Suivis temporels comparés de la structure thermique d'eaux côtières libanaises (Batroun) et françaises (Marseille) entre juin 1999 et octobre 2002

Vertical temperature profiles were recorded from June 1999 to October 2002 (at least once a month) at two Mediterranean sites, in the eastern basin (Batroun, Lebanon; 0–100 m) and in the northwestern basin (Marseilles, France; 0–55 m). At the two sites, the thermal seasonal evolution and the thermocline time dynamics are quite identical. But in the Lebanese waters, at comparable water depths, temperatures are currently 4 to 5?°C higher than in the French waters, the thermocline is longer (more than 6 months), permanent and deeper (40–50 m) than in Marseilles (20–30 m). The latter frequently disappears in summer due to northwest winds inducing cold waters. This is principally due to differences in prevailing wind regimes at each site. Such evaluation, coupled with long-term observations of temporal evolution of coastal water at the regional level of the Mediterranean basins, will shed light on temperature regime fluctuations and their consequences in the context of global warming of the Mediterranean. To cite this article: M. Abboud-Abi Saab et al., C. R. Geoscience 336 (2004).     

Groundwater nitrate pollution in the Essaouira Basin (Morocco)

The Essaouira Basin (Morocco) contains a multi-layered aquifer situated in fractured and karstic materials from the Middle and Upper Cretaceous (the Cenomanian, Turonian and Senonian). Water percolates through the limestone and dolomite formations of the Turonian stage either through the marls and calcareous marls of the Cenomanian or through the calcareous marly materials of the Senonian. The aquifer system may be interconnected since the marl layer separating the Turonian, Cenomanian and Senonian aquifers is thin or intensively fractured. In that case, the water is transported through a network of fractures and stratification joints. This paper describes the extent of the nitrate pollution in the area and its origin. Most of the wells and drillholes located in the Kourimat perimeter are contaminated by nitrates with some concentrations over $\text{400 }\text{mg}\text{l}{}^{\mathrm{?1}}$. Nitrate contamination is also observed in the surface water of the Qsob River, which constitutes the natural outlet of the multi-layered complex aquifer system. In this area, agriculture is more developed than in the rest of the Essaouira Basin. Diffuse pollution of the karstic groundwater body by agricultural fertiliser residues may therefore partially explain the observed nitrate pollution. However, point pollution around the wells, springs and drillholes from human wastewater, livestock faeces and the mineralisation of organic debris close to the Muslim cemeteries cannot be excluded.     

The Bolcana Cu–Au ore deposit (Metaliferi Mountains,Romania): first data on the alteration and related mineralisation

The Bolcana ore deposit (Metaliferi Mountains, western Romania) is a porphyry ore deposit with associated epithermal veins. On the basis of different parageneses, four alteration types were distinguished: potassic, phyllic, argillic and propylitic. The mineralogical and geochemical data and estimated crystallisation temperatures of alteration minerals indicate an evolution of the system from an early period of porphyry type mineralisation (Cu+Au) to a late period of low-sulphidation epithermal mineralisation (Au+base metal). To cite this article: V. Milu et al., C. R. Geoscience 335 (2003).     

Further absolute geomagnetic paleointensities from Baja California: evaluation of Pliocene and Early/Middle Pleistocene data

From a large collection (more than 300 oriented cores) of Baja California Mio-Pliocene volcanic units, sampled for magnetostratigraphy and tectonics, 46 samples were selected for Thellier paleointensity experiments because of their low viscosity index, stable remanent magnetization and close to reversible continuous thermomagnetic curves. 19 samples, coming from 4 individual basaltic lava flows, yielded reliable paleointensity estimates with the flow-mean virtual dipole moments (VDM) ranging from 3.6 to 6.2 ×10²² A m². Our results, although not numerous, are of high technical quality and comparable to other paleointensity data recently obtained on younger lava flows. The NRM fractions used for paleointensity determination range from 38 to 79% and the quality factors vary between 4.8 and 16.7, being normally greater than 5. The combination of Baja California data with the available comparable quality Plio-Plesitocene paleointensity results yields a mean VDM of 6.3 ×10²² A m², which is almost 80% of the present geomagnetic axial dipole. Reliable paleointensity results for the last 5 Ma are still scarce and of dissimilar quality, which makes it hard to draw any firm conclusions regarding the Pliocene and Early/Middle Pleistocene evolution of the geomagnetic field. To cite this article: J. Morales et al., C. R. Geoscience 335 (2003).     

Nouvelles données structurales et datations 40K–40Ar sur les roches métamorphiques de la région de Neyriz (zone de Sanandaj–Sirjan,Iran méridional). Leur intérêt dans le cadre du domaine néo-téthysien du Moyen-Orient

The metamorphic rocks of the Neyriz area (Sanandaj–Sirjan zone) represent a Palaeozoic sequence, the upper part of which being palaeontologically dated from the Carboniferous and the Permian. Field structural analysis of the whole sequence, detailed in laboratory by microstructural one and ⁴⁰K–⁴⁰Ar dating carried on separated minerals, lead to establish that the whole sequence, from gneisses to Permian rocks, has suffered a unique synmetamorphic deformation, of variable intensity, marked by a foliation. Isotopic ages measured on extracted amphiboles and micas, clustered in four groups between 300 and 60 Ma, show the successive stages of their slow exhumation, which ended by the end of the Cretaceous. To cite this article: R. Sheikholeslami et al., C. R. Geoscience 335 (2003).     

The Use of Reference Materials: A Tutorial

Any review of the analytical literature shows that, while reference materials are routinely used in laboratories world-wide, not all uses follow ISO Guide 33 (1989), which outlines best practices. Analytical data quality can suffer as a result. This paper reviews the various uses that the geoanalytical community has made of reference materials from a historical perspective, and suggests improvements in practice that would more closely follow ISO Guide 33 recommendations.     

The San Blas Pluton: An example of Carboniferous plutonism in the Sierras Pampeanas, Argentina

New geochronological and geochemical data are reported for the San Blas Pluton (SBP), in the northwestern Sierra de Velasco, Sierras Pampeanas, which intrudes Ordovician granitoids developed during the Famatinian orogeny. A precise Carboniferous age of 340±3 Ma is established by U–Pb dating of zircon using a sensitive high-resolution ion microprobe (SHRIMP). The SBP illustrates several petrological and geochemical characteristics of previously reported Carboniferous granitoids in the Sierras Pampeanas. Their generation is consistent with a regional reheating of the crust at approximately 342 Ma, which resulted in the formation of relatively large amounts of granitic melts that were emplaced in higher crustal levels along master fractures (older master shear zones of Lower Paleozoic age). The SBP can be chemically defined as a typical A-type granitoid related to postcollisonal or postorogenic magmatism. Its high REE content and extraordinarily high U and Th concentrations may have economic significance. Many previously published Devonian and Carboniferous K–Ar dates are reset Ordovician ages, but the existence of other Carboniferous bodies in the Sierra de Velasco cannot be discounted until detailed mapping of the whole Sierra is completed.     

A spectral approach to simulating intrinsic random fields with power and spline generalized covariances

This article presents a variant of the spectral turning bands method that allows fast and accurate simulation of intrinsic random fields with power, spline, or logarithmic generalized covariances. The method is applicable in any workspace dimension and is not restricted in the number and configuration of the locations where the random field is simulated; in particular, it does not require these locations to be regularly spaced. On the basis of the central limit and Berry–Esséen theorems, an upper bound is derived for the Kolmogorov distance between the distributions of generalized increments of the simulated random fields and the normal distribution.     

Une nouvelle méthode de cartographie de la région d’Oran (Algérie) à l’aide de la télédétection multispectrale

We have mapped the region of Oran, Algeria, using multispectral remote sensing with different resolutions. For the identification of objects on the ground using their spectral signatures, two methods were applied to images from SPOT, LANDSAT, IRS-1 C and ASTER. The first one is called Base Rule method (BR method) and is based on a set of rules that must be met at each pixel in the different bands reflectance calibrated and henceforth it is assigned to a given class. The construction of these rules is based on the spectral profiles of popular classes in the scene studied. The second one is called Spectral Angle Mapper method (SAM method) and is based on the direct calculation of the spectral angle between the target vector representing the spectral profile of the desired class and the pixel vector whose components are numbered accounts in the different bands of the calibrated image reflectance. This new method was performed using PCSATWIN software developed by our own laboratory LAAR. After collecting a library of spectral signatures with multiple libraries, a detailed study of the principles and physical processes that can influence the spectral signature has been conducted. The final goal is to establish the range of variation of a spectral profile of a well-defined class and therefore to get precise bases for spectral rules. From the results we have obtained, we find that the supervised classification of these pixels by BR method derived from spectral signatures reduces the uncertainty associated with identifying objects by enhancing significantly the percentage of correct classification with very distinct classes.     

Raman spectroscopy of natural silica in Chicxulub impactite,MexicoSpectroscopie Raman de silices naturelles dans l'impactite de Chicxulub,Mexique

A series of natural silica impactite samples from Chicxulub (Mexico) was investigated by Raman microprobe (RMP) analysis. The data yield evidence for high-pressure shock metamorphism in the rock. The impactite contains three polymorphs of silica: the original α-quartz, and two high-pressure varieties – coesite and disordered quartz representing various degrees of crystallinity. We found systematic changes in frequencies and half-widths of the Raman bands, caused by increasing irregularities of bond-lengths and bond-angles and a general breaking-up of the structure as a result of impact events. Therefore, RMP is an adequate tool for measuring the crystallinity of disordered quartz. The half-width Γ and the frequency ω of the symmetric SiOSi stretching vibrational band (A₁ mode) of the SiO₄ tetrahedra are the most amenable parameters for estimating the degree of crystallinity. In well-crystallized quartz, Γ=5 cm^?1 and ω=464 cm^?1, while in highly disordered quartz this line shifts up to ω=455 cm^?1 and broadens up to Γ=30 cm^?1. The Raman lineshapes appear to depend strongly on the degree of lattice disorder subsequent to impact events. To cite this article: M. Ostroumov et al., C. R. Geoscience 334 (2002) 21–26