橄榄石中H的结合机制及扩散行为

名义上无水矿物(nominally anhydrous minerals,NAMs)中以点缺陷形式存在的结构水,因其对于矿物物理化学性质的显著影响而受到越来越广泛的关注。橄榄石是上地幔中含量最丰富的矿物,水在橄榄石中的存在形式、扩散机制和速率对上地幔的流变学和电导性质有着重要的影响。因此,对于橄榄石中H的结合机制及其扩散机制和速率的了解有助于理解地球深部的水循环,也有助于构建上地幔流变结构以及解释电导测量结果。本文总结了近几十年来学界对于H在橄榄石中存在的缺陷类型与OH红外光谱吸收峰之间的对应关系,以及H在矿物晶格中的扩散机制、扩散速率等重要问题的研究成果,并探讨了现有研究中依然存在的问题。     

扩散法——EA-IRMS测定天然水体铵态氮同位素实验条件研究

稳定氮同位素是研究氮循环和氮污染源示踪的一个有效手段。然而目前国内对水体中铵态氮同位素测定方法研究较少,限制了水体氮循环和污染机理的深入探讨。本文采用改进的扩散法(EA-IRMS)测定水中铵态氮同位素,探讨了样品制备过程中扩散溶液的体积、浓度和扩散时间对回收率及氮同位素测定值的影响。实验得出最佳扩散条件为:1.50 mg/L氯化铵溶液400 mL扩散14天,回收率大于95%,且不会产生氮同位素分馏。本研究为高精度测定天然水体中铵态氮同位素提供了更可靠的实验条件。     

不同氧化还原条件下铅锌矿尾砂中重金属元素活化迁移规律

以广西大厂镇鲁塘铅锌矿尾砂为研究对象,通过淋滤实验研究了不同氧化还原条件下尾砂中Cu、Cd、Zn、Pb和As等元素的活化和迁移规律。结果表明：经高浓度氧化、高浓度还原条件处理的尾矿表现为pH<7的酸性环境,经低浓度氧化环境条件处理的尾砂呈现pH>7的弱酸性至弱碱性环境;尾砂中Cu、Cd元素活化迁移受pH值的影响明显,即高浓度还原和高浓度氧化条件可以促进Cu和Cd元素的迁移,酸性条件对Cu和Cd元素的迁移起到促进作用;Zn与Cd元素存在竞争吸附关系,但二者仍有明显差别;Pb和As元素受到还原条件的影响,能有效促进Pb和As元素的释放迁移。在淋滤实验前期,铅锌矿的表面阻力较小,由于环境酸碱性的改变,初始尾砂对重金属元素的吸附位能发生变化,重金属元素初期迁移能力得到加强;淋滤后期,矿物颗粒表面由于发生氧化还原反应,促使颗粒表面的阻力增加,重金属元素的溶出量减少,迁移能力受到抑制。     

Atténuation de l'intensité macrosismique pour la France métropolitaine : importance de l'intensité épicentrale

The main result of this work is to show that macroseismic intensity decay with distance strongly depends on the epicentral intensity. An attenuation law that takes this parameter into account is proposed for Metropolitan France, from the analysis of SISFRANCE macroseismic database. Such a model significantly reduces the difference between observed and theoretical intensities. A map of the attenuation variations is also set up for Metropolitan France. No major site effects are observed, but at a broad scale, young Alpine regions display a stronger attenuation than old Hercynian regions. To cite this article: P. Arroucau et al., C. R. Geoscience 338 (2006).     

冷冻管直径对冻土冻结影响规律的试验研究

近年来冻结施工方法越来越多地使用在城市土木工程施工中,但由于受冻土冻结理论基础的缺失和研究方法的局限,长时间以来人们对冻结法的设计始终没有找到较为理想的方案,参数变量选取遇到很大困难,同时在施工阶段没有较为标准统一的技术规范参照,使得该工法的实际应用往往出现工程量浪费、施工混乱和工程质量无保障等情况,而其中冷冻管直径是主要影响参数。通过同轴管土体冻结试验的研究,采用不同直径的冷冻管进行冻结试验,利用Fluent模型分析冻结过程的温度场分布规律,确定了最优冷冻管管径的选择方法,为冻结法的设计及施工提供依据。     

Early Estimation of Seismic Hazard for Strong Earthquakes in Taiwan

A shakemap system providing rapid estimates of strong ground shaking could be useful for emergency response providers in a damaging earthquake. A hybrid procedure, which combines site-dependent ground motion prediction models and the limited observations of the Real-Time Digital stream output system (RTD system operated by Central Weather Bureau, CWB), was set up to provide a high-resolution shakemap in a near-real-time manner after damaging earthquakes in Taiwan. One of the main factors that affect the result of ground motion prediction analysis is the existence of site effects. The purpose of this paper is to investigate the local site effects and their influence in the ground shaking and then establish an early estimation procedure of potential hazard for damaging earthquakes. Based on the attenuation law, the site effects of each TSMIP station are discussed in terms of a bias function that is site and intensity-level dependent function. The standard deviation of the site-dependent ground motion prediction model can be significantly reduced. The nonlinear behavior of ground soil is automatically taken into account in the intensity-level dependent bias function. Both the PGA and the spectral acceleration are studied in this study. Based on the RTD data, event correctors are calculated and applied to precisely estimate the shakemap of damaging earthquakes for emergency response.     

Time domain method for calculating free field motion of a layered half-space subjected to obliquely incident body waves

In numerical simulation of wave scattering under oblique incident body waves using the finite element method, the free field motion at the incident lateral boundary induced by the background layered half-space complicates the computational area. In order to replace the complex frequency domain method, a time-domain method to calculate the free field motion of a layered half-space subjected to oblique incident body waves is developed in this paper. The new method decouples the equations of motion used in the finite element method and offers an interpolation formula of the free field motion. This formula is based on the fact that the apparent horizontal velocity of the free field motion is constant and can be calculated exactly. Both the theoretical analysis and numerical results demonstrate that the proposed method offers a high degree of accuracy.     

Generalized flux law,with an application

A generalized flux law, which can specialize into power‐ and diffusive‐type flux laws, is proposed. When coupled with the continuity equation, a generalized flow equation is the result. The generalized equation specializes into several cases, one of which is the kinematic wave equation. By applying the generalized flow equation and its variants to flow routing in two rivers, the usefulness of the generalized flux law is evaluated. Copyright © 1999 John Wiley & Sons, Ltd.     

基于镭同位素分布的黄海和东海垂直混合速率计算

在黄海和东海采样测定了水体中的镭同位素分布,用平流扩散模型描述镭同位素分布,最小二乘方法计算了垂直涡动扩散系数和上升流或下降流流速.结果给出北黄海中部、南黄海中部、浙江沿岸和台湾北部海域存在上升流,流速分别为0.46×10-3cm·s-1、0.17×10-3~1.39×10-3cm·s-1、2.02×10-3~3.04×10-3 cm·s-1和1.06×10-3~2.51×10-3 cm·s-1.北黄海中部和东海东北部存在下降流.流速分别为-2.30×10-3 cm·s-1和-0.61×10-3~-2.10×10-3 cm·s-1.计算同时给出的垂直涡动扩散系数为5.84~48.2 cm2·s-1,平均值为22.3 cm2·s-1.北黄海和浙江沿岸上升流流速与文献的结果一致;北黄海中部存在下降流与文献的结论一致.本研究结果与文献结果一致是对所建立的方法的肯定,也是对文献研究结果的支持.     

龙门山断裂带上“破裂空段”的发震概率研究

本文采用分层粘弹性介质模型计算了汶川地震对芦山震中产生的库仑应力加载的影响,进而结合Dieterich(1994)提出的速率状态摩擦定律给出芦山附近区域6级地震累积发震概率随时间的变化。结果显示,2013年芦山7.0级地震时其累积发震概率达18%,说明汶川地震产生的应力扰动加速了芦山地震的发生。本文还计算了汶川、芦山2次地震对其间"破裂空段"处产生的累积库仑应力扰动的影响,结合背景地震发生率,给出了"破裂空段"处6级地震累积发震概率变化。虽然计算结果可能受到大邑地震、介质模型参数的选取和背景地震发生概率等因素影响而存在一定误差,但"破裂空段"在2次强震应力加载下累积发震概率是不断增大的,因此我们认为"破裂空段"处发生中强地震的紧迫性不断增强。