Impact ejecta and carbonate sequence in the eastern sector of the Chicxulub crater

The Chicxulub 200 km diameter crater located in the Yucatan platform of the Gulf of Mexico formed 65 Myr ago and has since been covered by Tertiary post-impact carbonates. The sediment cover and absence of significant volcanic and tectonic activity in the carbonate platform have protected the crater from erosion and deformation, making Chicxulub the only large multi-ring crater in which ejecta is well preserved. Ejecta deposits have been studied by drilling/coring in the southern crater sector and at outcrops in Belize, Quintana Roo and Campeche; little information is available from other sectors. Here, we report on the drilling/coring of a section of der="0">34 m of carbonate breccias at 250 m depth in the Valladolid area (120 km away from crater center), which are interpreted as Chicxulub proximal ejecta deposits. The Valladolid breccias correlate with the carbonate breccias cored in the Peto and Tekax boreholes to the south and at similar radial distance. This constitutes the first report of breccias in the eastern sector close to the crater rim. Thickness of the Valladolid breccias is less than that at the other sites, which may indicate erosion of the ejecta deposits before reestablishment of carbonate deposition. The region east of the crater rim appears different from regions to the south and west, characterized by high density and scattered distribution of sinkholes.     

Historic reconstruction of reservoir topography using contour line interpolation and structure from motion photogrammetry

The geometry of impounded surfaces is a key tool to reservoir storage management and projection. Yet topographic data and bathymetric surveys of average-aged reservoirs may be absent for many regions worldwide. This paper examines the potential of contour line interpolation (TOPO) and Structure from Motion (SfM) photogrammetry to reconstruct the topography of existing reservoirs prior to dam closure. The study centres on the Paso de las Piedras reservoir, Argentina, and assesses the accuracy and reliability of TOPO- and SfM- derived digital elevation models (DEMs) using different grid resolutions. All DEMs were of acceptable quality. However, different interpolation techniques produced different types of error, which increased (or decreased) with increasing (or decreasing) grid resolution as a function of their nature, and relative to the terrain complexity. In terms of DEM reliability to reproduce area–elevation relationships, processing-related disagreements between DEMs were markedly influenced by topography. Even though they produce intrinsic errors, it is concluded that both TOPO and SfM techniques hold great potential to reconstruct the bathymetry of existing reservoirs. For areas exhibiting similar terrain complexity, the implementation of one or another technique will depend ultimately on the need for preserving accurate elevation (TOPO) or topographic detail (SfM).     

Quantitative assessment of remotely sensed global surface models using various land classes produced from Landsat data in Istanbul

Digital elevation model(DEM) is the most popular product for three-dimensional(3D) digital representation of bare Earth surface and can be produced by many techniques with different characteristics and ground sampling distances(GSD). Space-borne optical and synthetic aperture radar(SAR) imaging are two of the most preferred and modern techniques for DEM generation. Using them, global DEMs that cover almost entire Earth are produced with low cost and time saving processing. In this study, we aimed to assess the Satellite pour l'observation de la Terre-5(SPOT-5), High Resolution Stereoscopic(HRS), the Advanced Space-borne Thermal Emission and Reflection Radiometer(ASTER), and the Shuttle Radar Topography Mission(SRTM) C-band global DEMs, produced with space-borne optical and SAR imaging. For the assessment, a reference DEM derived from 1∶1000 scaled digital photogrammetric maps was used. The study is performed in 100 km2 study area in Istanbul including various land classes such as open land, forest, built-up land, scrub and rough terrain obtained from Landsat data. The analyses were realized considering three vertical accuracy types as fundamental, supplemental, and consolidated, defined by national digital elevation program(NDEP) of USA. The results showed that, vertical accuracy of SRTM C-band DEM is better than optical models in all three accuracy types despite having the largest grid spacing. The result of SPOT-5 HRS DEM is very close by SRTM and superior in comparison with ASTER models.     

Rapid Determination of Trace and Ultra Trace Level Elements in Diverse Silicate Rocks in Pressed Powder Pellet Targets by LA‐ICP‐MS using a Matrix‐Independent Protocol

A simple, single sample preparation involving pressed rock powder pellets was utilised to determine the trace and ultra trace abundances of petrogenetically important elements including high field‐strength elements and REEs by laser ablation‐ICP‐MS. One of the elements predetermined by XRF spectrometry served as an internal standard. The influence of sample preparation parameters (grain size, pellet compactness and amount of binding media) on analytical performance was also investigated, including sample homogeneity issues at the laser sampling scale. Line scanning with a high repetition frequency (20 Hz) and large beam diameter (200 μm) ensured ablation from a larger sample surface area, eliminating issues related to sample heterogeneity. A median grain size of about 10 μm for silicate rock powders was found to be sufficiently representative at this scale of laser sampling. Granitic rocks or samples containing resistant minerals such as zircon needed extra grinding to achieve grain sizes down to < 5 μm for better precision for elements that are concentrated in these phases. Using ¹³⁷Ba as an internal standard, reasonable accuracies within 15–20% for most of the high mass trace elements were achieved; in the case of low mass elements, it may deviate up to 40%. Precision of measurements rarely exceeded 15% RSD.     

Spatial Geochemistry: A Characterisation of Heterogeneity in Reference Materials

Geochemical reference materials (RMs) for microbeam techniques are typically characterised by averages and dispersion statistics (e.g., standard deviation, variance) that are calculated for a number of measurements (beam shots). It is proposed that the mapping of RMs will add spatial information that better characterises the grouping and magnitudes of the heterogeneities and provides the information necessary to define a minimum analytical mass. A simple mathematical solution is proposed, which can be easily computed and understood. The analogous notions to sill and range from geostatistics are applied to the minimum analytical mass versus the relative standard deviation. To assess grouping and magnitudes of the heterogeneities, a ‘proximity number’ is computed for each average value ± ‘n’ standard deviations (magnitude). Different chemical anomalies have been simulated to demonstrate the behaviour of the proximity number. To further test the proposed spatial geochemistry concept, sulfide‐ and oxide‐bearing RMs have been selected because many are crippled with nugget effect. They have been mapped with a micro‐XRF apparatus, and results are presented for CHR‐Bkg, CHR‐Pt+, MASS‐1, MASS‐3, WMS‐1 and WMS‐1a. MASS‐1 and MASS‐3 are the most suitable RMs for microbeam techniques. Spatial geochemistry offers a new approach to better characterise reference materials.     

Preparation and Characterisation of Two Geochemical Reference Materials: DG‐H (Granite) and AM‐H (Amphibolite) from the Himalayan Orogenic Belt

Two geochemical reference materials of Himalayan origin named DG‐H (a granite) and AM‐H (an amphibolite) prepared by the Wadia Institute of Himalayan Geology Dehradun are described. Both samples were collected from the NW Himachal Himalaya in India. With the participation of analysts from more than forty international laboratories, element determination data collected during the past 10 years for characterisation of the samples was processed to assign working values using statistical procedures in use for this purpose. Earlier work published on these samples is incorporated in the present communication making it an updated document. The typical chemical and petrological characteristics of these two samples may prove useful for method validation and calibration of analytical instruments used for analysing similar rock types, and for widening the analytical range of several analytical methods used for geochemical analysis.     

Determination of U–Pb Ages for Young Zircons using Laser Ablation‐ICP‐Mass Spectrometry Coupled with an Ion Detection Attenuator Device

We have developed new analytical procedures to measure precise and accurate ²³⁸U–²⁰⁶Pb and ²³⁵U–²⁰⁷Pb ages for young (~ 1 Ma) zircons using laser ablation‐ICP‐mass spectrometry. For young zircons, both careful correction for the background counts and analysis of very small Pb/U ratios (i.e., ²⁰⁶Pb/²³⁸U < 0.00016 and ²⁰⁷Pb/²³⁵U < 0.0001 for 1 Ma zircons) are highly desired. For the correction of the background, the contribution of the background signal intensities for the analytes, especially for the residual signal intensities for ²⁰⁶Pb and ²⁰⁷Pb, was defined through laser ablation of synthesised zircons (ablation blank) containing negligible Pb. The measured signal intensities for ²⁰²Hg, ²⁰⁶Pb and ²⁰⁷Pb signals obtained by the ablation blank were slightly higher than those obtained by data acquisition without laser ablation (gas blank). For the wider dynamic range measurements on Pb/U ratios, an attenuator device for the ion detection system was employed to extend the capability to monitor high‐intensity signals (i.e., > 3 Mcps). Through the attenuator device, the ion currents were reduced to 1/450 of the signal intensity without the attenuator. Because the switching time for the attenuator was shorter than 1 ms, signal intensities for only specific isotopes could be reduced. With attenuation of the ²³⁸U signal, counting statistics on ²⁰⁶Pb and ²⁰⁷Pb isotopes could be improved and counting loss on the ²³⁸U signal could be minimised. To demonstrate the reliability of this new analytical technique, ²³⁸U–²⁰⁶Pb and ²³⁵U–²⁰⁷Pb ages for three young zircon samples (collected from Osaka Group Pink Volcanic Ash, Kirigamine and Bishop Tuff) were measured. The data presented here demonstrate clearly that the present technique could become a major analytical tool for in situ U–Pb age determination of young zircons (~ 1 Ma).     

Iron Distribution in Size‐Resolved Aerosols Generated by UV‐Femtosecond Laser Ablation: Influence of Cell Geometry and Implications for In Situ Isotopic Determination by LA‐MC‐ICP‐MS

The influence of ablation cell geometry (Frames single‐ and HelEx two‐volume cells) and laser wavelength (198 and 266 nm) on aerosols produced by femtosecond laser ablation (fs‐LA) were evaluated. Morphologies, iron mass distribution (IMD) and ⁵⁶Fe/⁵⁴Fe ratios of particles generated from magnetite, pyrite, haematite and siderite were studied. The following two morphologies were identified: spherules (10–200 nm) and agglomerates (5–10 nm). Similarity in IMD and ablation rate at 198 and 266 nm indicates similar ablation mechanisms. ⁵⁶Fe/⁵⁴Fe ratios increased with aerodynamic particle size as a result of kinetic fractionation during laser plasma plume expansion, cooling and aerosol condensation. The HelEx cell produces smaller particles with a larger range of ⁵⁶Fe/⁵⁴Fe ratios (1.85‰) than particles from the Frames cell (1.16‰), but the bulk aerosol matches the bulk substrate for both cells, demonstrating stoichiometric fs‐LA sampling. IMD differences are the result of faster wash out of the HelEx cell allowing less time for agglomeration of small, low‐δ ⁵⁶Fe particles with larger, high‐δ ⁵⁶Fe particles in the cell. Even with a shorter ablation time, half the total Fe ion intensity, and half the ablation volume, the HelEx cell produced Fe isotope determinations for magnetite that were as precise as the Frames cell, even when the latter included an aerosol‐homogenising mixing chamber. The HelEx cell delivered a more constant stream of small particles to the ICP, producing a more stable Fe ion signal (0.7% vs. 1.5% RSE for ⁵⁶Fe in a forty‐cycle single analysis), constant instrumental mass bias and thus a more precise measurement.     

Tephras in lacustrine sediments of the Sarliève marsh (French Massif Central): age and preservation

The Sarliève marsh sediments (Massif Central, France) contain two tephras. The first tephra [der="0" height=14 width="120"/>, ca. 12 000 BP], regionally well known, enables to date the beginning of lacustrine infill to the Lateglacial. The second tephra, the ‘tephra de Sarliève’, the emitting volcano of which is unknown, would be dated to around the Early Subboreal from pollen data. This occurrence, after the discovery of the ‘tephra de Beaunit’, emphasizes that volcanic eruption(s) occurred in the ‘Chaîne des Puys’ or in the volcanic Cézallier more than 1000 years after the last known eruption (Pavin) in the ‘Chaîne des Puys’ at around 6.6/6.7 ka (5800/5900 BP). In the Sarliève piles, these tephras, well preserved in thick and more silicated deposits of deltas, were not observed in carbonated basin sediments where they were altered. The abundance of authigenic zeolites formed during the Lateglacial in restricted depocentre lacustrine waters allows us to detect initial CF1 tephra occurrence. To cite this article: A. Fourmont et al., C. R. Geoscience 338 (2006).     

Theoretical analysis of equatorial near-inertial solitary waves under complete Coriolis parameters

An investigation of equatorial near-inertial wave dynamics under complete Coriolis parameters is performed in this paper. Starting from the basic model equations of oceanic motions, a Korteweg de Vries equation is derived to simulate the evolution of equatorial nonlinear near-inertial waves by using methods of scaling analysis and perturbation expansions under the equatorial beta plane approximation. Theoretical dynamic analysis is finished based on the obtained Korteweg de Vries equation, and the results show that the horizontal component of Coriolis parameters is of great importance to the propagation of equatorial nonlinear near-inertial solitary waves by modifying its dispersion relation and by interacting with the basic background flow.