosphorus, but there were no significant correlations between Δ[chl.a-int] and the change of silicate. These results suggest that the concentrations of chlorophyll a and nutrients in the Offshore Water were decreased due to the increasing intrusion of Kuroshio Water. The Offshore Water is likely to be related to the regulation of primary production by nitrate.     

Geophysical Evidence of a Relict Oceanic Crust in the Southwestern Scotia Sea

The southwestern part of the Scotia Sea, at the corner of the Shackleton Fracture Zone with the South Scotia Ridge has been investigated, combining marine magnetic profiles, multichannel seismic reflection data, and satellite-derived gravity anomaly data. From the integrated analysis of data, we identified the presence of the oldest part of the crust in this sector, which tentative age is older than anomaly C10 (28.7 Ma). The area is surrounded by structural features clearly imaged by seismic data, which correspond to gravity lows in the satellite-derived map, and presents a rhomboid-shaped geometry. Along its southern boundary, structural features related to convergence and possible incipient subduction beneath the continental South Scotia Ridge have been evidenced from the seismic profile. We interpret this area, now located at the edge of the south-western Scotia Sea, as a relict of ocean-like crust formed during an earlier, possibly diffuse and disorganized episode of spreading at the first onset of the Drake Passage opening. The successive episode of organized seafloor spreading responsible for the opening of the Drake Passage that definitively separated southern South America from the Antarctic Peninsula, instigated ridge-push forces that can account for the subduction-related structures found along the western part of the South Scotia Ridge. This seafloor accretion phase occurred from 27 to about 10 Ma, when spreading stopped in the western Scotia Sea Ridge, as resulted from the identification of the marine magnetic anomalies.     

使用水块混合层模式模拟上层海洋的季节变化

使用块体混合层模式对一个固定海洋观测站所测的上层海洋之物理特性进行了模拟，结果发现了难以重复观测到的许多物理特征。文章提出了水块混合层模式，着重模拟了扩展湾流体系（ＥＧＳＳ）中的一个水块，在它被海流从佛罗里达海峡（２４°Ｎ，８０°Ｗ）带到挪威海（６８°Ｎ，１０°Ｅ）的过程中，其物理特性（其中包括温度、盐度、混合层深度和夹卷速度）随时间的变化。模拟结果较好地再现了所观测的物理特性的演化。     

季节内SST和混合层深度变化的模式研究

用Niiler—Kraus类型的混合层积分模式,对TOGA—COARE强化观测期间由《实验3号》科学考察船观测资料得到的混合层深度和SST在季节内时间尺度的变化进行了模式研究。指出:1.混合层耗散参数与较长时间尺度过程风应力的变化存在着比较好的对应关系;2.模式可以较好的对风场和热通量场在季节内时间尺度的变化作出响应,模拟出季节内时间尺度SST的变化;3.Niiler,-Kraus模式在考虑耗散作用后,可用于海洋季节内时间尺度变化的模式研究。