估算钙碱性长英质侵入岩结晶压力的地质压力计评述

本文对四种常见的矿物压力计（角闪石全铝压力计、黑云母压力计、榍石压力计和“石英”压力计）的适用性进行了经验性检验。基于国内外典型钙碱性长英质岩体的矿物化学和全岩化学成分数据,采用不同压力计估算岩体侵位压力,并与角闪石全铝压力计结果对比。结果表明：角闪石六次配位Al压力计与广泛使用的角闪石全铝压力计的估算值存在系统相关性;榍石压力计计算的压力与角闪石全铝压力计的估计结果相关性较为显著;基于Qtz—Ab—Or简并花岗岩体系的“石英”压力计可以用于估计准铝质—弱过铝质钙碱性（狭义）花岗岩的结晶压力。但是,经验性的黑云母压力计和基于实验数据的黑云母压力压计均不能很好地复现角闪石全铝压力计的结果。黑云母压力计不适用于估算钙碱性侵入岩的结晶压力。     

伟晶质岩浆的同化混染与分离结晶(AFC)作用及铀成矿效应:以纳米比亚湖山铀矿为例

纳米比亚湖山铀矿位于达马拉造山带的中央南部地区,工业铀矿物为晶质铀矿,属于伟晶岩型铀矿床。关于不同矿石中铀元素的富集与沉淀机制还存在一定争议。为了揭示伟晶质岩浆演化与铀矿化作用的关系,本文对矿区内不同矿物组成的伟晶岩型矿石开展了岩石和矿物地球化学研究。野外及镜下鉴定结果显示,矿化伟晶岩可以分为“简单类型”矿体和“复杂类型”矿体。前者具有正常的花岗伟晶结构,晶质铀矿均匀分布于造岩矿物之间,矿化程度低到中等;后者表现出非均匀的结构特征,且矿化程度极高,晶质铀矿在成因上与大量黑云母团块有明显的空间联系。地球化学研究表明:在“简单类型”伟晶岩中,铀元素主要通过伟晶质岩浆的分离结晶作用富集;“复杂类型”伟晶质岩浆的演化则明显受控于同化混染作用,其铀矿化为岩浆同化混染与分离结晶(assimilation-fractional crystallization,AFC)作用产物。具体而言,外来基性组分(FeO,MgO,TiO₂,MnO)的混入导致“复杂类型”熔体中矿物的结晶顺序发生改变,长石类矿物的“延后”结晶为黑云母提供了更加有利的结晶空间和条件,促使黑云母以团块状聚集的形式产出。黑云母的大量析出会引发残余岩浆中UF_m^4-m络合物的水解,导致晶质铀矿在团块黑云母内部或周围沉淀。因此,本文有关“简单类型”和“复杂类型”产铀伟晶岩的研究,有效地揭示了岩浆演化过程与铀矿化机制,丰富了伟晶岩型铀矿床理论,为后期勘查开发提供了科学依据。     

Determination of total sulfur in geothermal water by inductively coupled plasma-atomic emission spectrometry

Sulfur speciation and concentration in geothermal water are of great significance for the research and utilization of the water resources. In most situations, it is necessary to determine the total sulfur in geothermal water. In this study, the method was established for the determination of determining total sulfur content — the inductively coupled plasma-atomic emission spectrometry (ICP-AES), with the wavelength of 182.034 nm selected in spectral line of sulfur. It was identified that the optimal working conditions of the ICP-AES instrument were 1 200 W for high frequency generator power 9 mm for vertical observation height, 0.30 MPa atomizer pressure, and 50 r/min analytical pump speed. The matrix interference of the method was eliminated by the matrix matching method. Using this method, sulfur detection limit and minimum quantitative detection limit were 0.028 mg/L and 0.110 mg/L, respectively, whilst the linear range was 0.0–100.0 mg/L. The recovery rate of sample was between 90.67% and 108.7%, and the relative standard deviation (RSD) was between 0.36% and 2.14%. The method was used to analyze the actual samples and the results were basically consistent with the industry standard method. With high analysis efficiency, the method has low detection limit and minimum quantitative detection limit, wide linear range, good precision and accuracy, and provides an important detection method for the determination of total sulfur in geothermal water.     

Response characteristics of plunge pool slabs of Xiaxiluodu Hydropower Station to flood discharge pulsating-pressure under valley deformation conditions

The key problem of the energy dissipation scheme of the arch dam body flood discharge and plunge pool below the dam is the stability problem of the plunge pool slab. As the protection structure of the underwater bed, the plunge pool slab bears the continuous impact of high-speed water flow. The hourly average dynamic water pressure on the slab is one of the main loads directly affecting the stability of the slab and is the main factor causing its erosion destruction. After the impoundment of the Xiluodu Hydropower Station, the measuring line of valley width in the plunge pool area has been continuously shrinking. By 2020, the cumulative shrinking value is about 80 ​mm. In light of the general background condition of valley shrinkage, daily inspection, annual detailed inspection, underwater inspection and drainage inspection of the plunge pool found that the plunge pool has experienced different degrees of damage, which greatly influences the long-term safety stability of the plunge pool. In this paper, the prototype observation data of flood discharge is used as the input load of pulsating-pressure, and the stress and displacement distribution of the plunge pool structure under the vibration load of flood discharge is analyzed under the condition that the stress and strain state of the plunge pool is changed under the influence of valley displacement. The results show that the stress, strain, and displacement distribution of the plunge pool are mainly caused by valley deformation, the vibration caused by flood discharge is little in influence, and the impact effect of deep hole flood discharge tongue on the plunge pool slab is weak.     

Under the surface: Pressure-induced planetary-scale waves,volcanic lightning,and gaseous clouds caused by the submarine eruption of Hunga Tonga-Hunga Ha'apai volcano

We present a narrative of the eruptive events culminating in the cataclysmic January 15, 2022 eruption of Hunga Tonga-Hunga Ha'apai Volcano by synthesizing diverse preliminary seismic, volcanological, sound wave, and lightning data available within the first few weeks after the eruption occurred. The first hour of eruptive activity produced fast-propagating tsunami waves, long-period seismic waves, loud audible sound waves, infrasonic waves, exceptionally intense volcanic lightning and an unsteady volcanic plume that transiently reached—at 58 ?km—the Earth's mesosphere. Energetic seismic signals were recorded worldwide and the globally stacked seismogram showed episodic seismic events within the most intense periods of phreatoplinian activity, and they correlated well with the infrasound pressure waveform recorded in Fiji. Gravity wave signals were strong enough to be observed over the entire planet in just the first few hours, with some circling the Earth multiple times subsequently. These large-amplitude, long-wavelength atmospheric disturbances come from the Earth's atmosphere being forced by the magmatic mixture of tephra, melt and gasses emitted by the unsteady but quasi-continuous eruption from 0402±1–1800 UTC on January 15, 2022. Atmospheric forcing lasted much longer than rupturing from large earthquakes recorded on modern instruments, producing a type of shock wave that originated from the interaction between compressed air and ambient (wavy) sea surface. This scenario differs from conventional ideas of earthquake slip, landslides, or caldera collapse-generated tsunami waves because of the enormous (～1000x) volumetric change due to the supercritical nature of volatiles associated with the hot, volatile-rich phreatoplinian plume. The time series of plume altitude can be translated to volumetric discharge and mass flow rate. For an eruption duration of ～12 ?h, the eruptive volume and mass are estimated at 1.9 ?km³ and ～2 900 ?Tg, respectively, corresponding to a VEI of 5–6 for this event. The high frequency and intensity of lightning was enhanced by the production of fine ash due to magma—seawater interaction with concomitant high charge per unit mass and the high pre-eruptive concentration of dissolved volatiles. Analysis of lightning flash frequencies provides a rapid metric for plume activity and eruption magnitude. Many aspects of this eruption await further investigation by multidisciplinary teams. It represents a unique opportunity for fundamental research regarding the complex, non-linear behavior of high energetic volcanic eruptions and attendant phenomena, with critical implications for hazard mitigation, volcano forecasting, and first-response efforts in future disasters.     

天然气水合物样品带压转移装置的抓捕机构设计

在天然气水合物岩心样品的带压转移过程中,岩心衬管抓捕装置是实现样品转移的关键。岩心抓取是在岩心管内进行,属于非可视化操作过程,同时岩心样品和抓捕器都处于高压液体中,岩心衬管与岩心管之间的间隙非常小,要保证岩心样品的原位状态,对岩心抓捕装置的结构设计、精准定位、快速抓取和释放都有很高的要求。根据该装置所需实现的抓取、拖动、定位和释放功能,设计挂盘自锁和触碰解锁机构,探针抓取衬管,经过室内抓捕实验,该机构可以顺利抓捕和解卡,其结构简单,能在压力状态下进行岩心转移,加快了天然气水合物样品的带压转移装置的研究进展。     

基于离散元方法的不同挡墙变位模式下有限土体主动土压力研究

为研究挡墙变位模式以及墙后填土宽度对无黏性有限土体主动土压力的影响,在不同墙后填土宽度条件下分别开展了挡墙平动(T)模式、绕墙底转动(RB)模式以及绕墙顶转动(RT)模式的离散元模拟。根据离散元模拟结果对主动土压力、墙后土体破坏模式以及应力状态进行了分析。研究结果表明:挡墙变位模式和墙后填土宽度的变化使得土体破坏模式和应力状态发生变化,引起主动土压力大小及分布的差异。T与RB模式滑动土楔中内摩擦角调动值会相对初始值增加,且T模式滑动土楔中会出现小主应力拱。RT模式较为特殊,在填土宽度较小时,其应力状态与T模式相似;在填土宽度较大时,滑动土楔上部会出现内摩擦角调动值相对初始值减小的区域,并出现大主应力拱。     

T型巷道中突出煤−瓦斯两相流动力学试验研究

为了进一步探究突出煤−瓦斯两相流在不同巷道布置方式下的动力学行为,利用多场耦合煤矿动力灾害大型物理模拟试验系统,开展了T型巷道布置方式下的煤与瓦斯突出试验,得出了两相流运移过程中冲击力与静压的演化特征。结果表明：直线主巷内冲击力随时间呈多峰值震荡衰减趋势,体现了突出过程的脉冲特性,且距突出口越近,冲击力震荡次数越多;分岔两侧支巷内冲击力突出前期呈现两种演化趋势,其一是迅速增大至峰值后缓慢下降,其二是缓慢增大后缓慢下降;距分岔结构中心左侧1 500 mm处出现了较大冲击力值,出现重度危险区域,而右侧则在距500 mm和1 900 mm处。利用突出运移动态图像将整个过程分为单相气流和两相流两个阶段,单相气流阶段中分岔后支巷的冲击力就迅速上升至峰值,而在两相流阶段分岔前主巷的冲击力上升至最高值,存在分岔后冲击力峰值高于分岔前的现象。突出过程中,巷道壁面上静压值总体偏低;静压随时间呈间歇式波动发展,且其峰值点自煤层由近及远呈先增大后减小的趋势;距突出口越远,直线主巷内静压出现峰值的时刻越滞后;分岔支巷内静压左右两侧的演化近似,随着时间推进,分岔结构前后静压衰减逐渐增大。     

基于孔压静力触探试验的水运工程土分类方法研究

土的工程分类是工程勘察和设计应用的关键问题之一。基于孔压静力触探测试（piezocone penetration test,简称CPTU）原位测试参数进行土分类是高效实用的方法。国内外现有分类方法的名称及标准与我国《水运工程岩土勘察规范》（JTS 133－2013）不符合。因此,建立基于CPTU原位测试参数、符合我国行业标准的土工程分类方法具有重要工程意义。在收集大量国内外水运工程CPTU测试资料的基础上,对比分析了616个间距小于5 m的CPTU测试孔和相应钻孔取样与室内土工试验成果。选择国内外7种常用的CPTU土分类图进行应用比较,发现这些土分类图所采用的应力修正计算方法在考虑浅层土体的有效上覆应力修正时存在一定的缺陷,通过引入新的应力修正方法和修正土分类边界线,建立了适合我国水运工程的CPTU土分类方法。对比应用分析表明,该分类图能够准确地进行水运工程土类划分,尤其适合于软土、粉细砂和中粗砂的划分,可作为我国水运工程的土工程分类方法。     

絮凝−真空−电渗联合加固滩涂软土的模型试验研究

针对真空预压作用下排水板淤堵与排水条件受限等问题,提出絮凝−真空−电渗联合加固法。首先通过沉降柱试验确定合适的有机絮凝剂,然后采用该絮凝剂,分别在 48 h（开始介入真空预压,固结度为0 ）、60 h（排水速率明显下降,固结度为60%）及 84 h（排水速率近乎 0,固结度为 80%）时介入电渗,开展不同电渗介入时间的絮凝−真空−电渗联合加固试验。试验从排水量、十字板剪切强度、含水率与孔压等对比分析联合加固的有效性,确定其最佳电渗介入时间。试验结果表明：当固结度为 80% 时介入电渗,絮凝−真空−电渗联合加固法能够有效地抑制排水速率减小的趋势,增长有效排水时间。同时,土体的抗剪强度和承载力亦得到大幅提升,孔压消散更加均匀。此外,在阳离子聚丙烯酰胺絮凝剂的作用下,初始排水速率快,在一定程度上使土体的渗透性得到提升,有效地解决了排水板淤堵问题,说明絮凝−真空−电渗联合加固法具有较强的优越性。