碱型地幔流体与富碱热液成矿

碱交代作用是整个热液作用成矿的一个基本机理,包括:①所有的热液作用是碱型地幔流体从对岩石(或岩体或地层)进行碱交代(K、Na的带入)开始的;②提供矿源(靠富K、Na热液的强烈交代作用在热液上升路途中萃取岩石矿质);③形成碱交代岩,使热液由强碱性向酸性([H+]离子浓度增长)演化,以破坏稳定的矿质迁移形式,导致沉淀、卸载、成矿;④碱交代岩是高压高温爆裂岩,角砾和次生孔隙度由此大增,有利于热液和构造再活动,成为金属成矿和油气成藏的有利储矿围岩.文章用新的证据证明此富碱热液来自深部碱型地幔流体(A-HA00NS).通过碱金属地球化学这条纲把热液作用和地幔流体作用串联为深浅一个整体.     

山东胶莱盆地边缘层间滑动角砾岩型金矿地质特征及成矿动力学背景

以蓬家夼、大庄子和发云夼为代表的胶莱盆地北缘层间滑动角砾岩型金矿是近年来确立的一种新类型金矿。这种新类型金矿产出于走滑拉分盆地边缘,并受层间滑动断裂的控制。层间滑动断裂是在伸展构造环境下形成的,一般沿大理岩等相对脆性岩层产出,是一条由碎裂岩、角砾岩等张性构造岩构成、具有一定宽度的断裂构造岩带,具有倾向滑移的特点。层间滑动角砾岩型金矿化主要发生在大理岩质碎裂岩、角砾岩等张性构造岩胶结物内。地质研究及硫、碳及氢氧同位素证据表明,成矿物质和成矿流体具有多源性的特点,以源于下地壳及上地幔的深源成矿流体为主,下渗大气降水及盆地流体不同程度地参与了成矿作用过程,对金矿的形成起到了重要的作用。控矿断裂和金矿化的形成与中生代期间华北东部大地构造环境及胶莱盆地的形成演化密切相关。受区域构造应力场的影响,断裂经历了挤压—伸展—挤压的构造过程。中生代中晚期华北东部岩石圈的剧烈拉张减薄及郯庐断裂带的强烈活动为深源成矿流体的形成和大规模上升创造了聚集和运移的条件,金矿即与这次深源岩浆活动密切相关。     

下庄铀矿田337矿床成矿流体稀土元素示踪

337铀矿床位于下庄矿田东缘,区内发育近EW向、NNE向构造裂隙群及NW向辉绿岩和正长岩脉体,发育以碱性为主的多种围岩蚀变。区内矿床主要赋矿围岩的稀土元素特征属壳源型。矿石内金属矿物以沥青铀矿为主,矿石的LREE/HREE比值为3.25,Sm/Nd比值平均为0.307,Ce/Yb比值为7.127,这些数据都显示出成矿流体具有较深来源。矿石较围岩亏损稀土元素尤其是轻稀土元素,稀土元素分布模式平缓,与幔源辉绿岩特别是与正长岩的稀土元素分布模式相近,负铕异常比围岩更为强烈,反映成矿流体的来源具有幔源性。结合区域地质特征,可以认为337矿床成矿流体来源具有幔源性质。     

Regional Variations in the Mineralogy of Metasomatic Assemblages in Mantle Xenoliths from the West Eifel Volcanic Field, Germany

Xenoliths record two distinct events in the mantle below theQuarternary West Eifel Volcanic Field, Germany. The first, duringthe Hercynian Orogeny, led to widespread formation of secondary,Ti-poor amphibole, clinopyroxene and phlogopite. The signatureof the second event, related to Quaternary volcanism, variesacross the field. At Dreiser Weiher and Meerfelder Maar, thisevent is characterized by amphibole–phlogopite–clinopyroxeneveins, hosted in lherzolite and harzburgite xenoliths broughtto the surface by sodic olivine nephelinite–basanite suitelavas. These veins formed from crystallization of sodic magmathat flowed along fractures in the mantle. At Rockeskyller Kopf,Gees and Baarley, the Quaternary event is characterized by wehrlitexenoliths, many of which have phlogopite–clinopyroxeneveins, that were transported by potassic foid suite lavas. Wehrliteformed by reaction of lherzolite–harzburgite, with a largevolume of potassic magma that flowed along grain boundariesrather than in fractures. During reaction, orthopyroxene wasconsumed and secondary clinopyroxene, olivine and phlogopiteprecipitated. Veins formed in wehrlites only during periodicover-pressure events. The composition of the magmas parentalto the veins is similar to the lavas that carried the xenolithsto surface, indicating that the source of foid and olivine nephelinite–basanitesuite magma is domainal, as was the flow regime and magma flux. KEY WORDS: Eifel; mantle xenoliths; metasomatism; trace elements     

Mg-Sr isotopes of low-δ26Mg basalts tracing recycled carbonate species: Implication for the initial melting depth of the carbonated mantle in Eastern China

ABSTRACT

Recent studies show that crustal carbonates recycled into the mantle can be traced using Mg isotopes of basalts. However, the species of recycled carbonates are poorly constrained. Carbonates have lower δ²⁶Mg values and higher ⁸⁷Sr/⁸⁶Sr ratios relative to the mantle, but different carbonate species display different mixing curves with the mantle in the Mg-Sr isotopic diagram because of differences in their Sr and Mg contents. Thus a combined study of Mg-Sr isotopes can constrain the species of deeply recycled carbonates. Here, we present newly determined ⁸⁷Sr/⁸⁶Sr ratios of the <110 Ma basalts from Eastern China, and together with published Mg isotopic data we evaluate the species of recycled carbonates in the mantle and discuss their implication. The <110 Ma basalts display low δ²⁶Mg values of ?0.60 to ?0.30‰ and relatively low initial ⁸⁷Sr/⁸⁶Sr ratios of 0.70328 to 0.70537, suggesting that their mantle source was hybridized by recycled carbonates with a light Mg isotopic composition which had more significant effects on Mg than Sr isotope ratios. Mg-Sr isotopic data indicate that the recycled carbonates consist of magnesite and aragonite, but the possibility of calcite and dolomite cannot be eliminated. Based on the carbonated peridotite solidus, the equilibrium line between dolomite and magnesite + aragonite, as well as the mantle adiabat, the initial melting depth of the carbonated mantle, the source region of the studied basalts, was constrained at ~300–360 km. Thus, the subducted depth of the west Pacific slab underlying the carbonated mantle and supplying recycled carbonates should be greater than ~300–360 km, consistent with the seismic tomography result that the west Pacific slab now stagnates in the mantle transition zone.     

鲁中碳酸岩中磷灰石同位素地球化学研究

鲁中地区分布着100多个碳酸岩体，微量元素含量及稀土配分等均与世界典型碳酸岩相近。而碳酸岩的碳氧及斑晶磷灰石的锶、钛同位素组成与典型地幔物质有差异，与富集地幔颇为近似，从而证实在山东地区陆壳下存在富集地幔源区。     

联合古陆演化周期中超大型含煤及含油气盆地的形成

联合古陆———Ｐａｎｇｅａ的拼合与裂解反映了地球系统内部的巨大变革，这一过程根本上改变了浅部圈层的构造和环境。地史上超大型含煤盆地及含油气盆地与Ｐａｎｇｅａ的演化周期密切相关。在石炭纪及二叠纪拼合过程中形成了一系列超大型聚煤盆地；晚侏罗世Ｐａｎｇｅａ开始裂解，出现全球性裂陷作用期，大西洋张开，许多与裂陷有关的大型叠合盆地形成。在这些盆地中已发现十余个与晚侏罗世烃源岩有关的巨型含油气系统。上述情况表明Ｐａｎｇｅａ演化过程中出现了对能源资源聚集极为有利的古构造、古环境和古气候条件。     

河北洞子沟银铜多金属矿床地质特征及成因分析

洞子沟银铜多金属矿床产于华北克拉通北缘长城系常州沟组地层中,受地层控制明显。通过对该矿床地质特征及矿石的稀土元素地球化学特征、矿物流体包裹体特征、硫氢氧同位素组成及U-Pb同位素年代研究表明:成矿物质来源于幔源;矿床形成于古元古代晚期华北克拉通吕梁运动后的伸展裂解过程中,在断陷盆地接受沉积的同时,有沿同生断裂上升的幔源热液、银铜金铅锌等成矿物质组分与常州沟组陆源碎屑一同沉积,形成洞子沟银铜多金属沉积层控型矿床。     

试论湖南衡阳盆地与地幔柱的关系及其对关键矿产深部探测的意义

衡阳盆地是华南地区独具特色的中—新生代陆相沉积盆地,其形成机制与丰富的矿产资源都十分引人注目。衡阳盆地近等轴形态,地形上表现为典型的“盆山体系”,重力资料显示出地幔隆起的特征,构造形式上发育“棋盘状”和“环形(弧形)”格局,火成岩与成矿元素组合以及同位素特征均具有幔源特征,这表明衡阳盆地的形成与华南地区中生代地幔柱活动之间具有密切的成因联系。盆地及其周缘矿产资源具有长时期、多矿种、强富集的特征。不同时代和不同矿种组合的成矿作用与区域岩浆作用和盆地沉积作用具有明显的专属性。衡阳盆地及周边不但出现了丰富的有色金属和非金属矿产,也出现了钨锡铌钽铋碲铀等关键矿产,但后者的工作程度最低。因此,在深部矿产探测过程中应做到“四注意四加强”。     

Implications of εNd—La／Nb,Ba／Nb,Nb／Th Diagrams to Mantle Heterogeneity—Classification of Island—arc Basalts and Decomposition of EMII Component

A group of εNd/Nb,Ba/Nb,Nb/Th diagrams are used to study mantle heterogeneity.Island-arc basalts(IAB) are distributed in a triangle of these diagrams. Three end-member components (the MORB-type depleted mantle, the fluid released from subducted oceanic crust and the sediments from the continental crust) of the source of IAB may be displayed in these diagrams. Two types of IAB are identified .They are of the two-component type (with little continental sediments), such as the basalts from Aletians and New Britain ,and the three-compeonent type, such as those from Sunda, Lesser Antilles and Andes. In addition ,the EMII type mantle-derived rocks may also be divided into two groups. One is exemplified by continental flood basalts and some peridotite xenoliths, similar to IAB, with high La/Nb and Ba/Nb and low Nb/Th ratios, The other includes the Samoa-type oceanic island basalts, with low La/Nb and Ba/Nb and high Nb/Th ratios. The corresponding two sub-components of EMII are EMIIM, which is related to the metasomatism of lithosphere mantle by fluids released from the subducted oceanic crust, and EMIISR, related to the intervention of recycling continental sediments into the convective mantle.