原地宇宙成因核素暴露测年方法中石英的提取

原地宇宙成因核素10Be和26Al的暴露年龄测定是近年来发展较快的测年技术,已在地学研究中得到广泛应用。该方法需要选用经一系列前处理过程获得的纯净石英作为待测样品,制备成BeO和Al2O3以供加速器质谱仪测量。因此获得高纯度的石英样品,是该测年方法的关键环节之一。本研究在已有报道的石英提纯化学流程的基础上,尝试对流程进行部分优化,通过实验对比不同粒径组分、不同固液比水浴振荡器和滚筒HF-HNO3蚀刻效果,确定使用HF-HNO3(1%或2%,固液比15.0 g/L)滚筒加热法刻蚀样品以去除铝硅酸盐,多钨酸钠重液分离样品中的石英和其他组分。优化的分离纯化流程应用于处理采自祁连山北缘河流阶地含石英的岩石样品,经纯化的石英纯度可达98%以上,Al的含量小于200μg/g,表明采用优化的提取流程获得了高纯度的石英样品,可以满足10Be和26Al暴露测年所需样品要求。     

Longevity and progressive abandonment of the Rocky Flats surface, Front Range, Colorado

The post-orogenic evolution of the Laramide landscape of the western U.S. has been characterized by late Cenozoic channel incision of basins and their adjacent ranges. One means of constraining the incision history of basins is dating the remnants of gravel-capped surfaces above modern streams. Here, we focus on an extensive remnant of the Rocky Flats surface between Golden and Boulder, Colorado, and use in situ-produced ¹⁰Be and ²⁶Al concentrations in terrace alluvium to constrain the Quaternary history of this surface. Coal and Ralston Creeks, both tributaries of the South Platte River, abandoned the Rocky Flats surface and formed the Verdos and Slocum pediments, which are cut into Cretaceous bedrock between Rocky Flats and the modern stream elevations. Rocky Flats alluvium ranges widely in age, from > 2 Ma to  400 ka, with oldest ages to the east and younger ages closer to the mountain front. Numerical modeling of isotope concentration depth profiles suggests that individual sites have experienced multiple resurfacing events. Preliminary results indicate that Verdos and Slocum alluvium along Ralston Creek, which is slightly larger than Coal Creek, is several hundred thousand years old. Fluvial incision into these surfaces appears therefore to progress headward in response to downcutting of the South Platte River. The complex ages of these surfaces call into question any correlation of such surfaces based solely on their elevation above the modern channel.     

The use of ablation‐dominated medial moraines as samplers for 10Be‐derived erosion rates of glacier valley walls,Kichatna Mountains,AK

We use cosmogenic ¹⁰Be concentrations in amalgamated rock samples from active, ice‐cored medial moraines to constrain glacial valley sidewall backwearing rates in the Kichatna Mountains, Alaska Range, Alaska. This dramatic landscape is carved into a small ～65 Ma granitic pluton about 100 km west of Denali, where kilometer‐tall rock walls and ‘cathedral’ spires tower over a radial array of over a dozen valley glaciers. These supraglacial landforms erode primarily by rockfall, but erosion rates are difficult to determine. We use cosmogenic ¹⁰Be to measure rockwall backwearing rates on timescales of 10³–10⁴ years, with a straightforward sampling strategy that exploits ablation‐dominated medial moraines. A medial moraine and its associated englacial debris serve as a conveyor system, bringing supraglacial rockfall debris from accumulation‐zone valley walls to the moraine crest in the ablation zone. We discuss quantitatively several factors that complicate interpretation of cosmogenic concentrations in this material, including the complex scaling of production rates in very steep terrain, the stochastic nature of the rockfall erosion process, the unmixed nature of the moraine sediment, and additional cosmogenic accumulation during transport of the sediment. We sampled medial moraines on each of three glaciers of different sizes and topographic aspects. All three moraines are sourced in areas with identical rock and similar sidewall relief of ～1 km. Each sample was amalgamated from 25 to 35 clasts collected over a 1‐km longitudinal transect of each moraine. Two of the glaciers yield similar ¹⁰Be concentrations (～1·6–2·2 × 10⁴ at/g) and minimum sidewall slope‐normal erosion rates (～0·5–0·7 mm/yr). The lowest ¹⁰Be concentrations (8 × 10³ at/g) and the highest erosion rates (1·3 mm/yr) come from the largest glacier in the range with the lowest late‐summer snowline. These rates are reasonable in an alpine glacial setting, and are much faster than long‐term exhumation rates of the western Alaska Range as determined by thermochronometric studies. Copyright © 2010 John Wiley & Sons, Ltd.     

Geomorphic and cosmogenic nuclide constraints on escarpment evolution in an intraplate setting,Darling Escarpment,Western Australia

The ～900 km long Darling Scarp in Western Australia is one of the most prominent linear topographic features on Earth. Despite the presence of over‐steepened reaches in all westerly flowing streams crossing the scarp, and significant seismic activity within 100 km of the scarp, there is no historical seismicity and no reported evidence for Quaternary tectonic displacements on the underlying Darling Fault. Consequently, it is unclear whether the scarp is a rapidly evolving landform responding to recent tectonic and/or climatic forcing or a more slowly evolving landform. In order to quantify late Quaternary rates of erosion and scarp relief processes, we obtained measurements of the cosmic‐ray produced nuclide beryllium‐10 (¹⁰Be) from outcropping bedrock surfaces along the scarp summit and face, in valley floors, and at stream knickpoints. Erosion rates of bedrock outcrops along the scarp summit surface range from 0·5 to 4·0 m Myr^?1. These are in the same range as erosion rates of 2·1 to 3·6 m Myr^?1 on the scarp face and similar to river incision rates of 2·6 to 11·0 m Myr^?1 from valley floor bedrock straths, indicating that the Darling Scarp is a slowly eroding ‘steady state’ landform, without any significant contemporary relief production over the last several 100 kyr and possibly several million years. Knickpoint retreat rates determined from ¹⁰Be concentrations at the bases of two knickpoints on small streams incised into the scarp are 36 and 46 m Myr^?1. If these erosion rates were sustained over longer timescales, then associated knickpoints may have initiated in the mid‐Tertiary to early Neogene, consistent with early‐mid Tertiary marginal uplift. Ongoing maintenance of stream disequilibrium longitudinal profiles is consistent with slow, regional base level lowering associated with recently proposed continental‐scale tilting, as opposed to differential uplift along discrete faults. Cosmogenic ¹⁰Be analysis provides a useful tool for interpreting the palaeoseismic history of intraplate near‐fault landforms over 10⁵ to 10⁶ years. Copyright © 2010 John Wiley & Sons, Ltd.     

Importance of sampling across an assemblage of glacial landforms for interpreting cosmogenic ages of deglaciation

Deglaciation chronologies for some sectors of former ice sheets are relatively poorly constrained because of the paucity of features or materials traditionally used to constrain the timing of deglaciation. In areas without good deglaciation varve chronologies and/or without widespread occurrence of material that indicates the start of earliest organic radiocarbon accumulations suitable for radiocarbon dating, typically only general patterns and chronologies of deglaciation have been deduced. However, mid-latitude ice sheets that had warm-based conditions close to their margins often produced distinctive deglaciation landform assemblages, including eskers, deltas, meltwater channels and aligned lineation systems. Because these features were formed or significantly altered during the last glaciation, boulder or bedrock samples from them have the potential to yield reliable deglaciation ages using terrestrial cosmogenic nuclides (TCN) for exposure age dating. Here we present the results of a methodological study designed to examine the consistency of TCN-based deglaciation ages from a range of deglaciation landforms at a site in northern Norway. The strong coherence between exposure ages across several landforms indicates great potential for using TCN techniques on features such as eskers, deltas and meltwater channels to enhance the temporal resolution of ice-sheet deglaciation chronologies over a range of spatial scales.     

Surface exposure dating of the Veliki vrh rock avalanche in Slovenia associated with the 1348 earthquake

Over 30 samples from bedrock and boulders from the Veliki vrh rock avalanche have been collected for surface exposure dating. The limestone rocks have been radiochemically treated to isolate and determine long-lived ³⁶Cl by accelerator mass spectrometry. It could be shown that the Veliki vrh rock avalanche from the Košuta Mountain (Slovenia) event can be very likely linked to one of the major historical earthquakes in Europe happening on the 25^th of January 1348. Taken into account independently determined denudation rates, inherited ³⁶Cl originating from pre-exposure at shallow depths (20–55 m) could be calculated. The high amount of inherited ³⁶Cl, i.e. 17–46% of the total ³⁶Cl, makes this site not suitable for a precise determination of the ³⁶Cl production rate as it was originally anticipated. Veliki vrh is a “classic” rock avalanche of high velocity. The slope failed in the upper part with a translational slide predominantly along the bedding planes, whereas dynamic fragmentation is the cause for further crushing of the material and the long runout.     

Simple computer code for estimating cosmic-ray shielding by oddly shaped objects

This paper describes computer code for estimating the effect on cosmogenic-nuclide production rates of arbitrarily shaped obstructions that partially or completely attenuate the cosmic ray flux incident on a sample site. This is potentially useful for cosmogenic-nuclide exposure dating of geometrically complex landforms. The code has been validated against analytical formulae applicable to objects with regular geometries. It has not yet been validated against empirical measurements of cosmogenic-nuclide concentrations in samples with the same exposure history but different shielding geometries.     

Erosion of a high‐altitude,low‐relief area on the Korean Peninsula: implications for its development processes and evolution

The processes involved in the development of high‐altitude, low‐relief areas (HLAs) are still poorly understood. Although cosmogenic nuclides have provided insights into the evolution of HLAs interpreted as paleo‐surfaces, most studies focus on estimating how slowly they erode and thereby their relative stability. To understand actual development processes of HLAs, we applied several techniques of cosmogenic nuclides in the Daegwanryeong Plateau, a well‐known HLA in the Korean Peninsula. Our denudation data from strath terraces, riverine sediments, soils, and tors provide the following conclusions: (1) bedrock incision rate in the plateau (~127 m Myr^?1) is controlled by the incision rate of the western part of the Korean Peninsula, and is similar to the catchment‐wide denudation rate of the plateau (~93 m Myr^?1); (2) the soil production function we observed shows weak depth dependency that may result from highly weathered bedrock coupled with frequent frost action driven by alpine climate; (3) a discrepancy between the soil production and catchment‐wide denudation rates implies morphological disequilibrium in the plateau; (4) the tors once regarded as fossil landforms of the Tertiary do not reflect Tertiary processes; and (5) when compared with those of global paleo‐surfaces (<20 m Myr^?1), our rapid denudation rates suggest that the plateau cannot have maintained its probable initial paleo landscape, and thus is not a paleo‐surface. Our data contribute to understanding the surface processes of actively eroding upland landscapes as well as call into question conventional interpretations of supposed paleo‐surfaces around the world. Copyright © 2015 John Wiley & Sons, Ltd.     

Evolution and degradation of flat‐top mesas in the hyper‐arid Negev,Israel revealed from 10Be cosmogenic nuclides

Mesas are ubiquitous landforms in arid and semiarid regions and are often characterized by horizontal stratified erodible rocks capped by more resistant strata. The accepted conceptual model for mesa evolution and degradation considers reduction in the width of the mesa flat‐top plateau due to cliff retreat but ignores possible denudation of the mesa flat‐top and the rates and mechanism of erosion. In this study we examine mesas in the northeastern hyperarid Negev Desert where they appear in various sizes and morphologies and represent different stages of mesa evolution. The variety of mesas within a single climatic zone allows examination of the process of mesa evolution through time. Two of the four sites examined are characterized by a relatively wide (200–230 m) flat‐top and a thick caprock whereas the other two are characterized by a much narrower remnant flat‐top (several meters) and thinner caprock. We use the concentration of the cosmogenic nuclide ¹⁰Be for: (a) determining the chronology of the various geomorphic features associated with the mesa; and (b) understanding geomorphic processes forming the mesa. The ¹⁰Be data, combined with field observations, suggest a correlation between the width of flat‐top mesa and the denudation and cliff retreat rates. Our results demonstrate that: (a) cliff retreat rates decrease with decreasing width of the flat‐top mesa; (b) vertical denudation rates increase with decreasing width of the flat‐top mesa below a critical value (~60 m, for the Negev Desert); (c) the reduction in the width of the flat‐top mesa is driven mainly by cliff retreat accompanied by extremely slow vertical denudation rate which can persist for a very long time (>10⁶ Ma); and (d) when the width of the mesa decreases below a certain threshold, its rate of denudation increases dramatically and mesa degradation is completed in a short time. Copyright © 2014 John Wiley & Sons, Ltd.