累托石中晶层含量及规则度测定

本文用直接付里叶交换法测定我国产出的10个累托石样品结构中两类晶层(A云母层、B蒙皂石层)含量(A%、B%)及规则度(Re%)。测定结果表明天然累托石中,A/B不等于1,1.27>A/B>1.01。A%为50.5%—55.8%,B%为44.2%—49.5%;A、B层也不是严格规则交替堆垛,规则度Re%为72%—98.6%。     

Temperature dependence of the magnetic rotation process of kaolinite microcrystals containing paramagnetic impurity ions dispersed in liquid medium

Temperature dependencies of magnetic rotation were measured in micron-sized silicates dispersed in ethanol for two different samples of kaolinite. Magnetic rotation proceeded by balance between thermal agitation energy and magnetic anisotropy energy. Measurements were performed between 195 and 343 K. The field intensity required to achieve magnetic alignment of microcrystals increases with temperature, because of the temperature dependence of paramagnetic anisotropy, and the temperature dependence of thermal agitation energy. The results indicate that the values of magnetic anisotropy of nonmagnetic materials might partially derive from the paramagnetic moments, which derive from paramagnetic impurity ions. The present experiment provides a technical basis for determining the precise values of diamagnetic anisotropy ()_DIA from minerals which have a concentration of paramagnetic ions and do not form a single crystal large enough to allow bulk measurements. The values of ()_DIA can be obtained by extrapolating the –T relations, which follow the Curie law, to the temperature limits.     

U-Th-Pb副矿物的原地原位测年微束分析方法比较与微区晶体化学研究

系统地对比分析了各种微束分析技术在原地原位测年中的优势和局限性,并对近年发展的微区原位化学测年技术(EPMA)和质子激发X射线微探针分析技术(μ-PIXE)进行了探讨.阐明了矿物微区晶体化学研究的各种方法及其对实现精确原地原位测年的重要性.介绍了北大别黄土岭麻粒岩锆石测定点的晶体化学特征,应用激光剥蚀微探针-感应耦合等离子体质谱(LAM-ICPMS)技术对其进行了锆石的U-Pb表面年龄的测定,结果表明该岩石的麻粒岩相变质发生在2.050 Ga前,锆石来源为多源区.     

Crystal Structure of Natural Non-metamict Ti- and Fe~(2+)-rich Chevkinite-(Ce)

1 Introduction Chevkinite groups can be assigned to the chevkinite-(Ce) subgroup and perrierite-(Ce) subgroup in accord with the angle β : β ≈ 100o for the chevkinite subgroup and β ≈ 113o for the perrierite subgroup. Chevkinite-(Ce), polykovite-(Ce) and Maoniupingite (new mineral No. 017 of 2003) belong to the former subgroup, while renjeite and matsubaraite belong to the latter group. As strontio-chevkinite is a Sr-analogue of perrierite, usually the natural chevkinite-(Ce) group min…     

Comparative Study of Nucleation by Different Alcoholic Solutions of Benzoin, and Benzoin Dust

Nucleation properties of different alcoholic solutions of Benzoin and Benzoin dust have been studied by varying the seeding temperature in a laboratory Cold Chamber. In the present study, three different alcoholic solutions are being used and these are due to the standard Ethyl alcohol, one higher alcohol i.e. Isopropyle alcohol and one lower alcohol i.e. Methyl alcohol. In addition, Benzil dust and droplets of Acetone and Chloroform have been used to examine if these agents have any ice nucleation ability. It has been observed that all alcoholic solutions of Benzoin have sufficient ice nucleation ability at the negative side of 0^°C, with the maximum concentration occurring at −14.4^°C. In case of Benzoin dust, the nucleation ability is better on the positive side of 0^°C than the negative side. On the other hand, Benzil dust has insignificant nucleation ability and the droplets of two other agents have no nucleation ability at all.Considering the chemical as well as crystalline structure, one can conclude that the presence of OH group in the seeding molecule plays the central role in ice nucleation/hydrate crystal formation. In fact, a number of supplementary experiments like crystal growth in an incubator, XRD analysis and NMR study are performed to identify the nature of crystals formed by Benzoin dust above 0^°C. One can conclude that these are hydrate crystals of Benzoin with water caging around Benzoin crystals.     

基于B／S体系结构的地图制图生产管理系统

为适应地图制图生产模式的转变，实现地图制图生产管理的科学性和高效率，本文提出了一种基于B／S体系结构构建地图制图生产管理系统的方法。采用．NET、Java Applet和水晶报表技术解决普通页面、带地图元素页面和带统计图表页面的实现难题。系统具有易维护、视觉化效果好和软件复用性高等优点。     

Statistical Properties of Ideal Rock Textures: Relationship Between Crystal Size Distribution and Spatial Correlation of Minerals

The concept of an ideal rock texture, in which crystals are distributed randomly in space, is proposed for use in general analysis of rock textures. The spatial correlation function for the ideal rock texture was examined and the function, a specific kind of spatial correlation function, is related to crystal size distribution and to some extent to crystal boundaries. The function is unity at distance zero, and monotonically decreases with increasing distance for the ideal texture. This behavior of the function is observed for any size distribution. In an ideal texture, the function is directly related to crystal size distribution and crystal shape. It is important in stereology because the crystal size distribution in three dimensions may be deduced from analyzing a function that is obtained from analyzing two-dimensional section images. Crystal shape is also related to the function. If crystals are concave in shape, or have inclusions of other phases, the function may show a hump or plateau when plotted against distance. However, the crystal shape effect cannot produce values smaller than zero. If values become negative, the texture is no longer considered ideal. The ideal textures for two model size distributions—step and delta functions—are considered. The rate of decrease of values is more strongly dependent on size distribution than on system dimension.     

玻镁安山岩中辉石枝晶的形貌与晶体生长方式

川西乡城地区的玻镁安山岩基质中辉石微晶具有奇特的枝晶形貌。通过高倍率光学显微镜和扫描电镜观察,较详细地分析了辉石枝晶的形貌细节。辉石枝晶一般发育三级分枝,各分枝间以近于90°和110°交角沿单斜辉石结晶学主轴方位优先生长,各级分校具有整体一致的光学性质,如同单个晶体。玻镁安山岩浆流动性大,呈薄层状。快速冷凝作用和强的结晶能力是辉石枝晶发育的前提条件。初步探讨了在远离平衡态结晶时,辉石枝晶生长方式和界面稳定性对晶体形貌的控制作用。     

贵州麻山冰洲石矿床成因的初步研究

贵州麻山冰洲石矿床成因的初步研究＊金志升朱成明刘钧蔡恩照（中国科学院地球化学研究所，贵州５５０００２）关键词方解石冰洲石成因晶体生长贵州省望谟县麻山地区分布有大小不等的方解石、冰洲石矿点数十处，是我国较重要的冰洲石产地之一。曹俊臣［１］曾对该地区冰洲...     

氟碳铈矿和氟铈矿晶体结构的精确测定

用强功率四圆单晶衍射仪精确地修正了氟碳铈矿和氟铈矿的晶体结构．氟碳铈矿（ｂａｓｔｎａｅｓｉｔｅ，Ｃｅ（ＣＯ３）Ｆ）属六方晶系，其晶胞参数为：ａ＝０．７１４３８（９）ｎｍ，ｃ＝０．９８０８（２）ｎｍ，γ＝１２０°，Ｚ＝６，空间群Ｐ６－２ｃ．使用３６７个（Ｆ≥３σ（Ｆ））独立衍射点，经多轮最小二乘法修正后，最终获得偏离因子Ｒ＝０．０４９９．氟碳铈矿的晶体结构特征表现为［ＣＯ３］平面三角形平行ｃ轴分布，铈的配位数为９，Ｃｅ－Ｏ（Ｆ）平均键长为０．２５１５ｎｍ，Ｃ－Ｏ平均键长０．１３２７ｎｍ，每个氟原子与周围三个铈原子相连．氟铈矿（ｆｌｕｏｃｅｒｉｔｅ，ＣｅＦ３）属六方晶系，其晶胞参数为：ａ＝０．７１４１２（２１）ｎｍ，ｃ＝０．７２９８９（２１）ｎｍ，γ＝１２０°，Ｚ＝６．其空间群为：Ｐ３－ｃ１（Ｎｏ．１６５）．使用３２１个（Ｆ≥３σ（Ｆ）））独立衍射点，经多轮最小二乘法修正后，最终获得偏离因子Ｒ＝０．０５４２．氟铈矿的晶体结构表现为每个氟原子与周围三个铈原子相连接，每个铈原子与周围９个氟原子相连，铈的配位数为９，Ｃｅ－Ｆ平均键长为０．２４６８ｎｍ．