金刚石粒度对孕镶金刚石钻头性能的影响

孕镶金刚石钻头已获得了广泛的应用,但人们对其性能和钻头金刚石参数间的一些问题仍需进一步认识。本文通过理论计算得出了钻头唇面上金刚石的分布模型,其结论与实际相吻合;并以此为依据,探讨了金刚石粒度对钻头性能的影响      

基于Web的金刚石钻头模具钢体设计

介绍了应用网页技术进行金刚石钻头模具钢体设计计算的方法。该方法丰富了模具钢体设计的远程教育,免去了传统人工求解的繁杂过程,界面友好,精度高,结果可靠,具有实际使用价值。      

Prograde pressure–temperature records from inclusions in zircons from ultrahigh-pressure–high-pressure rocks of the Kokchetav Massif, northern Kazakhstan

Abstract In the first extensive, systematic study of inclusions in zircons from ultrahigh-pressure (UHP) and high-pressure (HP) metamorphic rocks of the Kokchetav Massif of Kazakhstan (separated from 232 rock samples from all representative lithologies and geographic regions), we identified graphite, quartz, garnet, phengite, phlogopite, rutile, albite, K-feldspar, amphibole, zoisite, kyanite, calcite, dolomite, apatite, monazite, omphacite and jadeite, as well as the diagnostic UHP metamorphic minerals (i.e. microdiamond and coesite) by laser Raman spectroscopy. In some instances, coesite + quartz and diamond + graphite occur together in a single rock sample, and inclusion aggregates also comprise polycrystalline diamond crystals overgrowing graphite. Secondary electron microscope and cathodoluminescence studies reveal that many zircons display distinct zonation textures, which comprise core and wide mantle, each with distinctive inclusion microassemblages. Pre-UHP metamorphic minerals such as graphite, quartz, phengite and apatite are common in the core, whereas diamond, coesite, garnet and jadeite occupy the mantle. The inclusions in core are irrelevant to the UHP metamorphism. The zircon core is of detrital or relatively low-grade metamorphic origin, whereas the mantle is of HP to UHP metamorphic origin. The zonal arrangement of inclusions and the presence of coesite and diamond without back-reaction imply that aqueous fluids were low to absent within the zircons during both prograde and retrograde metamorphism, and that the zircon preserves a prograde pressure–temperature record of the Kokchetav metamorphism which, elsewhere, has been more or less obliterated in the host rock.     

Overview of the geology, petrology and tectonic framework of the high-pressure–ultrahigh-pressure metamorphic belt of the Kokchetav Massif, Kazakhstan

Abstract High‐ to ultrahigh‐pressure metamorphic (HP–UHPM) rocks crop out over 150 km along an east–west axis in the Kokchetav Massif of northern Kazakhstan. They are disposed within the Massif as a 2 km thick, subhorizontal pile of sheet‐like nappes, predominantly composed of interlayered pelitic and psammitic schists and gneisses, amphibolite and orthogneiss, with discontinuous boudins and lenses of eclogite, dolomitic marble, whiteschist and garnet pyroxenite. On the basis of predominating lithologies, we subdivided the nappe group into four north‐dipping, fault‐bounded orogen‐parallel units (I–IV, from base to top). Constituent metabasic rocks exhibit a systematic progression of metamorphic grades, from high‐pressure amphibolite through quartz–eclogite and coesite–eclogite to diamond–eclogite facies. Coesite, diamond and other mineral inclusions within zircon offer the best means by which to clarify the regional extent of UHPM, as they are effectively sequestered from the effects of fluids during retrogression. Inclusion distribution and conventional geothermobarometric determinations demonstrate that the highest grade metamorphic rocks (Unit II: T = 780–1000°C, P = 37–60 kbar) are restricted to a medial position within the nappe group, and metamorphic grade decreases towards both the top (Unit III: T = 730–750°C, P = 11–14 kbar; Unit IV: T = 530°C, P = 7.5–9 kbar) and bottom (Unit I: T = 570–680°C; P = 7–13.5 kbar). Metamorphic zonal boundaries and internal structural fabrics are subhorizontal, and the latter exhibit opposing senses of shear at the bottom (top‐to‐the‐north) and top (top‐to‐the‐south) of the pile. The orogen‐scale architecture of the massif is sandwich‐like, with the HP–UHPM nappe group juxtaposed across large‐scale subhorizontal faults, against underlying low P–T metapelites (Daulet Suite) at the base, and overlying feebly metamorphosed clastic and carbonate rocks (Unit V). The available structural and petrologic data strongly suggest that the HP–UHPM rocks were extruded as a sequence of thin sheets, from a root zone in the south toward the foreland in the north, and juxtaposed into the adjacent lower‐grade units at shallow crustal levels of around 10 km. The nappe pile suffered considerable differential internal displacements, as the 2 km thick sequence contains rocks exhumed from depths of up to 200 km in the core, and around 30–40 km at the margins. Consequently, wedge extrusion, perhaps triggered by slab‐breakoff, is the most likely tectonic mechanism to exhume the Kokchetav HP–UHPM rocks.     

山东省金刚石深部找矿成果及技术进展

自原国土资源部等四部委发布《找矿突破战略行动纲要（2011—2020年)》,山东加强了对蒙阴金刚石原生矿深部及外围的勘查,深部及外围找矿工作取得丰硕成果,并在金刚石找矿方法和综合研究方面取得改进和新认识。本文总结了10年来山东省第七地质矿产勘查院金刚石找矿成果,蒙阴常马庄和西峪金刚石原生矿深部钻探控制至1000m,新增金刚石矿物量550万ct,改进了金刚石原生矿重砂矿物组合和粒级,完善了金刚石找矿方法和选矿方法,对金刚石成矿理论取得新认识,并在深部新发现含金刚石的金伯利岩管,在蒙阴金刚石原生矿外围发现了含金刚石的煌斑岩,查明了费县朱田大井头岩管为含金刚石的钾镁煌斑岩岩管。编制了《矿产地质勘查规范金刚石》,填补了我国没有《金刚石矿勘查规范》的空白,对我国今后的金刚石矿勘查具有重要的指导作用。     

热液金刚石压腔(HDAC)高温高压实验平台简介

热液金刚石压腔(HDAC)高温高压实验平台是在金刚石压腔的基础上发展起来的一种高温高压原位实验模拟设备.近年来,HDAC技术已经在地质科研领域取得了大量成果,多篇重要研究成果被《Science》《Nature》等知名期刊刊发.本文介绍了HDAC高温高压实验平台结构与组成、实验优势和应用前景.     

风城碱性杂岩与有关含金刚石岩类对比的意义

迄今为止,对金刚石矿床的研究已取得了新的进展,国内外学音认为:“金伯利岩不是金刚石矿床的唯一母岩”,并且在碱性杂岩体中发现了许多具有工业价值的金刚石矿床。 通过对比辽宁凤城碱性杂岩与有关含金刚石矿床母岩(主要是钾镁煌斑岩)及其共生岩类的构造背景、岩石类型组合、矿物成分组合及岩石的主元素、微量元素和稀土元素特征,发现本区碱性杂岩体岩石与西澳钾镁煌斑岩很相似,尤其是与西澳白榴石钾镁煌斑岩最为接近,而在岩石类型和矿物组合特点上,又与美国阿肯色碱性岩区金刚石矿床母岩及其共生岩类组合颇为相似,这为我们进一步找寻金刚石矿床提供某些有益的信息。     

超高压变质带金刚石研究进展

金刚石在自然界中非常稀缺,是极其珍贵的矿产资源。其中,变质成因的金刚石陆续在世界范围内多个超高压变质带被发现,更新了人们对超高压变质作用和板块构造运动的认识,推动了超高压变质带动力学的研究,引起了学术界的广泛关注。然而,对于变质成因金刚石的形成机制,还未形成一致的认识。本文在综述前人研究成果的基础上,介绍了金刚石形成的大地构造背景,研究了其形成所需的地质环境和物理化学条件,并着重对超高压变质带金刚石成因机制进行了探讨,全面分析了温压条件、XCO2、fO2对变质成因金刚石形成的影响。对比发现,当变质作用的峰期压力达到金刚石稳定域且具有较高的温度时(压力>3 GPa,温度为600~1000℃),有利于金刚石的形成,C-O-H流体中的较高CO2含量和较低氧逸度也是超高压变质带金刚石形成的必需因素。另外,金刚石形成后折返早期的降温作用有利于其保存。     

CVD合成钻石的层状生长结构和紫外荧光特征

最近NGTC实验室检测出多批次CVD合成钻石,这些CVD合成钻石均具有明显的鉴定特征,使用钻石观测仪（DiamondViewTM）观察可见蓝色、橙红色荧光和蓝色磷光以及细密层状生长纹理,光致发光光谱中可见737 nm处的特征发光线.这些特征均与其生长结构及生长过程中进入钻石晶体中的杂质有关.笔者以最近检测过程中发现的一颗CVD合成钻石为例,使用高倍率显微技术对其层状结构的微细特征及其在钻石观测仪下的荧光特征的关系进行了详细观察和对比.结果显示,此样品与之前检测到的CVD合成钻石略有差异.此次检测到的样品在钻石观测仪（DiamondViewTM）下观察具有较宽的层状生长分区,层与层之间的分界线十分明显且在高倍显微镜下也可见到细微的生长特征.通过对样品特征的分析,了解了晶体生长过程中多阶段生长条件的变化,更直观的展现了CVD合成钻石的生长过程.     

金刚石呈色机制的新观点

已知金刚石中能产生颜色的点缺陷(即色心)主要有氮、硼、空穴、填隙子以及各种形式的氮与空穴的复合体。随着各种现代微束与谱学分析技术以及量子化学计算的应用，对金刚石晶格中氮、硼以外的杂质—氢与过渡金属离子的赋存状态的研究，我们发现了新的致色点缺陷：成键氢，镍、钴离子，及其与氮的复合体，从而形成了氢致色与过渡金属离子致色的金刚石呈色机制的新观点。