Sound velocity and density of liquid Ni68S32 under pressure using ultrasonic and X-ray absorption with tomography methods

A new experimental setup for simultaneous P-wave velocity (V_P) and density (ρ) measurements for liquid alloys is developed using ultrasonic and X-ray absorption methods combined with X-ray tomography at high pressures and high temperatures. The new setup allows us to directly determine adiabatic bulk moduli (K_S) and to discuss the correlation between the V_P and ρ of the liquid sample. We measured V_P and ρ of liquid Ni₆₈S₃₂ up to 5.6 GPa and 1045 K using this technique. The effect of pressure on the V_P and ρ values of liquid Ni₆₈S₃₂ is similar to that of liquid Fe₅₇S₄₃. (Both compositions correspond to near-eutectic ones.) The obtained K_S values are well fitted to the finite strain equation with a $K_{{\text{S}}_0}$ value (K_S at ambient pressure) of 31.1 GPa and a dK_S/dP value of 8.44. The measured V_P was found to increase linearly with increasing ρ, as approximated by the relationship: V_P [m/s] = 1.29 ρ [kg/m³] – 5726, suggesting that liquid Ni–S follows an empirical linear relationship, Birch's law. The dV_P/dρ slope is similar between Ni₆₈S₃₂ and Fe₅₇S₄₃ liquids, while the V_P–ρ plot of liquid Ni–S is markedly different from that of liquid Fe–S, which indicates that the effect of Ni on Birch's law is important for understanding the V_P–ρ relation of planetary and Moon's molten cores.     

现浇连续箱梁的施工工艺

滨州黄河公路大桥南引桥上部构造为单箱单室大悬臂连续现浇箱梁,跨径42m,2001年12月开工,经过17个月的艰苦施工,提前顺利竣工。对该项工程的施工经验做了总结。     

Mineral chemistry,crystallization conditions and magma mixing‐mingling at Orduzu volcano (Malatya), Eastern Anatolia,Turkey

The Middle Miocene Orduzu volcanic suite, which is a part of the widespread Neogene Yamadağ volcanism of Eastern Anatolia, consists of a rhyolitic lava flow, rhyolitic dykes, a trachyandesitic lava flow and basaltic trachyandesitic dykes. Existence of mafic enclaves and globules in some of the volcanic rocks, and microtextures in phenocrysts indicate that magma mingling and mixing between andesitic and basaltic melts played an important role in the evolution of the volcanic suite. Major and trace element characteristics of the volcanic rocks are similar to those formed in convergent margin settings. In particular, incompatible trace element patterns exhibit large depletions in high field strength elements (Nb and Ta) and strong enrichments in both large ion lithofile elements (Ba, Th and U) and light rare earth elements, indicating a strong subduction signature in the source of the volcanic rocks. Furthermore, petrochemical data obtained suggest that parental magmas of rhyolite lava and dykes, and trachyandesite lava and basaltic trachyandesite dykes were derived from subduction‐related enriched lithospheric mantle and metasomatized mantle (± asthenosphere), respectively. A detailed mineralogical study of the volcanic suite shows that plagioclase is the principal phenocryst phase in all of the rock units from the Orduzu volcano. The plagioclase phenocrysts are accompanied by quartz in the rhyolitic lava flows and by two pyroxenes in the trachyandesitic lava flows and basaltic trachyandesitic dykes. Oxide phases in all rocks are magnetite and ilmenite. Calculated crystallization temperatures range from 650°C to 800°C for plagioclase, 745°C–1054°C for biotite, 888°C–915°C for pyroxene and 736°C–841°C for magnetite–ilmenite pairs. Calculated crystallization pressures of pyroxenes vary between 1.24–5.81 kb, and oxygen fugacity range from −14.47 to −12.39. The estimates of magmatic intensive parameters indicate that the initial magma forming the Orduzu volcanic unit began to crystallize in a high‐level magma chamber and then was stored in a shallow reservoir where it underwent intermediate‐mafic mixing. The rhyolitic lava flow and dykes evolved in relatively shallower crustal magma chambers. Copyright © 2007 John Wiley & Sons, Ltd.     

1917号台风“塔巴”对浙江沿海风场的影响及其成因分析

通过分析浙江省区域自动站加密资料、常规观测资料、NCEP/NCAR 1°×1°和0.25°×0.25°再分析资料以及卫星TBB (Black Body Temperature)资料,研究2019年第17号台风"塔巴"影响期间,浙江沿海风场分布的特点及其成因,以寻找台风影响时浙江沿海风场预报的着眼点。此次台风大风具有影响时间早、持续时间长、影响范围大和大风强度强的特点。台风环流与浙江沿海地面弱冷空气之间形成一定气压梯度的堆积,以及后续随着台风环流的发展加强,两者之间气压梯度进一步增大,是导致此次台风大风提早出现的原因之一。垂直环流有利于水平的动量输送和高层动量下传,导致此次台风大风范围大、强度强。冷空气在这次台风大风中起到非常重要的作用。随着台风外围环流与冷空气距离拉近,部分干冷空气侵入台风环流,冷、暖气团之间θse等值线密集,环流附近风速增强。由于干冷空气的继续侵入,冷、暖空气相互作用累积并释放斜压能。同时台风低层的暖心结构被冷空气占据,高层暖心结构上抬,形成上暖下冷的中心结构,导致台风开始变性减弱。地形的辐合、阻挡和摩擦作用对风场的再分布也有一定影响。     

Crack nucleation in saturated porous media

Crack nucleation has been the subject of important contributions in the last two last decades. However, it seems that few attention has been granted to the case of saturated porous media. This is the question addressed in the present paper which is devoted to nucleation in traction mode. From a physical point of view, nucleation is a sudden phenomenon, so that the material response is both adiabatic and undrained. In the spirit of the variational approach, the nucleated crack is viewed as the final state of a region of space in which the material undergoes a full damage process. In traction mode, the opening of a saturated crack in undrained condition induces a drop of fluid pressure. In case of low fluid compressibility, the presence of the fluid delays the brittle failure usually associated with nucleation, as long as the fluid pressure remains above the saturation vapor pressure. Nucleation is therefore possible only if a partial vaporization of the fluid takes place.     

Grain‐scale pressure variations and chemical equilibrium in high‐grade metamorphic rocks

In the classical view of metamorphic microstructures, fast viscous relaxation (and so constant pressure) is assumed, with diffusion being the limiting factor in equilibration. This contribution is focused on the only other possible scenario – fast diffusion and slow viscous relaxation – and brings an alternative interpretation of microstructures typical of high‐grade metamorphic rocks. In contrast to the pressure vessel mechanical model applied to pressure variation associated with coesite inclusions in various host minerals, a multi‐anvil mechanical model is proposed in which strong single crystals and weak grain boundaries can maintain pressure variation at geological time‐scales in a polycrystalline material. In such a mechanical context, exsolution lamellae in feldspar are used to show that feldspar can sustain large differential stresses (>10 kbar) at geological time‐scales. Furthermore, it is argued that the existence of grain‐scale pressure gradients combined with diffusional equilibrium may explain chemical zoning preserved in reaction rims. Assuming zero net flux across the microstructure, an equilibrium thermodynamic method is introduced for inferring pressure variation corresponding to the chemical zoning. This new barometric method is applied to plagioclase rims around kyanite in felsic granulite (Bohemian Massif, Czech Republic), yielding a grain‐scale pressure variation of 8 kbar. In this approach, kinetic factors are not invoked to account for mineral composition zoning preserved in rocks metamorphosed at high grade.     

碳酸氢钠冷却结晶动力学

碳酸氢钠(NaHCO_3)俗称小苏打,其产品质量取决于颗粒的大小,晶体的形貌和样品的纯度等诸多因素。本论文基于连续稳态MSMPR结晶器原理,研究了不同停留时间下,碳酸氢钠从碳酸钠溶液中冷却结晶过程动力学。利用实验数据建立了NaHCO_3的结晶动力学操作模型。实验和计算结果表明,随停留时间的增加,NaHCO_3过饱和度降低,晶体生长速率和成核速率均减小,相应的平均粒径增加,细颗粒含量减小;适当延长停留时间是制取高品质小苏打产品的有效途径。冷却结晶过程可有效增加小苏打产量,小苏打收率维持在55%左右。此外,一定Na_2CO_3存在下冷却结晶碳酸氢钠晶体形态由细长的针状变为规整的片状。     

北京地区城市热岛强度长期变化特征及气候学影响机制

选择北京地区为研究区,基于1967~2016年城市站（北京站）和城郊农村站（密云站）的长期气象观测数据,研究平均气温、最高气温、最低气温对应的城市热岛强度长期变化特征及其气候学影响机制。研究发现,过去50 a平均气温和最低气温对应的城市热岛强度显著增加,增温率分别为0.29℃/10a和0.45℃/10a,而最高气温对应的城市热岛强度则没有明显变化趋势;统计分析显示过去50 a北京地区相对湿度、风速和日照时数显著降低以及气温显著上升有利于城市热岛的形成,强化城市热岛强度;未来全球变暖和快速城市化背景下北京地区城市热岛效应将进一步加剧,形成更频繁和持续时间更长的夏季城市高温热浪,严重危及城市居民生产生活和生命健康。     

三小时负变压异常指数及对强对流天气的预报意义

低层暖平流强迫类强对流发生前,地面经常伴有低于日变化的3 h变压。结合常规地面观测资料,定义低于日变化的3 h变压异常（超过一个标准差定义为异常）指数PCR（Pressure Change Range）,讨论了中国中东部地区3 h变压标准差的气候分布特征;最后以3次强对流天气过程为例说明PCR指数的预报价值和时效。结果表明,与3 h变压均值相比,中国中东部地区的3 h变压标准差的日变化较小,PCR更适合作为变压异常程度的标准。东北、华北、华东-华中区域PCR冬春季节出现站次数偏多,夏秋季节偏少;华南区域除了冬春季外,夏季也偏多,秋季偏少。PCR主要集中在低级别强度上,但PCR级别越高,越有可能出现强对流天气。东北区域出现PCR的首要原因是受东北气旋的影响,且可能有TBB≤-52℃的云系相对应;华北、华东-华中、华南出现PCR的首要原因是冷高压变性或迅速东移,没有TBB≤-52℃的云系相对应;地面倒槽中出现的PCR全部有TBB≤-52℃的云系对应。3次强对流天气过程均发生在地面倒槽中;在发生前3 h左右,地面气压场上有较明显的负PCR中心出现,强对流天气中尺度云团有向负PCR中心移动的趋势。      

GPT2w模型在中国大陆地区的精度分析

全球气温气压（GPT）系列模型可用于计算全球任意位置的气温、气压和水汽压等各种气象参数,目前国内外广泛使用且精度较高的全球气温气压模型主要为GPT2w模型.本文利用2012—2016年中国大陆地区102个国家气象站实测的气温、气压和水汽压数据对GPT2w模型进行精度分析.结果表明：GPT2w模型的气温误差均值为-0.45 ℃,标准偏差均值为10.04 ℃;气压误差均值为2.05 hPa,标准偏差均值为6.55 hPa;水汽压误差均值为0.11 hPa,标准偏差均值为6.15 hPa.总体而言,GPT2w模型计算出的气温、气压和水汽压值在中国大陆大部分地区具有较高的精度.同时,三种气象参数的精度在中国大陆地区分布不均匀,不同纬度区间存在一定差异且以年为周期均具有明显的季节性.