Origin and depositional environments of source rocks and crude oils from Niger Delta Basin: Carbon isotopic evidence

Thirty-nine crude oils and twenty-one rock samples from Niger Delta Basin, Nigeria have been characterized based on their isotope compositions by elemental analysis-isotope ratio mass spectrometry and gas chromatography-isotope ratio mass spectrometry. The bulk carbon isotopic values of the whole rock extracts, saturate and aromatic fractions range from –28.7‰ to –26.8‰, –29.2‰ to –27.2 ‰ and –28.5 ‰ to –26.7 ‰, respectively while the bulk carbon isotopic values of the whole oils, saturate and aromatic fractions range from –25.4 ‰ to –27.8 ‰, –25.9 ‰ to –28.4 ‰ and –23.5 ‰ to –26.9 ‰, respectively. The average carbon isotopic compositions of individual alkanes (nC₁₂-nC₃₃) in the rock samples range from –34.9‰ to –28.2‰ whereas the average isotopic values of individual n-alkanes in the oils range from –31.1‰ to –23.8‰. The δ¹³C isotope ratios of pristane and phytane in the rock samples range from –29.2 ‰ to –28.2 ‰ and –30.2 ‰ to –27.4 ‰ respectively while the pristane and phytane isotopic values range from –32.1‰ to –21.9‰ and –30.5‰ to –26.9‰, respectively. The isotopic values recorded for the samples indicated that the crude oils were formed from the mixed input of terrigenous and marine organic matter and deposited under oxic to sub-oxic condition in lacustrine-fluvial/deltaic environments. The stable carbon isotopic compositions were found to be effective in assessing the origin and depositional environments of crude oils in the Niger Delta Basin.     

曹妃甸填海工程阻断浅滩潮道初期老龙沟深槽的地形变化

通过研究1992、1997、2006年的测深资料,对比分析了横切老龙沟深槽口门处的地形横剖面和大致沿老龙沟深槽轴线的地形纵剖面,可知在此期间深槽内的水深有变浅和淤积的趋势。总体看来,老龙沟深槽的淤积厚度在0.61~4.8 m之间,并且老龙沟深槽轴线也有自东向西迁移的趋势。自2004年曹妃甸填海工程的通岛公路阻断浅滩潮道后,使老龙沟深槽内的潮流流量和流速减小,是引起老龙沟深槽内的水深变浅和淤积的主要原因。淤积可能主要发生在通岛公路阻断浅滩潮道后的初期即2004-2006年期间。该研究结果也证实了我们阻断浅滩潮道会引起老龙沟深槽淤积的推断。     

闽江下游及河口海域水体中悬浮物的分布特征

采用重量法与浊度法对闽江下游及河口海域中的悬浮物进行了研究。通过对悬浮物的调查得出:平水期水体中悬浮物含量为5.67~493.8 mg/L,平均为114.2 mg/L,几乎所有的测站底层悬浮物含量高于表层。从上游向海方向,悬浮物呈增加趋势,高值区出现在琯头到英屿河段的底层,丰水期悬浮物含量为6.9~138.7 mg/L,平均为29.7 mg/L,呈中层 > 底层 > 表层的分布;同时,悬浮物浓度呈渐增之势,没出现悬浮物明显的富集。平水期温度、盐度、浊度断面资料显示,平水期上下层混合较为均匀,没有出现水体分层现象,在河口区有盐楔存在,最大浑浊带出现位置与盐度2~5.5的区域相对应。根据悬浮物的物质来源、水动力环境的分布特征,在调查时段内可将闽江口最大浑浊带划归为"海源——潮致型"。     

中国北方砂栖纤毛虫的空间分布及其驱动因素

为深入了解不同地理尺度因素对驱动微型生物群落空间结构的相对影响,本研究于2020年10月调查了中国北方14个砂质潮间带的砂栖纤毛虫群落。研究结果如下：（1）检获纤毛虫105种,隶属26目65属,按丰度优势依次为帆口目、小胸目和环毛目;（2）黄海、渤海两区域的环境因子存在显著差异,但纤毛虫群落组成趋于相似;（3）偏Mental分析显示,环境条件较空间距离在纤毛虫群落组成的驱动中更为重要,其中盐度、粒度和海滩坡度是解释纤毛虫空间分布的最优环境因子组合,而潮差和溶解无机氮含量是次要影响因子;（4）沿海区域微型生物的强扩散效应在一定程度上掩盖了环境异质性影响。综上,由于沿海生态系统中微型生物受到更少扩散限制,在空间分布格局的形成上,环境条件的影响比空间距离更重要。本研究为海洋微型生物地理学提供了基础数据,有助于在全球变化背景下制定沙滩管理和保护规划。     

天山中段的深浅构造特征

天山起源于古生代的陆-陆碰撞作用,又经历了中新生代的典型陆内造山过程,其深浅构造结构和活动性一直是众多学者关注的热点。文中通过多种地球物理探测和综合地质构造分析, 以地学断面形式对其深浅构造进行填图,揭示了天山中段复杂的深浅构造特色。结果表明:沿古生代的陆-陆碰撞缝合带两侧分别呈现出主要构造地质单元由老到新的对称性,并伴有相应深部结构的复杂性,反映了碰撞过程及后期的构造演化特点;天山中部的上地幔顶部存在厚近 10km、宽近 200km、几乎涵盖整个天山的低速高导层,可能是中新生代以来天山的陆内再造山作用引起的壳幔拆沉作用形成的残留下地壳     

晚更新世以来青海北部的人类活动与湖泊演变

作为高海拔生态环境的青海北部是青藏高原的重要组成部分。晚更新世晚期以来 ,青海北部气候环境一直处于冷暖、干湿波动过程之中 ,湖泊水域也发生了相应的扩张和收缩 ,成为高原人类迁移和发展的自然背景。约 3 0kaB .P .,在晚期智人出现和迁徙的关键时期 ,青海北部开始有了最早的人类活动 ;更新世末—全新世初 ,气候转暖 ,古人类再次来到青海北部 ;进入全新世中期 ,气候暖湿 ,湖水位回升 ,细石器技术变得十分普通 ,青海北部的人类活动渐趋频繁。     

Effects of Deep Fluids on Hydrocarbon Generation and Accumulation in Chinese Petroliferous Basins

Deep fluids in a petroliferous basin generally come from the deep crust or mantle beneath the basin basement, and they transport deep substances(gases and aqueous solutions) as well as heat to sedimentary strata through deep faults. These deep fluids not only lead to large-scale accumulations of CO_2, CH_4, H_2, He and other gases, but also significantly impact hydrocarbon generation and accumulation through organic-inorganic interactions. With the development of deep faults and magmatic-volcanic activities in different periods, most Chinese petroliferous basins have experienced strong impacts associated with deep fluid activity. In the Songliao, Bohai Bay, Northern Jiangsu, Sanshui, Yinggehai and Pearl Mouth Basins in China, a series of CO_2 reservoirs have been discovered. The CO_2 content is up to 99%, with δ~(13)C_(CO2) values ranging from-4.1‰ to-0.37‰ and ~3He/~4He ratios of up to 5.5 Ra. The abiogenic hydrocarbon gas reservoirs with commercial reserves, such as the Changde, Wanjinta, Zhaozhou, and Chaoyanggou reservoirs, are mainly distributed in the Xujiaweizi faulted depression of the Songliao Basin. The δ~(13)CCH4 values of the abiogenic alkane gases are generally -30‰ and exhibit an inverse carbon isotope sequence of δ~(13)C_(CH4)δ~(13)C_(C2H6)δ~(13)C_(C3H8)δ~(13)C_(C4H10). According to laboratory experiments, introducing external H_2 can improve the rate of hydrocarbon generation by up to 147% through the kerogen hydrogenation process. During the migration from deep to shallow depth, CO_2 can significantly alter reservoir rocks. In clastic reservoirs, feldspar is easily altered by CO_2-rich fluids, leading to the formation of dawsonite, a typical mineral in high CO_2 partial pressure environments, as well as the creation of secondary porosity. In carbonate reservoirs, CO_2-rich fluids predominately cause dissolution or precipitation of carbonate minerals. The minerals, e.g., calcite and dolomite, show some typical features, such as higher homogenization temperatures than the burial temperature, relatively high concentrations of Fe and Mn, positive Eu anomalies, depletion of 18 O and enrichment of radiogenic ~(87)Sr. Due to CO_2-rich fluids, the development of high-quality carbonate reservoirs is extended to deep strata. For example, the Well TS1 in the northern Tarim Basin revealed a high-quality Cambrian dolomite reservoir with a porosity of 9.1% at 8408 m, and the Well ZS1 C in the central Tarim Basin revealed a large petroleum reserve in a Cambrian dolomite reservoir at ~6900 m. During the upward migration from deep to shallow basin strata, large volumes of supercritical CO_2 may extract petroleum components from hydrocarbon source rocks or deep reservoirs and facilitate their migration to shallow reservoirs, where the petroleum accumulates with the CO_2. Many reservoirs containing both supercritical CO_2 and petroleum have been discovered in the Songliao, Bohaiwan, Northern Jiangsu, Pearl River Mouth and Yinggehai Basins. The components of the petroleum trapped with CO_2 are dominated by low molecular weight saturated hydrocarbons.     

基于模糊物元的城市化生态预警模型及应用

根据模糊物元理论建立了城市化的生态预警模型,将警报级别分为无警、轻警、中警、重警和巨警5级,并从资源预警、生态预警和环境预警3个方面构建河西走廊城市化进程中的生态环境预警指标体系,设立了预警参照标准与预警界限、警灯、警度,对河西走廊进行了实证分析。结果发现,河西走廊及五大地市按照预警指数从大到小的顺序依次为：张掖市、武威市、金昌市、河西走廊、嘉峪关市和酒泉市。其中,河西走廊的生态用水比重、植被覆盖率、人均环境保护费用和万元产值工业SO2排放量的景气指数最高,处于重警状态;城市工业用地定额、城市居住用地定额、万元产值工业废水排放量和万元产值工业粉尘排放量的景气指数最低,均处于轻警状态;其它指标均处于中警状态。可见,相对于土地资源和环境污染因素而言,水资源和生态条件已经对河西走廊的城市化产生了较强的束缚作用。     

京津唐地区深部挤压带特征及其与地震的关系

京津唐地区的深部挤压带轴线沿宁河、香河、昌平一线呈南东—北西走向,在通过该带的北东向Ｍ和Ｃ面上均有一向北西弯曲的弧形。地壳下部和上地幔顶部层位呈透镜状增厚,浅部的北东向断裂也向北西弯曲。应力测量表明现今该带的应力场为向北西挤压。深部挤压作用是由渤海底部的扩张所产生的。该挤压带控制着地震的发生,特别其北东侧是一个强地震区     

深部找矿钻探施工工艺与方法

介绍了在老矿区深部进行找煤所采用的工艺与方法,即在采空煤层井段采用风动潜孔锤钻进方法进行施工,在钻穿采空煤层后在深部采用绳索取心钻进方法施工。对施工中遇到的技术问题所采用的方法及取得的经验与教训进行了阐述。