大兴安岭北段争光金矿英安斑岩地球化学特征、锆石U-Pb年龄及Hf同位素组成

争光金矿位于大兴安岭北段多宝山矿集区内,矿区内火成岩的成岩时代、岩石成因及成岩背景研究薄弱。因此,本文对矿区内英安斑岩进行了主微量元素、锆石U-Pb年龄和Hf同位素组成的系统研究,以期为探讨同时代火成岩的成因及矿床成矿背景提供帮助。锆石LA-ICP-MS U-Pb测年结果表明,争光金矿英安斑岩形成于早奥陶世(478~481Ma)。岩石地球化学特征显示,英安斑岩属准铝-过铝质高钾钙碱性系列,具有SiO_2≥56%(平均为63.91%)、高铝(Al_2O_3平均14.85%)、低镁(MgO平均2.70%)、低Y和Yb(Y=6.00×10~(-6)~7.74×10~(-6),Yb=0.70×10~(-6)~0.92×10~(-6))、高锶(平均368×10~(-6))、高Mg#(56.84~60.60)、轻重稀土分馏明显[(La/Yb)N=8.74~11.54]和Eu异常不明显的特点,类似于俯冲洋壳成因埃达克岩。锆石εHf(t)介于13.03~13.31之间,两阶段模式年龄(tDM2)为605~624Ma。综合岩石地球化学特征和锆石Hf同位素组成,我们认为争光英安斑岩由俯冲的新生洋壳发生部分熔融形成。本文研究结果也表明,早奥陶世,兴安地块和松嫩地块之间存在洋壳,并且该洋壳向兴安地块俯冲。     

Dimensions and deglacial chronology of the Outer Hebrides Ice Cap,northwest Scotland: implications of cosmic ray exposure dating

Cosmic ray exposure ages of frost-weathered bedrock from mountain summits in the Outer Hebrides exceed the age of Late Devensian glaciation. Exposure ages of most glacially-abraded bedrock surfaces at low and intermediate elevations are younger than the age of maximum Late Devensian glaciation. These results confirm that previously mapped periglacial trimlines in the Outer Hebrides define the upper limit of bedrock erosion by Late Devensian ice. They are consistent with the interpretation, based on geomorphological evidence, that the trimlines mark the approximate upper limit of a Late Devensian Outer Hebrides Ice Cap. A postglacial exposure age from the summit of Oreval (662 m) suggests that this mountain was overrun during the last glaciation, indicating thicker ice cover and a lower surface gradient west of the ice-cap divide than previously inferred. Although bedrock surfaces below the trimlines are strongly ice-moulded, some show evidence of prior cosmic ray exposure, which we attribute to limited erosion during Late Devensian glaciation. If this interpretation is correct, the youngest apparent ages from these surfaces give the most reliable dates for deglaciation, at ca. 14.5–14 ka. This implies that ice persisted at favourable sites through the warm opening phase of the Windermere Interstade. Comparison with radiocarbon-dated evidence from offshore cores suggests net ice margin retreat of ∼74 km eastwards across the adjacent shelf in > 2.3 ± 1.0 ka. The dating evidence is consistent with relatively rapid retreat of calving margins to the coast, then slower withdrawal of ice margins to high ground. Copyright © 2005 John Wiley & Sons, Ltd.     

Characterization, lateral variability and lateral extent of discontinuity surfaces on a Carbonate Platform (Barremian to Lower Aptian, Oman)

Hiati of various duration in carbonates are commonly expressed as discontinuity surfaces. The understanding of processes that form and affect these surfaces leads to an improved sequence-stratigraphic interpretation, a reliable outcrop correlation, and better models for reservoir compartmentalization. Various intraformational discontinuities were analysed and interpreted in a well-exposed study window, 2·5 km in lateral length and 60 m in height comprising the Barremian-Aptian Qishn Formation (Haushi-Huqf area, central Oman). This study focuses on the lateral extent and morphology of the surfaces, the petrography of the underlying rocks, and the facies changes and geochemical trends across these discontinuities. Furthermore, the lateral variability of discontinuity surfaces was documented. Three genetic types of discontinuities are differentiated: (i) erosion surfaces; (ii) omission surfaces (hard- and firmgrounds); and (iii) composite surfaces with evidence for both subaerial exposure and submarine boring. Field observations, combined with petrographic and geochemical data, suggest that 17 surfaces are laterally extensive for at least 20 km and record relative sea-level fluctuations of regional scale. In contrast, a large number of laterally limited surfaces (<1 km) are related to locally active processes such as waves and current erosion. The lateral variability along extensive surfaces is the result of the depositional environment below the discontinuity, the sea-floor topography, waves and currents and differential erosion. The most pronounced lateral variability is present along six laterally extensive composite surfaces that record terrestrial exposure and subsequent flooding of a tidal flat environment. This variability is caused by spatial variability in the tidal flat environment, meteoric alteration and differential erosion. This study emphasizes the spatial and temporal complexity of processes that form and modify discontinuity surfaces. This variability must be kept in mind when interpretations and correlations are based on one-dimensional sections or cores.     

Assessment of Workers’ Contamination Caused by Air Pollution Exposure in Industry Using Biomonitors

The workers health service is guided to look for risks. There is not an evaluation of the onset of the disease linked to a long-term exposure to low levels of toxic agents. Besides, there are few records of the level of metal concentration in the environmental air in industry, as well as few records of the level of contamination of factory workers. To assess the level of pollution in workplace, galvanising industry was chosen as the object of this study. The worker exposure and contamination levels were assessed by means of airborne particulate matter collected in air filters and biomonitors. The analysis of the air filter, hair and toenail samples were carried out by Instrumental Neutron Activation Analysis, and urine samples by Graphite Furnace Atomic Absorption Spectrophotometry. The statistical multivariate analysis and ANOVA methods were applied to elemental concentration. Copper and iron elements were highlighted as the main contributors on the differentiation of the classes. The results point out the effectiveness of biomonitors in occupational studies.     

Variations in stratigraphic and reservoir properties adjacent to the Mid-Paleocene sequence boundary, Campo section, Pyrenees, Spain

The Paleocene of the Campo section, Spain has different sedimentological characteristics above and below the Mid-Paleocene Unconformity. Beneath the unconformity sediments are dominated by evaporitic carbonates and collapse breccias. Above it they are characterized by continental detrital beds alternating with paleosols. Different subaerial features are observed and correspond to different porosity values, pore–throat sizes and micrite morphologies. Unexposed or intertidal facies have low porosity, low throat–pore size (mesoporosity) and well preserved rhombic crystals. Intermediate exposed facies (paleosols) possess medium porosity, medium pore–throat size (microporosity) and mainly micro-rhombic crystals. Finally, the facies corresponding to high exposure intensity and to evaporitic original facies presents high porosity, permeability, large pore–throat size and rounded micritic crystals. These observations show that the emersion phase caused important dissolution, especially when associated with an easily dissolved original lithofacies.     

Sediment cascades and the entangled relationship between human impact and natural dynamics at the pre-pottery Neolithic site of Göbekli Tepe,Anatolia

This study presents a meta-analysis of radiocarbon ages for the environs of Göbekli Tepe – one of the oldest monumental structures worldwide – using cumulative probability functions to diachronically assess phases of geomorphodynamic activity as controlled by natural or anthropogenic drivers. We employ sediment cascades as a heuristic framework to study the complex responses of the geomorphological system to various triggers at local to supra-regional scales. Possible triggers include climatic variability as documented by supra-regional hydroclimatic proxy data, regional demographic trends, and local to regional socioeconomic developments such as the emergence of sedentism or the introduction and dispersal of livestock herding. Our results show that phases of intensified geomorphodynamic activity occurred between ca. 7.4–7.0 and 5.8–3.3 ka BP. These phases roughly coincide with phases of population growth in southern Turkey and climatic variations in Turkey and the Levant. The phase between ca. 5.8–3.3 ka BP also corresponds to the time when organized agriculture and the seeder plough were introduced. Also, the identified phases are in agreement with the general trend of varying geomorphodynamic activity in the Eastern Mediterranean as driven by human impact and climatic change. However, neither the Younger Dryas–Holocene transition nor the development of herding during the Pre-Pottery Neolithic left a clear signature. We demonstrate how the different depositional environments in the studied landscape compartments vary with respect to their spatiotemporal coverage and discuss challenges when trying to understand processes that once shaped landscapes of past societies. © 2020 The Authors. Earth Surface Processes and Landforms published by John Wiley & Sons Ltd     

Modelling ecohydrological feedbacks in forest and grassland plots under a prolonged drought anomaly in Central Europe 2018–2020

Recent studies have highlighted the importance of understanding ecohydrological drought feedbacks to secure water resources under a changing climate and increasing anthropogenic impacts. In this study, we monitored and modelled feedbacks in the soil–plant-atmosphere continuum to the European drought summer 2018 and the following 2 years. The physically based, isotope-aided model EcH₂O-iso was applied to generic vegetation plots (forest and grassland) in the lowland, groundwater-dominated research catchment Demnitzer Millcreek (NE Germany; 66 km²). We included, inter alia, soil water isotope data in the model calibration and quantified changing “blue” (groundwater recharge) and “green” (evapotranspiration) water fluxes and ages under each land use as the drought progressed. Novel plant xylem isotope data were excluded from calibration but were compared with simulated root uptake signatures in model validation. Results indicated inter-site differences in the dynamics of soil water storage and fluxes with contrasting water age both during the drought and the subsequent 2 years. Forest vegetation consistently showed a greater moisture stress, more rapid recovery and higher variability in root water uptake depths from a generally younger soil water storage. In contrast, the grassland site, which had more water-retentive soils, showed higher and older soil water storage and groundwater recharge fluxes. The damped storage and flux dynamics under grassland led to a slower return to younger water ages at depth. Such evidence-based and quantitative differences in ecohydrological feedbacks to drought stress in contrasting soil-vegetation units provide important insights into Critical Zone water cycling. This can help inform future progress in the monitoring, modelling and development of climate mitigation strategies in drought-sensitive lowlands.     

继承性宇生核素对暴露测年结果影响的定量分析方法探讨

宇生核素暴露测年过程中,通常假设在样品最后一次暴露前,样品中的宇生核素（继承性宇生核素）浓度为0。然而,大量的测年数据研究发现,样品的暴露年代结果会受到继承性核素的影响从而高估地貌的真实年代。因此,如何降低继承性核素对暴露年代结果的影响或者定量分析继承性核素的影响程度不仅可为地貌演化提供准确的年代数据,而且对宇生核素暴露测年技术的研究具有重要意义。因此,本文以宇生核素暴露测年技术在冰川地貌中应用为例,通过分析继承性核素的研究概况,并结合宇生核素暴露测年原理,探讨继承性核素对测年结果影响的定量分析方法。研究结果表明： ① 通过样品中 n ( 26 Al)/ n ( 10 Be) 值\[即同一样品中宇生核素Al 26 与Be 10 浓度（单位为atom/g）的比值\]以及同一地貌位置多个的样品年代数据分布情况可初步判断测年结果是否受到继承性核素的影响;② 通过现代冰川冰碛物中宇生核素的浓度可以定量分析继承性核素对暴露测年结果的影响; ③ 通过计算冰碛垄顶部和一定深度（＞2~3 m）样品的宇生核素浓度差,可以减少继承性核素的影响。本研究内容对冰川地貌宇生核素暴露测年具有重要意义。     

Effect of pedogenesis on the stable isotopic composition of calcretes and n‐alkanes: Implications for palaeoenvironmental reconstruction

In a fluvial system, depending on sub‐aerial exposure, non‐pedogenic pond calcretes can be modified into pedogenic calcretes. The present study attempts to understand the effect of sub‐aerial exposure and pedogenesis on calcretes using carbon and oxygen isotopic composition. For this purpose, two profiles (profile‐A and profile‐B) from the same stratigraphic level in Rayka from the western part of India were selected. The profiles are separated by a distance of 500 m and showed differences in calcrete characteristics. In profile‐A, the calcretes showed pedogenic features (root traces and void filling spar) whereas calcretes in profile‐B showed non‐pedogenic characteristics (fine laminations). However, some of the calcretes in profile‐A exhibited remnants of fine laminations suggesting that initially the calcretes had a non‐pedogenic origin but were modified due to pedogenesis. In profile‐A, the carbon and oxygen isotope values of pedogenic calcrete (δ¹³C_PC and δ¹⁸O_PC) showed more variation compared with non‐pedogenic pond calcretes (δ¹³C_SPC and δ¹⁸O_SPC) in profile‐B. The δ¹³C_PC and δ¹³C_SPC values exhibited a spread of 3·0‰ and 1·3‰, respectively, and δ¹⁸O_PC and δ¹⁸O_SPC values showed a spread of 2·3‰ and 1·3‰, respectively. The differences in the isotopic composition between the two profiles suggest that pedogenesis controlled the isotopic inheritance in calcretes. In addition, the carbon isotopic composition of organic matter (δ¹³C_OM) and n‐alkanes (δ¹³C_n‐alk) that forms the basis of palaeovegetational reconstruction have also been measured to understand the effect of pedogenesis on organic matter in both of the profiles. The average δ¹³C_OM values in profile‐A and profile‐B are ?23·4‰ and ?21·1‰, respectively. The disparity in δ¹³C_OM values is a result of the difference in the sources and preservation of organic matter. However, the δ¹³C_n‐alk values show a similar trend in profile‐A and profile‐B, indicating that sources of n‐alkanes are the same in both of the profiles and δ¹³C_n‐alk values are unaffected by the pedogenic modifications.