Topographical controls on small‐volume pyroclastic flows

Emplacement of small‐volume (<0·1 km³) pyroclastic flows is significantly influenced by topography. The Arico ignimbrite on Tenerife (Canary Islands) is a characteristic small‐volume pyroclastic flow deposit emplaced on high relief topography. The pyroclastic flow flowed down pre‐existing valleys on the southern slopes of the island. In proximal areas deep (up to 100 m) valleys acted as efficient conduits for the pyroclastic flow, which was mostly channelled; in this particular area the ignimbrite corresponds to a homogeneous, moderately welded deposit, consisting of flattened pumices in an abundant ashy matrix with a relatively low lithic fragment content. In intermediate zones significant changes occur in the steepness of the slope and, although still channelled, here the pyroclastic flow was influenced by hydraulic jumps. In this area, two different units can be clearly distinguished in the ignimbrite: the lower unit is composed of a lithic‐rich ground‐layer deposit that formed at the turbulent, highly concentrated head of the flow; the upper unit consists of a well welded pumice‐rich deposit that occasionally reveals a basal layer formed by shearing with the lower part. This division into two units is maintained as far as distal areas near the present‐day coastline, where the slope is very gentle or null and the ignimbrite is not channelled. The ground layer is not found in distal areas. The ignimbrite here only consists of the upper unit, which is occasionally repeated due to a surging process provoked by the lower flow speed, as the pyroclastic flow spread out of the channelled zone. A theoretical model on how topography controlled the deposition of the Arico ignimbrite is derived by interpreting the observed lithological and sedimentological variations in terms of changes in topography and bedrock morphology. This new model is of general applicability and will help to explain other deposits of similar characteristics.     

Methodological aspects of surveying the volume, structure, activities and perceptions of city centre visitors

Counting pedestrians on a street and visitors entering a store is a method used to measure the attractiveness of these places. Their volumes are governed by daily, weekly, monthly and yearly cycles and are subject to random influences. This must be taken into account especially where comparison counts reveal changes. When single streets or stores are counted, it must be ascertained whether this figure is representative of the whole city centre and its retailing. Pedestrian volumes can be used for adjusting interview samples to the distribution in time and space of the city centre visitors. Counts of the qualitative characteristics of the pedestrian with respect to composition of groups reveal that surveys among pedestrians are biased in relation to the size of the group. Special attention in surveys should be given to the linking of activities. Whereas much emphasis is given to the accessibility of the city centre from outside, the ‘inner accessibility’ of the city centre is just as important. Long distances are often walked and many destinations visited. This is best recorded by conducting interviews at public transport stops and car parks. The attractiveness of the city centre depends not only on its physical structures but very much on the subjective perception of them; therefore judgements on accessibility, goods and services offered and the urban ambiance should be recorded. Retailer's attitudes concerning the qualities of the city centre should also be compiled for comparison. This revised version was published online in July 2006 with corrections to the Cover Date.     

A Eulerian air pollution model for Europe with nonlinear chemistry

A long-range transport model with nonlinear chemical reactions is described. The model contains 35 pollutants and 70 chemical reactions. This is a Eulerian model defined on a space domain containing the whole of Europe. The spherical space domain (corresponding to the Earth's surface covered by the model) is mapped into a square plane domain and discretized by using a 32×32 grid. The grid increments are equidistant (both along the Ox axis and along the Oy axis). The choice of values of the physical parameters involved in the model and the numerical treatment of the model are shortly discussed. The model is tested with meteorological data for 1985 and 1989. The numerical results are compared with measurements at stations located in different European countries. Extensive comparisons of ozone concentrations for July 1985 with measurements taken at 24 European stations are also carried out. Results concerning three episodes in July 1985 as well as results obtained in the study of the sensitivity of the ozone concentrations to variations of NO _x and/or anthropogenic VOC emissions are presented. The advantages and the limitations of such a model are discussed. The model is continuously improved by adding new modules to it. The plans for improvements in the near future are outlined.     

Studies on Intercorrelation between Ions Co-Occurring in Precipitation in the Gdańsk-Sopot-Gdynia Tricity (Poland)

The paper presents monitoring results and environmental pollution assessment for the Gdask-Sopot-Gdynia Tricity (Poland), based onanalysis of precipitation. Precipitation samples were collected over a period of 12 months (January–December 1998) at ten locations in the Tricity. The following selected ions were determined in the samples:SO₄ ^2–, F^–, Cl^–, NO₃ ^–,PO₄ ^3–, NH₄ ⁺, Na⁺,Mg²⁺, Ca²⁺, K⁺. The results were subjected to full statistical evaluation. Values of the parameters determined were correlated with each other. An attempt was made to explain co-occurrences of certain ions and the significance of their mutual effects. Pollutant concentrations and loads in precipitation were also correlated with data on wind direction and temperature in the region.Deposition of pollutants was very high in spring due to the prevailing air circulation patterns and low temperatures. Analysis of the correlations between co-occurring ions confirmed the significant impact of the location (sea coast) on the composition of rain water. Ionic ratios in rainwater were similar to those observed for sea salt samples. In addition, heavy traffic was most probably responsible for high concentrations of various forms of nitrogen and sulphates in the vicinity of major highways.     

A Study of DMS Oxidation in the Tropics: Comparison of Christmas Island Field Observations of DMS, SO2, and DMSO with Model Simulations

This study reports comparisonsbetween model simulations, based on current sulfurmechanisms, with the DMS, SO₂ and DMSOobservational data reported by Bandy et al.(1996) in their 1994 Christmas Island field study. For both DMS and SO₂, the model results werefound to be in excellent agreement with theobservations when the observations were filtered so asto establish a common meteorological environment. Thisfiltered DMS and SO₂ data encompassedapproximately half of the total sampled days. Basedon these composite profiles, it was shown thatoxidation of DMS via OH was the dominant pathway withno more than 5 to 15% proceeding through Cl atoms andless than 3% through NO₃. This analysis wasbased on an estimated DMS sea-to-air flux of 3.4 ×10⁹ molecs cm^-2 s^-1. The dominant sourceof BL SO₂ was oxidation of DMS, the overallconversion efficiency being evaluated at 0.65 ± 0.15. The major loss of SO₂ was deposition to theocean's surface and scavenging by aerosol. Theresulting combined first order k value was estimated at 1.6 × 10^-5 s^-1. In contrast to the DMSand SO₂ simulations, the model under-predictedthe observed DMSO levels by nearly a factor of 50. Although DMSO instrument measurement problems can notbe totally ruled out, the possibility of DMSO sourcesother than gas phase oxidation of DMS must beseriously considered and should be explored in futurestudies.     

论雾与污染的关系

简述了近年来雾的研究进展，并从雾的酸化、雾层内污染物的扩散、雾层对污染物的清除、污染物对雾形成与发展的影响等方面讨论了雾与大气污染的关系。     

天津市空气污染数值预报试验中的模式系统

介绍了天津市空气污染数值预报实验中城市空气污染数值预报模式系统的构成及各模块的功能。在天津市空气污染预报实验期间, α中尺度气象模式对区域范围内的逐时风、温、湿及其降水预报取得了较好的效果, 且模式的计算时间短; β中尺度气象模式在边界层内具有较高的垂直分辨率, 模拟结果合理, 其中计算与观测的风向差小于６０ｏ的概率达到６４３％ , 计算与观测的风速比值接近于１; 预报的地面ＳＯ２、ＮＯｘ和ＴＳＰ浓度与同步监测值相比, 城市空气污染预报模式对ＳＯ２和ＮＯｘ的日平均浓度的预报效果较好, 预报准确率达６４０％ , 而对ＴＳＰ的预报则较差     

A STUDY ON THE FLOOD STORAGE CAPACITY IN DONGTING LAKE

1 INTRODUCTION Dongting Lake lies south of the middle reach of the Yangtze River in Hunan and Hubei provinces (Fig. 1). On the north side of Dongting Lake, there are the three diversion openings of the Yangtze River named Songzi, Taiping, and Ouchi, and, on the south and west sides, there are the four tributary streams named Xiang, Zi, Yuan, and Li Rivers. The flow of the three diversion openings and the four tributary streams runs into Dongting Lake, and runs out at Chenglingji a…     

Scaling and correlation of atmospheric acid deposition evolutions

Detrended fluctuation analysis (DFA) and power spectrum density are applied to verify the presence of temporal scaling behavior and long-range persistence (LRP) of weekly hydrogen ion deposition (WHD), NO₃^- and SO₄^2- deposition series in National Atmospheric Deposition Program, USA, for the period 1978–2001. The results show a common scaling behavior for all sites analyzed. Two distinct scaling regions are identified by DFA1, one corresponding to 1 month to 1 year and the other to 1 year to 5 years. The WHD series obey power-law in two temporal regimes respectively with mean DFA1 scaling exponents α ₁≈0.68 and α ₂≈0.45, implying the presence of LRP in the acid deposition series and there is a tendency for a large deposition event to be followed by another large event, and vice versa. For DFA2–DFA4, however, the annual crossover, which divides the temporal scale into two regimes, disappears gradually with the order q of DFAq increasing, and the two scaling regimes turn to share the same scaling exponent close to α ₁. The result indicates that the scaling behavior exits in the two regimes with the same scaling exponent α ₁, and LRP prevails during the examined 1-month to 5-years scale. NO₃^- and SO₄^2- deposition evolve the same way as WHD does, implying the pollutants involving in acid deposition may share some prominent mechanism controlling their evolutions. We ascribe the long-range power-law scaling of acid deposition evolutions to the self-organized critical behavior of atmosphere under pollution stress and it should be considered in the trend prediction of acid deposition as an important factor.     

Floodplain sedimentation and sensitivity: summer 1993 flood,Upper Mississippi River Valley

Patterns of overbank sedimentation in the vicinity of, and far removed from, levee breaks that occurred in response to the >100 year, summer 1993 flood in the upper Mississippi River valley are elucidated. Two suites of overbank deposits were associated with the failure of artificial levees within a 70 km long study reach. Circumjacent sand deposits are a component of the levee break complex that develops in the immediate vicinity of a break site. As epitomized by the levee break complex at Sny Island, these features consist of an erosional, scoured and/or stripped zone, together with a horseshoe-shaped, depositional zone. At locales farther removed from the break site, the impact of flooding was exclusively depositional and was attributed to the settling of suspended sediment from the water column. The overall picture was one of modest scour at break sites and minimal suspended deposition (<4 mm) at locales farther removed from the breach. Downriver from the confluence with the Missouri River, suspended sediment deposition was of a similar magnitude to that observed within the study reach and levee break complexes exhibited a similar morphology, but scour at break sites was greatly enhanced and the excavated sand formed extensive deposits on the floodplain surface. The different erosional response was probably engendered by the higher sand content and reduced aggregate cohesion of the floodplain soils downriver from the confluence with the Missouri River. A qualitative comparison serves to highlight the influence that the resistance threshold may have on the sensitivity of floodplains bordering large low-gradient rivers to high magnitude floods. © 1997 John Wiley & Sons, Ltd.