Structure Refinement of Cs-rich Na-Li Beryl and Analysis of Its Typomorphic Characteristics of Configurations

1 Introduction Natural beryl is an accessory mineral mainly in pegmatite, partly in some highly diffractionated granite or metamorphic rocks, with the crystal shapes beingprismatic, or occasionally tabular. For tabular beryl found in pegmatite it is believed that the tabular configuration is connected with alkali metals (Bieus, 1960; Wang et al., 1981) and geneses of the tabular configuration have been reported before. In recent years, tabular beryl has been found in the Xuebaoding W-Sn-Be d…     

钠基蒙脱土水合演化机制

为了查明钠基蒙脱土的水合演化过程,以天然钠基蒙脱土为研究对象,开展在相对湿度（ ）为0～0.98区间的水汽等温吸-脱附试验,通过吸附速率曲线、BET曲线界定钠基蒙脱土各水合阶段及相应的水合主控因素;通过测定晶层 值变化规律,从吸附水影响黏土矿物晶层厚度的角度探讨钠基蒙脱土的水合演化特征;基于傅里叶红外光谱,从水分子结构伸缩振动信息角度对钠基蒙脱土水合演化过程进行定性定量验证;通过热重/差热分析,以吸附水相变所需能量与吸附水重量变化的角度解释钠基蒙脱土的吸附水特征与其水合机制的关系。试验结果表明：在较低相对湿度下（0 0.15）,以钠基蒙脱土矿物外表面吸附为主,形成表面吸附水;0.15 0.40为钠基蒙脱土层间阳离子水合阶段;0.40 0.98,为晶层内外表面水合阶段,水分子逐步完整的包裹蒙脱土,形成多层吸附层。钠基蒙脱土的水合演化过程受控于层间钠离子与晶层基面,层间钠离子的水合能影响了钠基蒙脱土水合演化的起始顺序。     

用Pg波走时重建华北地区结晶基底速度及时间项图像

应用层析成象以投影方法，对华北地区２８条深地震剖剖面地震测深剖面Ｐｇ波走时进行处理，作出该区结晶基底速度及时间项成像。并作了方法的数值模型合成数据的敏感性分析，证明所采用有效性及成象结果的可靠性。计算中应用ＬＳＱＲ算法求解大型稀疏超定方程。并采用只存储矩阵非零元素技术，使存储量减小到原矩阵百分之一，同时零元素不参数加计算，提高了运算速度。华北地区结昌基底速度为５．９－６．３５ｋｍ／ｓ，时间最大为２     

水晶包裹体的类型及成因综述

水晶中的包裹体是在水晶生长过程中被包裹在晶体内的由一相或多相物质组成的封闭系统。水晶中包裹体的形成与生长时的物化条件密切相关 ,而生长过程中的物化环境又直接影响了水晶的结晶习性。     

压电双晶片双向大幅振动的探讨

通过压电陶瓷的逆压电效应对压电陶瓷双晶片在自动生产送料线上的应用研究，得出在二元系Ph(Ni1／3Nb2／3)O3-PhTiO3-PhZrO3的基础上作调整制作的压电双晶片。经运用在振动料斗上，作调频调幅控制。达到了压电双晶片振子结构，振子谐振频率为300Hz，当外加电压达300V时，振子偏转位移量大于1．7mm，故可作为一种理想的振动源。     

Constraints on Cation Order in Calcium-rich Sedimentary Dolomite

Most sedimentary Ca-rich dolomite in pre-Holocenerocks is known to exhibit a fine-scale modulation inTEM images, reflecting a domain structure of which onecomponent is a low-symmetry variant of dolomite. Thevarious structural models proposed for thelow-symmetry component involve Ca–Mg order patternsthat are different from that in dolomite. Caution istherefore required for interpretation of X-raydiffraction data, which average over the entirestructure. The average structures of two Ca-richdolomites having a structural modulation are refinedusing single-crystal intensity data. The resultsindicate a poor fit using a dolomite model, which isconsistent with the findings from TEM and electrondiffraction indicating that one component of thedomain structure is different than dolomite. Resultsalso indicate that average model A and B cation siteshave mixed Ca–Mg occupancy, which provides someconstraints on possible models for the low-symmetrydomains.     

时频测控技术的发展

目前，在所有的物理量中时间与频率标准的物理实现具有最高的准确度和稳定度，它们的发展不但在计量技术中，而且在几乎整个高科技领域中起着十分重要的作用。这方面的发展一直受到发达国家的高度重视。根据近年来与国外同行的技术交流和了解的情况，对时频测控技术的发展和影响等作了介绍。     

Improvement in the calculation of anti-Stokes energy transfer and experimental justification based on Er0.01YbxY1 - 0.01 - xVO4 crystal

The improvement on the calculation of anti-Stokes energy transfer rate is studied in the present work. The additional proportion coefficient between Stokes and anti-Stokes light intensities of quantum Raman scattering theory as compared with the classical Raman theory is introduced to successfully describe the anti-Stokes energy transfer. The theoretical formula for the improvement on the calculation of anti-Stokes energy transfer rate is derived for the first time in this study. The correctness of introducing coefficient exp{ΔE / kT} from well-known Raman scatter theory is demonstrated also. Moreover, the experimental lifetime measurement in Er_0.01Yb_xY_{1 - 0.01 - x}VO₄ crystal is performed to justify the validity of our important improvement in the original phonon-assisted energy transfer theory for the first time.     

袖珍矿物晶体结构模型的制作

所谓晶体结构,即晶体内部原子的排列形式}o晶体结构的表示方法有两种,即图示和模型。虽然所有的物理学、化学、矿物学和材料科学的教科书中都有晶体结构图,但是要使学生乃至专家建立结构的空间概念却绝非易事。因此,许多著名的晶体学家和矿物学家都十分强调制作模型的重要性。     

偏岭石及煅烧高岭石的红外光谱研究

通过对偏岭石和相应煅烧高岭石的红外光谱测定,发现偏岭石同煅烧高岭石在结构上有很大的差异。在偏岭石中不存在非晶态SiO_2相,其中Si—O_4四面体同Al—O_6八面体是相互聚合的:煅烧高岭石(600～995℃)中则不同,其中Si大部分是以独立的非晶态SiO_2相存在,而同其中的Al_2O_3相分离。偏岭石同煅烧高岭石的关系是:对偏岭石进行一定温度的煅烧,它可以转变成像煅烧高岭石一样的结构状态。