从平衡-封闭-静态转向非平衡-开放-动力学研究-热液矿床成因的若干新概念概述

热液金属矿床成因研究过程中,观测与实验始终是密切结合的。上世纪70年代,平衡热力学的实验数据的快速积累,使人们用热力学理论计算可以预测和反演矿石和岩石的成因。但是,没有矿物-水溶液的反应速率数据,又没有与流体力学的结合,搞清楚矿石成因是困难的。七、八十年代,开始研究矿物与水溶液的反应动力学实验。科学家们开始瞄准了从平衡-封闭-静态转向非平衡-开放-动力学研究的这个大方向。1992年我们建立地球化学动力学开放研究实验室。研究高温高压矿物与水反应速率,发现固液的开放体系的自组织现象。实验发现温度影响矿物的各个元素反应速率改变,发现在跨越水临界态时矿物与水反应速率涨落、在近临界的气-液两相不混溶区一些金属进入气相、超临界流体的氧化作用及特别的溶剂性能影响矿物溶解性质。实验证实:临界态区流体与矿石成因有关。水岩相互作用的反应动力学实验温度从低温到550度,揭示矿石的金属来源、迁移、金属与蚀变分带机制。一大批大于300度的矿物与水反应动力学实验在国际界是少有报道的。九十年代,超高压的科学发展,与同步辐射光源的技术进步的结合,使固体地球科学又迈向了地球深内部。我们发展了高温高压流体性质的原位直测(测量850℃水溶液)红外谱,发现深部流体的新性质:气液两相流体的新结构,在临界温度区(300~400℃),水分子氢键网络的破坏受压力影响不大(23MPa~3GPa),同时,出现水的高电导率。研发新仪器为开放-流动-非平衡的反应动力学实验与极端条件下物质性质的直接观测结合,在科学前沿领域开辟了创新道路。     

青藏高原拉萨地块西部念青唐古拉岩群的地球化学特征及构造意义

拉萨地块西部呈断块状沿狮泉河-申扎-嘉黎蛇绿混杂岩带附近分布的念青唐古拉岩群被认为是前寒武纪变质基底。本文对念青唐古拉岩群进行了系统的岩石学、地球化学、同位素年代学及构造地质学研究。研究结果表明片岩-片麻岩-变粒岩含十字石、石榴子石等特征变质矿物,遵循粒度分异规律,其原岩可能为来自冈瓦纳古陆核北缘中新元古代弧盆体系的活动大陆边缘浊积岩。斜长角闪岩具低硅、高铁镁、富钙的基性岩特征,其原岩为岛弧型基性火山岩。念青唐古拉岩群中的花岗伟晶岩锆石LA-ICPMS U-Pb年龄为1150±13Ma,具过铝质S型花岗岩地球化学特征,可能为中元古代(1150±13 Ma)以前就开始沉积的念青唐古拉岩群基底岩石通过部分熔融形成。与花岗伟晶岩渐变过渡接触的二云斜长片麻岩第一组变质重结晶锆石U-Pb年龄为701±15 Ma,结合十字石特征变质矿物,暗示了该地区中温高压变质作用的峰期变质,变质程度达角闪岩相;第二组热液流体锆石UPb年龄为301±8.4 Ma,可能与冈瓦纳大陆北缘古特提斯洋演化过程中的岩浆热液作用有关。     

Reactivity of micas and cap-rock in wet supercritical CO2 with SO2 and O2 at CO2 storage conditions

Seal or cap-rock integrity is a safety issue during geological carbon dioxide capture and storage (CCS). Industrial impurities such as SO₂, O₂, and NOx, may be present in CO₂ streams from coal combustion sources. SO₂ and O₂ have been shown recently to influence rock reactivity when dissolved in formation water. Buoyant water-saturated supercritical CO₂ fluid may also come into contact with the base of cap-rock after CO₂ injection. Supercritical fluid-rock reactions have the potential to result in corrosion of reactive minerals in rock, with impurity gases additionally present there is the potential for enhanced reactivity but also favourable mineral precipitation.The first observation of mineral dissolution and precipitation on phyllosilicates and CO₂ storage cap-rock (siliciclastic reservoir) core during water-saturated supercritical CO₂ reactions with industrial impurities SO₂ and O₂ at simulated reservoir conditions is presented. Phyllosilicates (biotite, phlogopite and muscovite) were reacted in contact with a water-saturated supercritical CO₂ containing SO₂, or SO₂ and O₂, and were also immersed in the gas-saturated bulk water. Secondary precipitated sulfate minerals were formed on mineral surfaces concentrated at sheet edges. SO₂ dissolution and oxidation resulted in solution pH decreasing to 0.74 through sulfuric acid formation. Phyllosilicate dissolution released elements to solution with ∼50% Fe mobilized. Geochemical modelling was in good agreement with experimental water chemistry. New minerals nontronite (smectite), hematite, jarosite and goethite were saturated in models. A cap-rock core siltstone sample from the Surat Basin, Australia, was also reacted in water-saturated supercritical CO₂ containing SO₂ or in pure supercritical CO₂. In the presence of SO₂, siderite and ankerite were corroded, and Fe-chlorite altered by the leaching of mainly Fe and Al. Corrosion of micas in the cap-rock was however not observed as the pH was buffered by carbonate dissolution. Ca-sulfate, and Fe-bearing precipitates were observed post SO₂-CO₂ reaction, mainly centered on surface cracks and an illite rich illite-smectite precipitate quantified. Water saturated impure supercritical CO₂ was observed to have reactivity to rock-forming biotite, muscovite and phlogopite mineral separates. In the cap-rock core however carbonates and chlorite were the main reacting minerals showing the importance of assessing actual whole core.     

乌兰哈达变质岩地层地热勘探井钻头选择与取心工艺

内蒙古自治区察右后旗乌兰哈达苏木地热勘探井井深2006.87 m。采用石油30型钻机施工,钻遇地层大部分为变质岩,达1500 m以上,对牙轮钻头损坏严重,同时施工要求进行18次岩心采取。经过对钻头的试用、选择,最后选用HJ637G型牙轮钻头,钻进时效可达0.8～1.2 m,使用寿命可达到80～100 h。取心段采用川7-4型双管单动取心筒配合金刚石钻头,岩心采取率可达70%～95%。     

基于斜坡破坏模式的软弱变质岩区岩质滑坡易发性评价

滑坡受控于地质环境条件和坡体地质结构,不同地质结构的斜坡失稳破坏的模式存在差异,本文以后龙门山千枚岩区为例,基于现场调查,梳理总结了区内岩质滑坡发生的力学模式与斜坡地质环境、坡体结构之间的关系,进而选取控制滑坡发生的关键因素,运用ARCGIS软件的加权叠加功能定量划分了不同模式滑坡的易发区域,主要取得以下认识：（1）滑移—拉裂式滑坡主要发生在坡度30-45°的顺向飘倾坡内、滑移—溃曲式滑坡发生在坡度30-45°的顺向伏倾坡内、倾倒变形主要发生在岩层倾角大于65°的反向斜坡内;（2）区内倾倒变形易发区面积为8.73km2、滑移拉裂易发区面积为4.31m2、滑移溃曲易发区面积为3.28km2,以倾倒变形类型的滑坡为主,已发生滑坡与易发分区结果比对证明了滑坡易发分区与实际情况基本吻合。     

压力对辉长岩矿物反应和部分熔融影响的实验研究

本文在高温高压条件下,开展了辉长岩矿物反应与部分熔融实验,利用偏光显微镜与扫描电镜对实验样品微观结构观察,研究实验中的新生矿物与熔体的分布;通过电子探针分析熔体成分特征。实验结果表明,在低压(300MPa)条件下,静压和塑性变形实验样品中,单斜辉石以固体反应方式生成橄榄石,在高压(1300MPa)塑性实验中所有实验样品都没有发现新生矿物颗粒,这与相图中低压条件下斜长石与橄榄石稳定共存,而高压下斜长石-辉石稳定共存相吻合。高压塑性变形条件下,单斜辉石和黑云母首先发生部分熔融,随着温度增高,斜长石逐渐参与熔融,熔体呈薄膜状分布在矿物颗粒边界,熔体成分依赖于参与熔融的矿物成分,表明出现的熔体为非平衡熔融结果。     

西藏西北部浅变质石英砂岩岩石学特征及其构造意义

羌塘盆地中央隆起带主要由浅变质石英砂岩组成,由于化石匮乏、变形强烈,长期以来对这套浅变质石英砂岩成因的争议颇大,导致了对藏西北地区前中生代构造演化的认识长期模糊不清,其中,何处才是冈瓦纳大陆北界就是一个长期争论的议题。在西藏西北部,近东西走向的布尔嘎错断裂带将北部的查多岗日地块与南部的南羌塘地块分隔开,浅变质石英砂岩广泛出露于这两地块之内。沿近东西走向布尔嘎错断裂带断续产出的冈玛错蓝片岩、蛇绿岩等岩片大体呈南北向逆冲于浅变质石英砂岩之上,因此早期曾认为布尔嘎错断裂带是冈瓦纳大陆之北界。本文的调查与研究发现查多岗日和南羌塘地块内浅变质石英砂岩岩相学特征完全相同,均主要由石英组成,遭受了绿片岩相的变质作用,形成了钠长石+绿泥石+白云母组合,充填于早期石英颗粒之间,钠长石交代钾长石。这两地的浅变质石英砂岩均被未变质钙质胶结的钾长石石英砂岩平行不整合覆盖。碎屑锆石的阴极发光分析与U-Pb定年结果进一步证实了查多岗日与南羌塘地块内浅变质石英砂岩内的锆石来源完全相同。这些证据充分反映了查多岗日与南羌塘地块早期构造演化过程相似,源自同一大陆。碎屑锆石定年结果进一步表明浅变质石英砂岩的最大沉积年龄为520±8Ma,该岩石再被约480Ma的花岗岩脉侵入,因此其很可能形成于晚寒武世,而不整合面之上沉积岩的最大沉积年龄为460±8Ma,表明该不整合面上、下沉积岩之间存在明显的沉积间断,证实了该平行不整合面形成于奥陶纪。不整合面之下的浅变质石英砂岩因此与杨耀等(2014)报道的荣玛组相同,不整合面之上未变质长石石英砂岩则属于中上奥陶统塔石山组。查多岗日地块因此是西藏境内最北端的冈瓦纳大陆的碎块。在西藏西北部,冈瓦纳大陆北界为龙木错-帮达错-(83°40'E、35°N)-红脊山-荣玛乡。布尔嘎错断裂带不是冈瓦纳大陆之北界。     

关于巴罗式变质带的最新研究及其对研究秦岭杂岩的意义

本文对苏格兰高地Grampian造山运动中产生的经典巴罗变质带进行了讨论,重点介绍了近年来关于其变质作用的特征及发生机制认识方面的重大变化。强调巴罗变质作用仅发生在整个造山运动过程中的部分时段,纪录了短暂的加热过程,时空上与区域内大规模的双峰式岩浆活动有关。经典的巴罗变质系列并非形成于地壳增厚及其热弛豫,而是代表了中地壳内大规模的接触变质作用。参考经典地区的变质特征,对发育巴罗式变质作用的秦岭杂岩进行了初步对比分析,指出其中与夕线石有关的变质P-T-t轨迹可能是等压冷却过程,而不是等温降压的顺时针演化模式。秦岭杂岩的变质作用时间仍需要进一步准确厘定。结合其它相关地质特征的分析和对比,得出如下推论:巴罗式变质带发育地区的变质作用、混合岩与花岗岩均属于同一动力系统作用的结果,花岗质岩体不是变质作用的原因;基性岩浆可能提供了巴罗式变质作用发生所需要的热能,但不是必要条件;巴罗式变质作用可以发生在正常地壳厚度情况下,不是碰撞构造的标志;伴随热异常的变形过程中产生了变质带的梯度分布(巴罗式变质带)和一些花岗岩,形成类似于底辟的冲起构造。     

Discovery and significance of Lizifang metamorphic core complex in Zhuanghe area of southern Liaoning

On the basis of the previous regional geological survey, based on the macroscopic and microscopic structural survey, combined with the comprehensive analysis of the regional magmatic activity and dating data, the authors in this paper revealed that there is another metamorphic core complex structure in Lizifang area of Southern Liaoning, namely Lizifang metamorphic core complex. A typical three-layer structure and five parts exist in the core complex, which are the footwall composed of Neo-archean metamorphic plutonic rocks and mesozoic granite intrusive rocks, the detachment fault zone composed of different levels of tectonic rocks, and the upper plate composed of Precambrian sedimentary cap and Cretaceous extensional basin. Lizifang metamorphic core complex formed in the Early Cretaceous Epoch, and the upper plate moved from NWW to SEE relaive to the footwall, which was similar with Jinzhou metamorphic core complex and Wanfu metamorphic core complex in geometry, kinematics polarity and formation time, indicating the same dynamic background. The determination of the metamorphic core complex may provide a basis for the late Mesozoic lithospheric thinning process and the mechanical and rheological properties of the lithosphere in the east of North China Craton. At the same time, the metamorphic core complex is closely related to the mineralization of gold deposits. So the detachment fault zone of Lizifang metamorphic core complex can serve as the key work area for further gold exploration, which may possess large mineralization potential.     

赣中变质岩带地质地球化学演化特征

赣中变质岩带由结晶基底和褶皱基底组成。从结晶基底→褶皱基底,变质泥质岩类SI O2含量降低,AL2O3含量增加;变粒岩、石英片岩、硅质岩SI O2含量显著升高,AL2O3含量显著降低;NA2O含量显著降低,K2O的含量有明显的升高,NA2O/K2O值呈显著的降低趋势;FEO、MGO、TI O2及全铁含量(FE2O3 FEO)呈降低的趋势,但FE2O3升高,FE2O3/FEO值显著增高。铁族元素TI、V、CR升高,MN、CO、NI降低;亲铜元素ZN显著升高;大离子亲石元素LI、RB、SR显著降低,U、TH、BA显著升高,SR/BA值急剧降低;LA、CE、YB、NB、Y元素升高;稀土总量、轻稀土含量、轻重稀土比值、轻重稀土相互分离程度、EU亏损程度增加,说明它们原岩沉积环境的差异性,但它们的重稀土含量、LA/CE值、SM/ND值变化很小,稀土配分曲线相互平行反映它们源区岩石的一致性及继承性。从结晶基底→褶皱基底,岩石的ΕND(0)、(~(206)PB/~(204)PB)I、(~(207)PB/~(204)PB)I、(~(208)PB/~(204)PB)I值由低→高;地壳趋于成熟,结晶基底形成于岛弧环境,褶皱基底形成于活动大陆边缘环境。