Experimental Simulation Study of the Dominant Enrichment Area of Terrestrial Organic Matter in the Shallow-Delta Sedimentary System of the Yacheng Formation in the Qiongdongnan Basin

Shallow-delta sedimentary systems receive both terrestrial and marine organic matter. As oil and gas exploration activities determine that the source rocks of the deep-water area of the Qiongdongnan Basin, northern South China Sea, are generally rich in and even dominated by terrestrial organic matter, this has led many researchers to examine the rules governing terrestrial organic matter enrichment in shallow-delta sea sedimentary systems. However, the deep burial of source rocks in deep-water areas and the relatively small amount of drilling undertaken have greatly restricted the study of these rules. In this study, the ‘forward modeling’ research method was used to observe and analyze the deposition and preservation of terrestrial organic matter through flume experiments, where the depositional results were carefully depicted and sampled. The total organic carbon content of selected samples was measured and when combined with qualitative observations and quantitative comparison results, the dominant enrichment areas of terrestrial organic matter were identified. The experimental results show that the overbank parts of the delta front, the dune countercurrent surface, the low-lying parts, the delta front slope area and the shallow-prodelta sea area are where terrestrial organic matter is predominantly enriched. This provides an important basis and guidance for the prediction of the development areas of marine source rocks with terrestrial input in the deep-water areas of the Qiongdongnan Basin.     

Prediction of Shale Gas Pressure based on Multi-channel Seismic Inversion in Fuling

The accurate prediction of formation pressure is important in oil/gas exploration and development. However, the achievement of this goal remains challenging, due to insufficient logging data and the low predictive data accuracy from seismic data. In this work, a case study was carried out in the Baima area of Wulong, in order to develop a workflow for accurately predicting shale gas formation pressure. The multi-channel stack method was first used, as well as the inversion of single-channel seismic data, to construct velocity and density models of the formation. Combined with the existing well-logging data, the velocity and density models of the whole well section were established. The shale gas formation pressure was then estimated using the Eaton method. The results show that the multi-channel seismic stacking method has a higher accuracy than the inversion of the formation velocity obtained by the single-channel seismic method. The discrepancies between our predicted formation pressure and the actual formation pressure measurement are within an acceptable range, indicating that our workflow is effective.     

Crustal Electrical Structure and Deep Metallogenic Potential in Northern Wuyi Area (South China), based on Magnetotelluric Data

The northern Wuyi area, which is located in the northern Wuyi metallogenic belt, has superior mineralization conditions. The Pingxiang–Guangfeng–Jiangshan–Shaoxing fault (PSF) extends across the whole region regardless of whether or how the PSF relates to the near-surface mineralization. We carried out an MT survey in the region and obtained a reliable 2D model of the crustal electrical structure to a depth of 30 km. In the resistivity model, we inferred that a continuous high conductivity belt that ranges from the shallow to deep crust is a part of the PSF. Then, we estimated the fluid content and pressure gradient to identify the deep sources of fluid as well as its pattern of motion pattern. Finally, we proposed a model for the deep metallogenic migration processes that combines geological data, fluid content data, pressure gradient data, and the subsurface resistivity model. The model analysis showed that the Jiangnan orogenic belt and the Cathaysia block formed the PSF during the process of com. The deep fluid migrated upward through the PSF to the shallow crust. Therefore, we believe that the PSF is an ore-forming fluid migration channel and that it laid the material basis for large-scale mineralization in the shallow crust.     

Distribution Patterns of Calcite Cement in the Turbidite Sandstones of the Shahejie Formation in the Dongying Depression, Eastern China

Calcite cements are volumetrically dominant among the most diagenetic constituents in turbidite sandstones of the Paleogene Shahejie Formation in the Dongying Depression. The results show carbonate cements mainly occur in three phases: Calcite I (pre-compaction), Calcite II (post-compaction) and ankerite in the turbidite sandstone. The isotopic composition of Calcite I and Calcite II range from ?4.3‰ to 4.4‰, ?3.5‰ to 4.3‰ PDB, respectively, suggesting that the calcite cements are mainly derived from the interbedded shales. The early calcite cement precipitated from the mixing of lacustrine and meteoric waters at 38–69°C. The late-phase calcite precipitated from pore waters modified by water-rock interactions at 64–126°C. Two distribution patterns of calcite cements can be identified, depending on their position within the sandstone. The peripheral cementation of the sandstones is near the sand-shale contact. The development of cement is controlled by sandstone thickness and the properties of the interbedded shale. For scattered cementation, the distribution of the calcite cement is not controlled by the sand-shale contact. Calcite cement was preferentially distributed in coarse-grained sandstones, indicating that sandstones with high original permeability are the preferred pathway for the migration of early diagenetic fluids.     

矿用钻孔超声流量自适应检测技术

为了更好地实现煤矿井下瓦斯抽采钻孔端流量监测,针对管路内介质成分复杂、纯净度差、稳定性差等因素对抽采流量参数测量准确性影响的问题,提出以时差法为测量原理,以双阈值比较法为检测方法,设计了一套矿用钻孔超声流量自适应检测系统。通过分析影响双阈值比较法测量准确性的关键问题出发,设计了检测系统的总体方案,并对其中激励信号放大电路、接收信号调理电路及由峰值检波电路与增益控制电路构成的自适应电路几项关键模块进行了详细地介绍,叙述了检测系统运行软件的工作流程。通过工况环境适应能力测试与准确度性能检验,对检测系统的功能与性能进行了检验,检验结果表明,该系统能够适应瓦斯抽采钻孔管路内的工况需求,实现高精度的气体流量测量。      

基坑开挖对涉支护结构下穿盾构隧道变形的三维模拟与影响规律研究

依托某大厦基坑支护工程项目,研究深厚软土地层中基坑开挖对涉支护结构下穿盾构隧道变形的影响规律。采用三维有限元数值模拟分析隧道顶部支护桩的长度对支护结构变形和隧道隆起的影响,并将数值模拟结果与现场监测结果进行对比。结果表明：深厚软土地层中基坑开挖对下穿盾构隧道产生了较大的隆起变形;因下穿隧道的影响,隧道顶部支护桩嵌固深度的减小对支护结构的变形和下穿隧道的隆起会产生重要影响,当支护桩底与隧道顶的竖向间距S＞4 m或支护桩边缘与隧道边缘的水平间距S1＞4 m 时,支护桩的踢脚位移和下穿隧道的隆起变形迅速增加。研究成果可为类似工程提供应用参考和理论支撑。     

基于深部地球物理信息的构造变形岩相分类研究

“构造变形岩相”填图方法的创立和应用为老矿区深部及外围的找矿工作指明了方向,在实践中取得了显著的效果,需要大力推广和深入研究。对于构造变形岩相带的深部结构认识,需要依靠地球物理信息的解译。与地球物理场性质相类似,构造变形岩相带也是一个现存的地质体;物探工作目的是要探测和揭示构造变形岩相带的埋深、轮廓、内部结构构造等特征,为确定其形成时间和演化过程提供依据。由于地质与地球物理的复杂时空关系,如果仅以新鲜岩石标本物性参数的差异作为判别标志,难以提高地球物理方法的分辨率和有效性。结合构造变形岩相进行综合解译,更能提高解释推断成果的多学科融合性。作为终极勘探目标,需要紧密结合构造控矿级序,建立构造变形岩相带的三级分类标准,提取对应的地球物理信息:一级构造变形岩相带为目标物所处的构造单元及构造应力场,及其所对应的区域地球物理场特征,如隆凹构造相间的伸展构造域;二级构造变形岩相带为目标物所处的控矿构造体系,及其所对应的矿田地球物理场特征,如岩浆核杂岩隆起-拆离构造系统;三级构造变形岩相带为目标物所在的有利成矿构造部位,及其所对应于关键剖面的地球物理特征,如侵入岩体与围岩的接触带或者含矿断裂带等。选择国际流行的典型金属矿床类型,介绍了三级构造变形岩相带的地球物理组合信息特征及其分级利用操作流程,为有效应用地球物理勘探方法开展深部找矿预测提供了范例。     

天津平原区加油站地下水石油烃污染特征及其生物降解机理研究

加油站地下水中石油烃污染是较为普遍的现象,本文对研究区位于不同水文地质条件的加油站地下水进行取样分析,分析加油站地下水中石油烃的污染特征和地下水化学类型特征,并运用因子分析、相关性分析和多元回归分析揭示加油站地下水中石油烃潜在的生物降解机制。研究结果表明,地下水化学类型主要可划分为Cl-Na型、HCO₃-Na型、HCO₃-Ca型和SO₄-Na型4类。加油站地下水中石油烃的检出率为85.71%,检出浓度为0.020.35 mg/L。因子分析结果表明影响地下水化学组成的因素主要以水-岩相互作用和石油烃的生物降解为主。TPH与地下水化学指标间的相关关系表明:TPH与K⁺、Na⁺、Cl^-、Mn、Mg²⁺、 {\mathrm{SO}}_4^{2-}呈现负相关的关系,与pH值、 {\mathrm{HCO}}_3^{-}、 {\mathrm{NO}}_3^{-}、 {\mathrm{NO}}_2^{-}、Ca²⁺、Fe不存在显著的相关关系。加油站地下水环境中可能存在嗜盐或耐盐微生物,导致随着盐度的升高,总石油烃(total petroleum hydrocarbon,TPH)生物降解率加快,TPH浓度呈现出降低的趋势。微生物利用电子受体( {\mathrm{SO}}_4^{2-}、Mn、 {\mathrm{NO}}_3^{-}、Fe)降解TPH的过程中,电子受体的贡献率为:铁还原(64.88%)>锰还原(24.86%)>硫酸根还原(5.78%)>硝酸盐还原(4.46%),即加油站地下水中铁锰还原菌的石油烃生物降解为优势反应。     

大兴安岭中段林西组砂岩LA-ICP-MS碎屑锆石U-Pb年代学及其地质意义

大兴安岭中段扎赉特旗西北部分布大面积的晚二叠世林西组沉积地层,该沉积地层主要为长石砂岩、粉砂岩、长石岩屑砂岩夹不同规模的含砾砂岩及灰岩,中部含有较为丰富的双壳类、植物化石。本次研究针对林西组下部的长石岩屑砂岩进行LA-ICP-MS碎屑锆石U-Pb测年工作,共获得98个有效年龄,年龄分布范围为（2 552.3±22.5）~（227.6±5.4）Ma,大部分年龄位于谐和曲线上,部分结果偏离曲线,根据测试数据按年龄值和频率分布特征大致分为以下几组：上泥盆世—晚二叠世（380.0~246.1 Ma）、志留纪—寒武纪晚期（489.0~413.8 Ma）、中元古代—新元古代（1 239.5～808.1 Ma）、古元古代（2 554.0～1 784.3 Ma）。上述年龄与区域上的岩浆事件基本吻合。综合研究表明研究区内林西组沉积下限为（253.4±1.5） Ma,林西组的物源主体应来自于西拉木伦河—延吉一线,其余锆石来源主要为兴蒙造山带内部、华北板块北缘和东北各地块,1.8和2.5 Ga的碎屑锆石更有可能来自华北板块北缘,华北板块和西伯利亚板块在（253.4±1.5） Ma之前已经完成碰撞、拼合,古亚洲洋已经闭合,兴蒙海槽形成。林西组海相核形石的发现表明晚二叠世大兴安岭中段地区应以海相环境为主,直到三叠纪早期才逐渐转变为陆相沉积环境。     

鄂西宜昌斜坡带五峰组—龙马溪组页岩优势岩相及其生气潜力

【研究目的】不同页岩岩相的矿物组分、含气性和可压性等的差异,决定不同岩相的开发潜力不同,页岩岩相的划分及评价对找寻页岩气勘探开发甜点具有重要指导意义。【研究方法】基于钻井、岩心和分析测试资料,综合利用地质理论结合硅质矿物-黏土矿物-碳酸盐矿物含量三端元图解,对鄂西宜昌斜坡带上奥陶统五峰组—下志留统龙马溪组下段含气页岩岩相进行划分,结合有机碳含量、含气量、岩心镜下特征等划分优势岩相。优选有机质丰度、硅质矿物含量、黏土矿物含量3项指标与页岩含气量进行相关性分析,建立了五峰组—龙马溪组含气页岩优势岩相的分级标准。【研究结果】研究区优势岩相均为II类优势岩相,II₁类（最优）优势岩相为S-2混合硅质页岩相和S-3含黏土硅质页岩相,位于龙马溪组一亚段和五峰组上段,厚6 m;II₂类（次优）优势岩相为S硅质页岩相,位于五峰组下段,厚4 m。【结论】宜昌斜坡带和涪陵地区具有相似的岩相垂向演化序列,优势岩相均位于五峰组—龙马溪组一亚段,但同一岩相组合的页岩厚度和品质差异较大,发生在鲁丹阶早期的湘鄂西水下隆起和鲁丹阶晚期的水下隆起是造成宜昌地区优势岩相的厚度和品质均要差于涪陵地区的主要原因。创新点：建立五峰组—龙马溪组含气页岩优势岩相的分级标准,提出龙马溪组一亚段和五峰组是优势岩相发育层位。