LiBr溶液从低浓度到高浓度的分子动力学模拟

在 L i Br与水的物质量比分别为 1∶ 64、1∶ 32、1∶ 16、1∶ 8、1∶ 4和 1∶ 3的情况下 ,对 L i Br溶液从低温到高温的分子动力学模拟进行了研究。随浓度增加 ,锂离子的水合数量呈减少趋势但同时又从 L i+- Br-接触离子对的数量增加中得到补偿 ,而 L i离子的第一配位壳层的配位数量保持不变。在高浓度 Li Br溶液中 ,Br- O之间的距离有所增加 ,Br-- O的径向分布的形状更趋于非对称 ,从而很好地确定了 Br离子水合壳层 L i+- Br-接触离子对可以在更稀的溶液中产生 ,但随浓度增加而增加。L i+- Br-距离明显短于溶液中 Li离子与 Br离子的离子半径之和 ,也短于 L i Br晶体中两者离子半径之和。高浓度溶液中水分子的结构几乎被破坏 ,水分子间的氢键明显增加 ,但没有消失。对 L i+、Br-和水的扩数系数计算值与实验值进行了比较     

The Time-Varying Gravitational Potential Field of a Massive,Deformable Body

The internal as well as the external gravitational field of the Earth is computed under the assumption that (i) the mass distribution of the deformable body as well as (ii) the heights of the topographic surface and the depths of the interfaces (dynamic isostasy) vary in time. In order to represent those shape variations properly, the topographic masses as well as the interface masses are regarded as condensed following a proposal by F.R. Helmert (1884, p. 149-163). Accordingly time-varying simple layer mass densities are generated. Basic results are collected in 4 boxes.     

Influence of wave groups on SSC patterns over vortex ripples

Estimates of spatial and temporal variations in suspended sand concentrations (SSC) made with a multi-transducer Acoustic Backscatter Sensor (ABS) under a repeated wave group over a mobile rippled bed in the wave research flume at the National Hydraulics Laboratory in Ottawa, Canada, reveal an number of complex and intriguing patterns. Ensemble averages of 8 nearly identical wave groups provided much more robust estimates of SSC and allowed a detailed examination of the wave group effects. The largest SSC near the bed (< 0.10 m) occurs in phase with the largest waves in the group. Above approximately 0.10 m elevation, SSC lags behind the near bed SSC by as much as 2–3 waves; introducing significant curvature (on a semi-log plot) to the SSC profile. The log linear segments of the SSC profile grow and decay systematically on the scale of the wave group. The range in lengths of log-linear profile segments ( 0.03–0.355 m) suggest that the boundary layer thickness also fluctuates throughout the passage of the wave group. Furthermore, there are significant variations in the patterns of SSC, which occur under the largest and smallest waves in the group. Under the largest waves vertical bands of alternating high and low SSC produce an intra-wave modulation in the upper water column ( 0.075–0.30 m). The equivalent horizontal excursion of these bands scales to the ripple length. Under the smaller waves the intra-wave modulation of the SSC disappears and is replaced by temporally homogenous suspension that expands vertically through several individual wave cycles. The former pattern of homogenous suspension appears to be associated with growth of a boundary layer due to the persistent uni-directional horizontal flow during this part of the group together with the persistence of antecedent bed generated turbulence and vorticity which maintains the suspension. The latter pattern of bands of high and low SSC indicates a strong temporal and spatial constraint on the SSC (phase coupling) induced by the presence of the bedforms which may be enhanced by strong reversals in both flow and vorticity under the large waves in the group.     

现代冲积河流的河型空间转化模式探讨

论述了现代冲积河流系统中常见河型的自然分布及转化特征,归纳了河型从上游向下游发生空间转化的 5种主要模式。这些河型转化模式发生的相对频率是不同的,其中从辫状河流向曲流河流转化的发生频率最大。文中通过具体实例总结了这些转化模式分别发生时的主要影响因素。     

赣南地区煤矿分布规律及找煤方向

赣南地区各含煤岩系及煤矿（田）产布特征,具有东西向成片、北北东向成行,受东西向与北北东向推昨合控制的分布规律。因此,深入研究推覆构造系统的特点及其控煤规律,从而确定出煤系“构造窗”、覆于煤系之上的“飞来峰”,甚至辨认出覆于煤系之上的大片外来岩席（包括花岗岩外来岩席）,是确定找煤方向和预测隐伏煤矿（田）的重要途径。     

银川盆地第四纪地球化学元素特征及沉积环境

通过分析银川盆地Ｙ１孔地球化学元素含量及其分布规律,参考地层岩性等因素,确定了该盆地第四系地层地球化学元素的分带。依据地球化学元素分布,结合孢娄分析成果探讨了银川盆地第四纪中、晚期以来的沉积环境和古气候及其演化规律。     

Model study of the relationship between sediment yield and river basin area

The SHETRAN physically based, spatially distributed model is used to investigate the scaling relationship linking specific sediment yield to river basin area, for two contrasting topographies of upland and more homogeneous terrain and as a function of sediment source, land use and rainfall distribution. Modelling enables the effects of the controls to be examined on a systematic basis, while avoiding the difficulties associated with the use of field data (which include limited data, lack of measurements for nested basins and inability to isolate the effects of individual controls). Conventionally sediment yield is held to decrease as basin area increases, as the river network becomes more remote from the headwater sediment sources (an inverse relationship). However, recent studies have reported the opposite variation, depending on the river basin characteristics. The simulation results are consistent with these studies. If the sediment is supplied solely from hillslope erosion (no channel bank erosion) then, with uniform land use, sediment yield either decreases or is constant as area increases. The downstream decrease is accentuated if rainfall (and thence erosion) is higher in the headwaters than at lower elevations. Introducing a non‐uniform land use (e.g. forest at higher elevations, wheat at lower elevations) can reverse the trend, so that sediment yield increases downstream. If the sediment is supplied solely from bank erosion (no hillslope erosion), the sediment yield increases downstream for all conditions. The sediment yield/basin area relationship can thus be inverse or direct, depending on basin characteristics. There still remains, therefore, considerable scope for defining a universal scaling law for sediment yield. Copyright © 2006 John Wiley & Sons, Ltd.     

Modelling peak accelerations from earthquakes

This paper deals with the prediction of peak horizontal accelerations with emphasis on seismic risk and insurance concerns. Non‐linear mixed effects models are used to analyse well‐known earthquake data and the consequences of mis‐specifying assumptions on the error term are quantified. A robust fit of the usual model, using recently developed robust weighted maximum likelihood estimators, is presented. Outlying data are automatically identified and subsequently investigated. A more appropriate model accounting for the extreme value nature of the responses, is also developed and implemented. The implication on acceleration predictions is demonstrated. Copyright © 2006 John Wiley & Sons, Ltd.     

冲绳海槽宫古段中央地堑的形态与分布

采用中国科学院海洋研究所“科学1号”调查船及国家海洋局“向阳红9号”调查船最近几年在冲绳海槽宫古段进行海底地形及反射地震调查所取得的数据,首次详细展示了冲绳海槽宫古段南北长约200km区域内中央地堑的形态及空间展布特征。本文给出的成果大大加深了关于冲绳海槽中央地堑各种变化的认识。指出,按照形态,中央地堑分为U型、V型和半地堑三种。其中大部分中央地堑为U型地堑。地堑的深度40～250m,宽度6～14km,长度17～33km。冲绳海槽宫古段的最大水深为2244.4m,位于中央地堑城阳段北端底部靠东的一侧(125°19.3′E,25°49.8′N)。本研究区的中央地堑可分为断续的9段,从东北向西南大致呈右旋雁行排列。但黄岛段相对于崂山段,城阳段相对于莱西段,李仓段相对于城阳段又稍微向西偏出,呈现为左旋雁行排列。地堑的走向一般为N60°E左右,相对于冲绳海槽的走向更偏向于东西方向,偏角在15°左右。各段中央地堑是被NW向断裂错开的。这些断裂在海底表现为明显的海底断崖地貌和陡沟地貌,在地震剖面上表现为明显的地层错位,其错位的幅度往往老地层比新地层要大。根据地震剖面分析,这些NW向的断裂应该是走滑性质的。本文展示的中央地堑在形态上和空间展布形式上都和扩张洋脊类似。莱西段和城阳段中央地堑之间重叠地堑,在形式上也类似于扩张洋脊的重叠扩张中心。从地堑深度较浅并发育重叠地堑来分析,冲绳海槽的扩张速率应当介于慢速扩张和中速扩张之间。本研究区莱西段、即墨段和平度段海底地形相对较高,中央地堑深度变浅,并发育重叠中央地堑,应该相当于快速扩张大洋中脊的轴高,可能是正在孕育岩浆活动的位置。目前我们所观测到的中央地堑的错断和有规律的排列说明海槽的主体演化过程已经在拉张盆地和断陷盆地的基础上上升到一个更高的阶段。本文根据中央地堑的展布形式、重叠中央地堑,及其两侧中央地堑中的海底山推测此区域海底扩张可能正在进行。     

陆相坳陷盆地层序地层格架下岩性地层圈闭/油藏类型与分布规律——以松辽盆地白垩系泉头组—嫩江组为例

本文在圈闭组成和形成条件分析的基础上对坳陷盆地层序地层格架下岩性地层圈闭/油藏类型与分布规律进行了初步分析和总结,探讨了层序地层格架下不同体系域中圈闭/油藏类型的纵向分布、盆地中不同构造部位圈闭/油藏类型的横向分布规律。系统解剖了松辽坳陷盆地白垩系二级层序格架内低位、湖侵和高位体系域中圈闭/油藏类型的纵向分布和变化特征;对比分析了坳陷盆地从凹陷带(近凹中心)、过渡带(凹陷边缘)到斜坡带(环凹斜坡)圈闭/油藏类型的横向分布和变化规律。圈闭/油藏类型的纵、横向分布和变化规律表明:岩性地层圈闭/油藏的形成及类型具有纵向“层控”、横向“相控”的规律性,即纵向上受控于层序格架(体系域),横向上受控于一定构造背景下特定的沉积相带。