The δ60/58Ni Values of Twenty‐Six Selected Geological Reference Materials

The high‐precision δ^60/58Ni values of twenty‐six geological reference materials, including igneous rocks, sedimentary rocks, stream sediments, soils and plants are reported. The δ^60/58Ni values of all samples were determined by double‐spike MC‐ICP‐MS (Nu Plasma III). Isotope standard solution (NIST SRM 986) and geological reference materials (BHVO‐2, BCR‐2, JP‐1, PCC‐1, etc.) were used to evaluate the measurement bias and intermediate precision over a period of six months. Our results show that the intermediate precision of Ni isotope determination was 0.05‰ (2s, n = 69) for spiked NIST SRM 986 and typically 0.06‰ for actual samples, and the δ^60/58Ni _{NIST SRM 986} values were in excellent agreement with previous studies. Eighteen high‐precision Ni isotope ratios of geological reference materials are first reported here, and their δ^60/58Ni values varied from ?0.27‰ to 0.52‰, with a mean of 0.13 ± 0.34‰ (2s, n = 18). Additionally, SGR‐1b (0.56 ± 0.04‰, 2s), GSS‐1 (?0.27 ± 0.06‰, 2s), GSS‐7 (?0.11 ± 0.01‰, 2s), GSD‐10 (0.46 ± 0.06‰, 2s) and GSB‐12 (0.52 ± 0.06‰, 2s) could potentially serve as candidate reference materials for Ni isotope fractionation and comparison of Ni isotopic compositions among different laboratories.     

白涧铁矿南区复杂地层钻探施工技术

邢台白涧铁矿南区地层岩石破碎、部分地层含角砾、胶结性差、漏失严重,钻探施工中存在掉块卡钻、缩径、坍塌、埋钻及孔内泥浆全部漏失等难题。通过优化钻孔结构、使用新工艺、新方法,合理选择钻进参数,采用绳索取心钻进配合预留技术套管,有效解决了上部煤系地层的坍塌问题;采用反丝套管的方法,极大地减轻了由于地层缩径、掉块引起的套管下不到位、起拔困难等风险;常规型绳索取心钻杆替代套管方法的采用,提高了含角砾、松散地层的穿过速度,减少了钻探工作量的报废,加快了施工进度;特别是高胎体双水口钻头的使用,提高了钻进效率,节约了钻探施工成本,项目得以如期完成。     

2014年盈江双震的破裂历史

2014年5月24日在云南省盈江县发生Ms5.6级地震(主震A), 于5月30日在其附近再次发生Ms6.1级地震(主震B). 我们挑选云南省地震台网记录的数字波形资料, 借助于经验格林函数技术提取了这两次地震的震源时间函数,获得了其破裂历史. 为了利用经验格林函数技术提取震源时间函数,我们首先利用优选的速度模型,采用逆时成像技术重新确定了主震A和B以及挑选的6次较大余震的震源位置,并利用双差定位技术确定了主震与余震之间的相对位置;然后利用广义极性振幅技术反演了这些事件的震源机制;最后,根据主震和余震的相对位置以及震源机制特征挑选最优台站记录,提取了两个主震的震源时间函数. 结果表明,主震A持续时间约3.5 s, 分两个阶段,第一阶段0~1.3 s, 第二阶段1.3~3.5 s;主震B持续时间约5.0 s, 其过程比A复杂,至少可以分为五个阶段,第一阶段0~0.7 s, 第二阶段0.7~1.6 s, 第三阶段1.6~2.5 s,第四阶段2.5~3.8 s,第五阶段3.8~5.0 s.     

应用选权拟合法建立单历元伪距和载波相位双差模型

本文根据选权拟合法的一个重要性质:只要被约束的那部分参数估值无偏,其余的参数估值也无偏;该性质说明利用选权拟合进行参数估计的结果是条件无偏的。这个不同于一般正则化解的重要特性可以建立单历元伪距和载波相位双差模型,并通过实例验证了该方法的可行性。     

3S技术在晚稻长势监测中的综合应用研究

以江西省为试验区，探讨用RS－GIS－GPS技术监测作物长势的方法和途径。针对丘陵山区地形复杂、地块不成规模的情况，在GIS支持下，将数字高程数据、土地利用分类数据与GPS定位观测数据相结合，对NOAA／AVHRR进行判读，提取反映双季晚稻长势的植被指数，用该指数与GPS定位观测资料及地理信息数据进行监督分类监测苗情，并用迭代自组织分析法进行无GPS定位观测资料时相应时相的NOAA／AVHRR的长势监测。研究结果表明，选用的地理信息数据（数字高程数据、土地利用分类）与GPS定位观测资料相结合提高NOAA／AVHRR数据的利用效果是适合的和切实可行的。     

Simulation of double cold cores of the 35°N section in the Yellow Sea with a wave-tide-circulation coupled model

Based on the MASNUM wave-tide-circulation coupled numerical model, the temperature structure along 35°N in the Yellow Sea was simulated and compared with the observations. One of the notable features of the temperature structure along 35°N section is the double cold cores phenomena during spring and summer. The double cold cores refer to the two cold water centers located near 122°E and 125°E from the depth of 30m to bottom. The formation, maintenance and disappearance of the double cold cores are discussed. At least two reasons make the temperature in the center (near 123°E) of the section higher than that near the west and east shores in winter. One reason is that the water there is deeper than the west and east sides so its heat content is higher. The other is invasion of the warm water brought by the Yellow Sea Warm Current (YSWC) during winter. This temperature pattern of the lower layer (from 30m to bottom) is maintained through spring and summer when the upper layer (0 to 30m) is heated and strong thermocline is formed. Large zonal span of the 35°N section (about 600 km) makes the cold cores have more opportunity to survive. The double cold cores phenomena disappears in early autumn when the west cold core vanishes first with the dropping of the thermocline position. Supported by the National Basic Research Program of China (No. G1999043809) and the National Science Foundation of China (No. 49736190).     

Preparation of Mg/Al Layered Double Hydroxides by Buffer Solution Method and Cr（Ⅵ） Adsorption Characteristics

利用氨水-氯化铵体系在pH 9～10时具有缓冲能力的特点,以其作为沉淀剂成功合成了镁铝水滑石（Mg3Al-Cl-LDHs）,采用XRD、FT-IR、TG-DTA等手段对材料结构进行表征,并测试了合成Mg3Al-Cl-LDHs样品对溶液中Cr（Ⅵ）的吸附性能。研究结果表明,缓冲溶液法制备的Mg3Al-Cl-LDHs材料晶相单一,晶面生长的有序程度较高,结晶度较好。晶胞参数a=0.3106 nm,c=2.367 nm,粒子尺寸约为36.44 nm。其热分解过程包括水滑石层间结构水脱除和层板羟基脱水、氯离子分解两个步骤。Mg3Al-Cl-LDHs对Cr（Ⅵ）的吸附主要发生在0～1 h内,随着时间的增长吸附量先增加后趋于平缓;温度对Cr（Ⅵ）吸附量影响不大,在常温下即可进行;随着pH值的减小,饱和吸附量先增大后减小,在pH 6时吸附效果较好;2价与3价竞争阴离子比1价阴离子对吸附性能的影响更大。在最佳吸附条件下,Mg3Al-Cl-LDHs对Cr（Ⅵ）的饱和吸附量可达58.73 mg/g,有望应用于实际Cr（Ⅵ）废水处理。     

基于SLFT边坡双折减系数强度失稳判据

基于滑移线场理论（SLFT）,提出了一种边坡双折减系数强度折减法失稳判据：当由滑移线场理论计算得到的极限状态下的边坡坡面（简称\     

北半球500 hPa位势高度场时空频谱特征分析

利用1979～2004年NCEP2再分析资料,对逐日的北半球(20°N～90°N) 500 hPa的位势高度进行二维傅里叶的谱展开,并分析了不同波数下的谱展开系数的频域特征.对全年序列分析的结果表明:当纬向波数k和经向波数l均为0时,其谱展开系数表现为显著的低频(10～30天)变化特征;当经向波数l=0时,其谱展开系数...     

蒸馏水中蒙脱石晶层间膨胀压力理论研究

蒙脱石颗粒周围的溶液浓度对其膨胀性有较大影响,传统的双电层模型可以对电解质环境下蒙脱石的膨胀特性做出较好的模拟,但并不适于蒸馏水的情况。针对膨润土在蒸馏水或纯水中已有的膨胀特性试验,本文在前人的研究基础上详细推导了蒸馏水中蒙脱石晶层间的膨胀压力模型,并给出一种简便算法。运用此算法可以避免非线性方程的求解,从而可以较方便的将膨胀力和晶层间距联系起来。