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61.
62.
Binary coefficients: A theoretical and empirical study 总被引:1,自引:0,他引:1
Michael Ed. Hohn 《Mathematical Geology》1976,8(2):137-150
Binary coefficients can be assigned to several categories on the basis of algebraic and conceptual properties. The phi coefficient of association is related algebraically to the chi-square statistic for 2-by-2 contingency tables, and use of this coefficient in cluster analysis permits the objective, nonarbitrary partitioning of objects among groups on the basis of previously selected levels of significant, positive association. Similarity, matching, and distance coefficients possess neither conceptual nor operational statistical meaning for many geological data sets. The weighted pair group method and flexible clustering strategy may give an overly conservative partitioning of objects among groups. Clustering by the unweighted pair group method, using the phi coefficient, is recommended for the analysis of biostratigraphic and paleoecologic presence—absence data. 相似文献
63.
A consistent approach to the frequency analysis of hydrologic data in arid and semiarid regions, i.e. the data series containing several zero values (e.g. monthly precipitation in dry seasons, annual peak flow discharges, etc.), requires using discontinuous probability distribution functions. Such an approach has received relatively limited attention. Along the lines of physically based models, the extensions of the Muskingum‐based models to three parameter forms are considered. Using 44 peak flow series from the USGS data bank, the fitting ability of four three‐parameter models was investigated: (1) the Dirac delta combined with Gamma distribution; (2) the Dirac delta combined with two‐parameter generalized Pareto distribution; (3) the Dirac delta combined with two‐parameter Weibull (DWe) distribution; (4) the kinematic diffusion with one additional parameter that controls the probability of the zero event (KD3). The goodness of fit of the models was assessed and compared both by evaluation of discrepancies between the results of both estimation methods (i.e. the method of moments (MOM) and the maximum likelihood method (MLM)) and using the log of likelihood function as a criterion. In most cases, the DWe distribution with MLM‐estimated parameters showed the best fit of all the three‐parameter models. Copyright © 2005 John Wiley & Sons, Ltd. 相似文献
64.
Maurizio M. D’Eliseo 《Celestial Mechanics and Dynamical Astronomy》2007,98(2):145-154
It is shown how the generalized Laplace coefficients can be employed to deduce explicit formulas for ordinary and Newcomb
derivatives of the Laplace coefficients.
相似文献
65.
针对目前局部海域小时间尺度声速场建模方法未顾及不同深度区间内声速变化规律的问题,本文根据实测深海声速剖面的统计特征,提出了声速剖面分层方法,并进一步基于经验正交函数(Empirical Orthogonal Function, EOF)提出了局部小时间尺度的声速剖面分层时变模型构建方法。利用南海实测全海深声速剖面数据,分析了分层EOF第一模态系数和等效平均声速的日变化特征,并比较了不同拟合模型的精度。最后,利用试验海区的温度和潮汐数据分析了声速剖面周期变化的影响因素。结果表明: ①声速剖面分层EOF第一模态系数及等效平均声速具有日周期变化特征,上层声速日周期变化特征不明显,中层声速日周期变化特征较明显,下层声速变化较小但仍具有日周期变化特征;②局部海域小时间尺度声速拟合应考虑长期变化项的影响;③试验海区声速剖面EOF第一模态系数变化与温度显著相关,提取的声速剖面时变特征与海区潮汐周期特征基本吻合。 相似文献
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68.
Understanding the geochemical behavior of chalcophile elements in magmatic processes is hindered by the limited partition coefficients between sulfide phases and silicate melt, in particular at conditions relevant to partial melting of the hydrated, metasomatized upper mantle. In this study, the partitioning of elements Co, Ni, Cu, Zn, As, Mo, Ag, and Pb between sulfide liquid, monosulfide solid solution (MSS), and hydrous mantle melt has been investigated at 1200 °C/1.5 GPa and oxygen fugacity ranging from FMQ−2 to FMQ+1 in a piston-cylinder apparatus. The determined partition coefficients between sulfide liquid and hydrous mantle melt are: 750–1500 for Cu; 600–1200 for Ni; 35–42 for Co; 35–53 for Pb; and 1–2 for Zn, As, and Mo. The partition coefficients between MSS and hydrous mantle melt are: 380–500 for Cu; 520–750 for Ni; ∼50 for Co; <0.5 for Zn; 0.3–6 for Pb; 0.1–2 for As; 1–2 for Mo; and >34 for Ag. The variation of the data is primarily due to differences in oxygen fugacity. These partitioning data in conjunction with previous data are applied to partial melting of the upper mantle and the formation of magmatic-hydrothermal Cu–Au deposits and magmatic sulfide deposits.I show that the metasomatized arc mantle may no longer contain sulfide after >10–14% melt extraction but is still capable of producing the Cu concentrations in the primitive arc basalts, and that the comparable Cu concentrations in primitive arc basalts and in MORB do not necessarily imply similar oxidation states in their source regions.Previous models proposed for producing Cu- and/or Au-rich magmas have been reassessed, with the conclusions summarized as follows. (1) Partial melting of the oxidized (fO2 > FMQ), metasomatized arc mantle with sulfide exhaustion at degrees >10–14% may not generate Cu-rich, primitive arc basalts. (2) Partial melting of sulfide-bearing cumulates in the root of thickened lower continental crust or lithospheric mantle does not typically generate Cu- and/or Au-rich magmas, but they do have equivalent potential as normal arc magmas in forming magmatic-hydrothermal Cu–Au deposits in terms of their Cu–Au contents. (3) It is not clear whether partial melting of subducting metabasalts generates Cu-rich adakitic magmas, however adakitic magmas may extract Cu and Au via interaction with mantle peridotite. Furthermore, partial melting of sulfide-bearing cumulates in the deep oceanic crust may be able to generate Cu- and Au-rich magmas. (4) The stabilization of MSS during partial melting may explain the genetic link between Au-Cu mineralization and the metasomatized lithospheric mantle.The chalcophile element tonnage, ratio, and distribution in magmatic sulfide deposits depend on a series of factors. This study reveals that oxygen fugacity also plays an important role in controlling Cu and Ni tonnage and Cu/Ni ratio in magmatic sulfide deposits. Cobalt, Zn, As, Sn, Sb, Mo, Ag, Pb, and Bi concentrations and their ratios in sulfide, due to their different partitioning behavior between sulfide liquid and MSS, can be useful indices for the distribution of platinum-group elements and Au in magmatic sulfide deposits. 相似文献
69.
M. J. Liszewski J. J. Rosentreter K. E. Miller R. C. Bartholomay 《Environmental Geology》2000,39(3-4):411-426
The U.S. Geological Survey and Idaho State University, in cooperation with the U.S. Department of Energy, conducted a study
to determine strontium distribution coefficients (Kds) of surficial sediments at the Idaho National Engineering and Environmental Laboratory (INEEL). Batch experiments using
synthesized aqueous solutions were used to determine Kds, which describe the distribution of a solute between the solution and solid phase, of 20 surficial-sediment samples from
the INEEL. The Kds for the 20 surficial-sediment samples ranged from 36 to 275 ml/g. Many properties of both the synthesized aqueous solutions
and sediments used in the experiments also were determined. Solution properties determined were initial and equilibrium concentrations
of calcium, magnesium, and strontium, pH and specific conductance, and initial concentrations of potassium and sodium. Sediment
properties determined were grain-size distribution, bulk mineralogy, whole-rock major-oxide and strontium and barium concentrations,
and Brunauer-Emmett-Teller (BET) surface area. Solution and sediment properties were correlated with strontium Kds of the 20 surficial sediments using Pearson correlation coefficients. Solution properties with the strongest correlations
with strontium Kds were equilibrium pH and equilibrium calcium concentration correlation coefficients, 0.6598 and –0.6518, respectively. Sediment
properties with the strongest correlations with strontium Kds were manganese oxide (MnO), BET surface area, and the >4.75-mm-grain-size fraction correlation coefficients, 0.7054, 0.7022,
and –0.6660, respectively. Effects of solution properties on strontium Kds were interpreted as being due to competition among similarly charged and sized cations in solution for strontium-sorption
sites; effects of sediment properties on strontium Kds were interpreted as being surface-area related. Multivariate analyses of these solution and sediment properties resulted
in r2 values of 0.8071 when all five properties were used and 0.8043 when three properties, equilibrium pH, MnO, and BET surface
area, were used.
Received: 30 November 1998 · Accepted: 16 February 1999 相似文献
70.
本文针对传统的体散射模型并未考虑大气不均匀性对信号传输的影响等问题,通过引入垂直非均匀的大气参数改进了模型,并利用其建立了体目标的双基地激光测风雷达方程,仿真了侧向散射回波信号,并与单基地雷达进行了对比分析。研究表明:水平方向上,双基地激光测风雷达的回波信号分布特征与单基地雷达差异较大,其回波信号等值线在近地面为卵形线,随着探测高度的增加,回波信号等值线逐渐变为以主、被动雷达为焦点的椭圆形,并最终趋近于圆形;垂直方向上,双基地激光测风雷达的回波信号随高度衰减剧烈,近地面的回波能量约为10-10 J,4 km高度的回波能量约为10-15J,在中低层大气(0~10 km),回波信号中气溶胶散射占比大,在高层大气(10 km以上),分子散射占比大。 相似文献