垦71区块井间地震资料处理研究与应用

由于避开了地表低降速带和风化层的影响,井间地震能够采集到高频地震信号,经过资料处理可以得到较高分辨率的速度和上行反射波成像剖面。2004～2005年,胜利油田在垦71 区块实施了8对井间地震资料采集。针对原始资料特点,研究了以层析成像、管波衰减、VSP-CDP技术和有限角度叠加成像等关键处理技术,较好地完成了该区块的井间地震资料处理。初步分析解释表明,井间地震可以识别低序级断层、小幅度构造和薄储层。     

Treatment of high fluoride concentration wastewater by layered double hydroxides： Mechanism studies

An appropriate concentration of fluoride in drinking water is required to prevent dental cavities, but long-term ingestion of water that contains more than a suitable level of fluoride can cause bone disease and mottling of the teeth. Fluoride ions can be found in wastewater from the fluoride chemical industry, as well as the semiconductor, metal processing, fertilizer, and glass-manufacturing industries. The discharge standard for fluoride in industrial wastewater in China is 10 mg/L. Efficient treatment of fluoride-containing wastewater is therefore of major concern in China, following the rapid development of the fluoride chemical industry. Several methods have been used to remove fluoride from water, such as adsorption, chemical precipitation, electrodialysis, ion exchange and electrochemical processes. Layered double hydroxides （LDHs） are anionic clays with high anion exchange capacities which are effective adsorbents for removal of a variety of anionic pollutants. LDHs have been studied as potential adsorbents for removing toxic anionic species such as CrO4^2-, TcO4^-, SeO3^2-, pesticides, and anionic surfactants from aqueous systems. One of the main attractions of using LDHs for fluoride removal, is that unlike other chemical treatment methods, no chemical sludge should be produced. In the present study, an attempt was made to investigate the mechanism of fluoride removal by LDHs under different conditions using batch methods. In addition, the release of fluoride adsorbed on LDHs by treatment with an aqueous solution of Na2CO3 was studied. The residual fluoride was found to be 10 mg/L in a solution with an initial concentration of 1000 mg/L, which meets the discharge standard for fluoride in industrial wastewater in China.     

Structural Evolvement of Heating Treatment of Mg/AI-LDH and Preparation of Mineral Mesoporous Materials

Although hydrotalcite, or layered double hydroxides （LDHs）, is not a common mineral, it is an important material that can be easily synthesized in laboratory. In this study, structural evolvement and BET surface area changes of heat treated Mg/AI-LDH is evaluated by XRD, TEM and N2-BET analyses. The results indicate that the magnesium-aluminum LDH with carbonate as interlayer anion, periclase-like oxides was formed at temperatures of 400-800℃. Meanwhile, 2-3 nanometer mesoporous were formed during decomposition of LDH. However, the heat treated samples still preserve the morphology of the original LDH plates. Periclase-like formed from LDH heat treatment may re-hydrolyze and recover the structure of LDH. However, crystallinity of the recovered LDH is lower than that of the original LDH. This heat treatment will result in formation of （Mg, Al）-oxide nano-crystals and nanopores among the nano-crystals. When heating temperature exceeds 1000, the periclase-like （Mg, Al）-oxide is transformed into a composite with periclase （MgO） and spinel phases. The periclase can be re-hydrolyzed and dissolved in HCl solution. After acid treatment, the sample with a high surface area is composed of spinel nano-crystals and nanopores among them. Our results will provide a new and economic way to synthesize mesoporous materials through pathways of phase transformation of precursor materials with different composition.     

惯性／双星组合导航系统的滤波与仿真

介绍了惯性导航系统和双星导航系统各自的运行方式和优缺点；详细推导了组合导航系统的误差方程和量测方程；介绍了Kalman滤波的整个过程并最后进行了仿真计算。仿真结果显示，惯性导航系统和双星导航系统的组合弥补了各自的不足，具有较好的精度和可靠性。     

DSQ型水管倾斜仪电压灵敏度的调整技巧

DSQ型水管倾斜仪是“九五”期间推出的数字化地震前兆仪器，本文介绍了一些如何调整换能器的电压灵敏度及调整中的技巧。     

ISO-834标准火灾作用后钢管混凝土的轴压刚度和抗弯刚度

火灾后钢管混凝土的轴压刚度和抗弯刚度是钢管混凝土结构变形性能和抗震分析的重要指标，也是火灾后钢管混凝土修复和加固的重要依据之一，本文利用数值方法计算了标准火灾作用后钢管混凝土轴压构件和纯弯构件荷载-变形关系曲线，分析了受火时间、材料强度、含钢率、截面尺寸等因素的影响规律，最后推导了标准火灾作用后钢管混凝土轴压刚度和抗弯刚度的简化计算公式，所得结果可供有关钢管混凝土结构工程设计时参考。     

河南郑州台数字化DSQ水管倾斜仪观测精度的评定

选取了河南郑州台数字化 DSQ型水管倾斜仪观测资料较好的 2 0 0 1年 10月 1日至 12月 31日的数据进行了分析处理 ,对该仪器的观测精度进行了评定。经计算 ,其北南向和东西向日飘移分别为 0 .0 0 0 7s和 0 .0 0 2 6 s,M2 的振幅因子为 0 .714 9和 0 .6 4 14 ,振幅因子中误差为 0 .0 0 5 5和0 .0 0 4 4。     

真空-堆载预压处理高速公路软基的有限元计算

根据高速公路路基的变形特点，提出了真空-堆载联合预压法处理软基的三维Biot固结有限元计算模型，将砂井按照实际尺寸划分单元，避免了平面计算方法中的砂井处理的问题，较以往的平面数值方法更接近实际情况。结合修正剑桥模型，对某真空-堆载联合预压试验段进行了计算、分析，结果令人满意。     

用双孔热解石墨管原子吸收法测定微量金

石墨炉原子吸收法在对化探样品微量金的测试过程中存在因载气进入而使待测样品溅出的问题。利用自制的双孔热解石墨管代替普通石墨管可解决上述问题。通过大量的实验证明,仪器在最佳工作条件下,硫脲介质浓度10g·l-1、解脱时间40min时,获得检出限0 10×10-9、加标回收率为98 4%～103 7%的分析结果。     

重油凝胶色谱制备样品中痕量镍的分析研究

研究表明微波密闭消解法对重油凝肢色谱制各样品的前处理，不造成易挥发有机金属化合物的损失，对样品无污染。采用消解前定容，配合石墨炉二次进样富集样品，可以测定样品中低至10^—9级的镍。方法应用于镍在渣油中随相对分子质量分布分析中，标准样品对照数据吻合好，相对标准偏差(RSD，n＝11)为8％。