In situ estimation of the effective chemical diffusion coefficient of a rock matrix in a fractured aquifer

An in situ method of estimating the effective diffusion coefficient for a chemical constituent that diffuses into the primary porosity of a rock is developed by abruptly changing the concentration of the dissolved constituent in a borehole in contact with the rock matrix and monitoring the time-varying concentration. The experiment was conducted in a borehole completed in mudstone on the campus of the University of the Free State in Bloemfontein, South Africa. Numerous tracer tests were conducted at this site, which left a residual concentration of sodium chloride in boreholes that diffused into the rock matrix over a period of years. Fresh water was introduced into a borehole in contact with the mudstone, and the time-varying increase of chloride was observed by monitoring the electrical conductivity (EC) at various depths in the borehole. Estimates of the effective diffusion coefficient were obtained by interpreting measurements of EC over 34 d. The effective diffusion coefficient at a depth of 36 m was approximately 7.8×10^?6 m²/d, but was sensitive to the assumed matrix porosity. The formation factor and mass flux for the mudstone were also estimated from the experiment.     

华南海西—印支期成矿地质背景

华南海西—印支成矿期内,成矿序列完整,类型齐全,矿种繁多,为其它成矿期所莫及。沉积矿床需要稳定的地质背景,层控矿床形成的较有利的地质背景是稳中有动。     

地学“开合律”及其在造山带研究中的意义

“开合律”是地学辩证法基本规律之一。本文概述了它的内容与特点,阐明它在造山带研究中的意义及运用它指导造山带研究的步骤,并根据目前已总结的5种“开”、“合”类型相应地提出了5种造山带类型。     

Atténuation de l'intensité macrosismique pour la France métropolitaine : importance de l'intensité épicentrale

The main result of this work is to show that macroseismic intensity decay with distance strongly depends on the epicentral intensity. An attenuation law that takes this parameter into account is proposed for Metropolitan France, from the analysis of SISFRANCE macroseismic database. Such a model significantly reduces the difference between observed and theoretical intensities. A map of the attenuation variations is also set up for Metropolitan France. No major site effects are observed, but at a broad scale, young Alpine regions display a stronger attenuation than old Hercynian regions. To cite this article: P. Arroucau et al., C. R. Geoscience 338 (2006).     

The structure and dynamics of 2-dimensional fluids in swelling clays

The interlayer pores of swelling 2:1 clays provide an ideal 2-dimensional environment in which to study confined fluids. In this paper we discuss our understanding of the structure and dynamics of interlayer fluid species in expanded clays, based primarily on the outcome of recent molecular modelling and neutron scattering studies. Counterion solvation is compared with that measured in bulk solutions, and at a local level the cation-oxygen coordination is found to be remarkably similar in these two environments. However, for the monovalent ions the contribution to the first coordination shell from the clay surfaces increases with counterion radius. This gives rise to inner-sphere (surface) complexes in the case of potassium and caesium. In this context, the location of the negative clay surface charge (i.e. arising from octahedral or tetrahedral substitution) is also found to be of major importance. Divalent cations, such as calcium, eagerly solvate to form outer-sphere complexes. These complexes are able to pin adjacent clay layers together, and thereby prevent colloidal swelling. Confined water molecules form hydrogen bonds to each other and to the clays' surfaces. In this way their local environment relaxes to close to the bulk water structure within two molecular layers of the clay surface. Finally, we discuss the way in which the simple organic molecules methane, methanol and ethylene glycol behave in the interlayer region of hydrated clays. Quasi-elastic neutron scattering of isotopically labelled interlayer CH₃OD and (CH₂OD)₂ in deuterated clay allows us to measure the diffusion of the CH₃- and CH₂-groups in both clay and liquid environments. We find that in both the one-layer methanol solvates and the two-layer glycol solvates the diffusion of the most mobile organic molecules is close to that in the bulk solution.     

Early Estimation of Seismic Hazard for Strong Earthquakes in Taiwan

A shakemap system providing rapid estimates of strong ground shaking could be useful for emergency response providers in a damaging earthquake. A hybrid procedure, which combines site-dependent ground motion prediction models and the limited observations of the Real-Time Digital stream output system (RTD system operated by Central Weather Bureau, CWB), was set up to provide a high-resolution shakemap in a near-real-time manner after damaging earthquakes in Taiwan. One of the main factors that affect the result of ground motion prediction analysis is the existence of site effects. The purpose of this paper is to investigate the local site effects and their influence in the ground shaking and then establish an early estimation procedure of potential hazard for damaging earthquakes. Based on the attenuation law, the site effects of each TSMIP station are discussed in terms of a bias function that is site and intensity-level dependent function. The standard deviation of the site-dependent ground motion prediction model can be significantly reduced. The nonlinear behavior of ground soil is automatically taken into account in the intensity-level dependent bias function. Both the PGA and the spectral acceleration are studied in this study. Based on the RTD data, event correctors are calculated and applied to precisely estimate the shakemap of damaging earthquakes for emergency response.     

含水矿物在真空下的释Ar机制:Ar-Ar热年代学面临的新问题

地质体的实际情况、激光显微探针束研究、XRD和SEM观测以及真空加热下Ar的释放特征都表明体积扩散不是含水矿物在真空加热中释放Ar的唯一机制。在低温下 ,Ar的释放主要受由缺陷引起的短程扩散和体积扩散共同作用的多途径扩散机制制约 ;而在高温下 ,由于含水矿物在真空中不够稳定 ,Ar的释放受到脱羟基、脱氢、氧化反应、分层作用等造成的晶体结构改变的强烈影响。含水矿物在高温下的氧化分解会导致矿物中原始Ar浓度梯度的均一化 ,因而无法得到真实的Ar分布剖面 ,也无法据此计算矿物的封闭温度 ,并进而可能影响到ArAr年龄坪的地质意义。     

渤海湾盆地北部奥陶纪岩相古地理

渤海湾盆地北部主要包括黄骅坳陷、沧县隆起、冀中坳陷和下辽河坳陷,区内奥陶系厚 6 0 0～ 80 0m,主要由石灰岩和白云岩组成。下奥陶统分为冶里组和亮甲山组,中奥陶统分为下马家沟组、上马家沟组和峰峰组,上统缺失。其中下马家沟组、上马家沟组和峰峰组又进一步划分为下段和上段。早奥陶世冶里期和亮甲山期,本区以局限海环境为主,其内散布着一些潮坪和滩。中奥陶世,本区岩相古地理面貌变化旋回极为明显,下马家沟期早期潮坪广布,晚期以局限海为主;上马家沟期早期又是潮坪广布,晚期以开阔海为主;峰峰期早期潮坪广布,晚期又以开阔海为主。在奥陶纪,本区经历了 4个大的海侵-海退旋回,其中上马家沟期晚期是本区乃至整个华北地台的最大海侵期。     

地震次生毒气泄漏与扩散的数值模拟与动态仿真

文章对破坏性地震中可能发生的次生毒气泄漏与扩散灾害进行了数值模拟与动态仿真研究，设定了几种有实际意义的数值分析模型，分别进行了结构地震破坏，有毒有害气体泄漏，在一定泄漏和气象条件下的向周围空间扩散的动态仿真研究，给出了典型毒气扩散过程中可致人员死亡，严重危险和有感区域的范围的动态变化结果，作者认为地震次生毒气泄漏与扩散研究对大地震应急、城市和大型企业防灾都有重要的意义和广阔的应用前景。     

多矿物岩石流变规律的研究进展及存在问题

总结了近年来由多种矿物组成的岩石的流变规律的研究，阐述了多矿物岩石流变性质研究的意义和进展，再从实验和理论两个方面，详细论述了目前最具代表性的三种理论模型，算术平均方法、几何平均方法和能量极小方法，最后，指出这方面研究仍然存在的问题和进一步研究的方向。