熔融制样-X射线荧光光谱法测定电气石中12种主次量元素

电气石是一类含硼的铝硅酸盐矿物,化学成分复杂、化学稳定性强,不易湿法分解,B_2O_3含量较高,导致其主次量元素的同时测定存在一定困难。本文采用熔融法制样,建立了X射线荧光光谱法测定电气石Na_2O、MgO、Al_2O_3、SiO_2、P_2O_5、K_2O、CaO、TiO_2、V_2O_5、Cr_2O_3、MnO、TFe_2O_3等主次量元素的分析方法。样品与四硼酸锂-偏硼酸锂-氟化锂(质量比为4.5∶1∶0.4)混合熔剂的稀释比例为1∶10,消除了粒度效应和矿物效应;在缺少电气石标准物质的情况下,选择土壤、水系沉积物及多种类型的地质标准物质绘制校准曲线,利用含量与电气石类似的标准物质验证准确度,测定结果的相对标准偏差小于4.2%。采用所建方法测定四种不同类型电气石实际样品,测定值与经典化学法基本吻合。本方法解决了电气石不易湿法分解和硼的干扰问题,测定结果准确可靠,与其他方法相比操作简便,分析周期短。     

河流景观生态学的发展与当前核心议题

河流景观生态学已成为河流科学研究与应用的新范式,但国内研究还颇为不足。从河流景观生态学发展的逻辑必然性、主要进程、基本内容与重要理论等方面进行了总结。结果显示,多尺度跨学科整体论河流认识要求和景观尺度上处理河流问题的实践需求共同推动河流景观生态学的迅速发展,其中心议题是河流物理景观系统与生物系统在不同等级尺度上的结构、格局与功能过程,尤其重视物理景观与不同等级生物系统的相互作用关系,对河流景观多尺度等级性、高动态性和有向性等突出性质的认识已取得重要理论发展。指出当前面临5个方面的核心议题亟需取得突破:改进和统一河流景观分类系统、河流景观跨尺度研究、河流景观方法对经典河流生态理论的再认识、河流景观机理与模拟、河流景观对气候变化与区域土地利用/覆被变化的响应研究。     

Deformation patterns of upper Quaternary strata and their relation to active tectonics,Po Basin,Italy

Despite increased application of subsurface datasets below the limits of seismic resolution, reconstructing near‐surface deformation of shallow key stratigraphic markers beneath modern alluvial and coastal plains through sediment core analysis has received little attention. Highly resolved stratigraphy of Upper Pleistocene to Holocene (Marine Isotope Stage 5e to Marine Isotope Stage 1) alluvial, deltaic and coastal depositional systems across the southern Po Plain, down to 150 m depth, provides an unambiguous documentation on the deformation of previously flat‐lying strata that goes back in time beyond the limits of morphological, historical and palaeoseismic records. Five prominent key horizons, accurately selected on the basis of their sedimentological characteristics and typified for their fossil content, were used as highly effective stratigraphic markers (M1 to M5) that can be tracked for tens of kilometres across the basin. A facies‐controlled approach tied to a robust chronology (102 radiocarbon dates) reveals considerable deformation of laterally extensive nearshore (M1), continental (M2 and M3) and lagoon (M4 and M5) marker beds originally deposited in a horizontal position (M1, M4 and M5). The areas where antiformal geometries are best observed are remarkably coincident with the axes of buried ramp anticlines, across which new seismic images reveal substantially warped stratal geometries of Lower Pleistocene strata. The striking spatial coincidence of fold crests with the epicentres of historic and instrumental seismicity suggests that deformation of marker beds M1 to M5 might reflect, in part at least, syntectonically generated relief and, thus, active tectonism. Precise identification and lateral tracing of chronologically constrained stratigraphic markers in the ¹⁴C time window through combined sedimentological and palaeoecological data may delineate late Quaternary subsurface stratigraphic architecture at an unprecedented level of detail, outlining cryptic stratal geometries at the sub‐seismic scale. This approach is highly reproducible in tectonically active Quaternary depositional systems and can help to assess patterns of active deformation in the subsurface of modern alluvial and coastal plains worldwide.     

随钻测斜技术现状与发展趋势

在桩基领域,随着基础设施建筑对桩基础承载能力和桩孔垂直度的质量控制要求越来越高,现有常规桩基成孔监测技术已不能满足要求;在钻探领域,随着深井、超深井、科学钻探井及水平井的成井要求越来越高,由于地层因素、工艺技术等导致的实际钻孔轨迹偏离设计轨迹的井斜问题愈发突出,井斜的监控变得越来越严格,现有仪器已不能很好地满足钻孔轨迹测量的高精度要求。针对上述问题,本文梳理了随钻测斜技术发展现状,并结合地质岩心钻探、旋挖桩孔施工工艺特点,提出实现绳索取心钻探钻孔轨迹和大直径长钻孔灌注桩孔垂直度高精度实时监测的方案,这一思路的推广将对指导施工操作、保证钻孔/桩孔的整体质量产生积极影响。     

Brittleness index predictions from Lower Barnett Shale well-log data applying an optimized data matching algorithm at various sampling densities

The capability of accurately predicting mineralogical brittleness index(BI)from basic suites of well logs is desir-able as it provides a useful indicator of the fracability of tight formations.Measuring mineralogical components in rocks is expensive and time consuming.However,the basic well log curves are not well correlated with BI so correlation-based,machine-learning methods are not able to derive highly accurate BI predictions using such data.A correlation-free,optimized data-matching algorithm is configured to predict BI on a supervised basis from well log and core data available from two published wells in the Lower Barnett Shale Formation(Texas).This transparent open box(TOB)algorithm matches data records by calculating the sum of squared errors be-tween their variables and selecting the best matches as those with the minimum squared errors.It then applies optimizers to adjust weights applied to individual variable errors to minimize the root mean square error(RMSE)between calculated and predicted(BI).The prediction accuracy achieved by TOB using just five well logs(Gr,pb,Ns,Rs,Dt)to predict BI is dependent on the density of data records sampled.At a sampling density of about one sample per 0.5 ft BI is predicted with RMSE～0.056 and R2～0.790.At a sampling density of about one sample per 0.1 ft BI is predicted with RMSE～0.008 and R2～0.995.Adding a stratigraphic height index as an additional(sixth)input variable method improves BI prediction accuracy to RMSE～0.003 and R2～0.999 for the two wells with only 1 record in 10,000 yielding a BI prediction error of＞±0.1.The model has the potential to be applied in an unsupervised basis to predict BI from basic well log data in surrounding wells lacking mineralogical measure-ments but with similar lithofacies and burial histories.The method could also be extended to predict elastic rock properties in and seismic attributes from wells and seismic data to improve the precision of brittleness index and fracability mapping spatially.     

Discovery and significance of Lizifang metamorphic core complex in Zhuanghe area of southern Liaoning

On the basis of the previous regional geological survey, based on the macroscopic and microscopic structural survey, combined with the comprehensive analysis of the regional magmatic activity and dating data, the authors in this paper revealed that there is another metamorphic core complex structure in Lizifang area of Southern Liaoning, namely Lizifang metamorphic core complex. A typical three-layer structure and five parts exist in the core complex, which are the footwall composed of Neo-archean metamorphic plutonic rocks and mesozoic granite intrusive rocks, the detachment fault zone composed of different levels of tectonic rocks, and the upper plate composed of Precambrian sedimentary cap and Cretaceous extensional basin. Lizifang metamorphic core complex formed in the Early Cretaceous Epoch, and the upper plate moved from NWW to SEE relaive to the footwall, which was similar with Jinzhou metamorphic core complex and Wanfu metamorphic core complex in geometry, kinematics polarity and formation time, indicating the same dynamic background. The determination of the metamorphic core complex may provide a basis for the late Mesozoic lithospheric thinning process and the mechanical and rheological properties of the lithosphere in the east of North China Craton. At the same time, the metamorphic core complex is closely related to the mineralization of gold deposits. So the detachment fault zone of Lizifang metamorphic core complex can serve as the key work area for further gold exploration, which may possess large mineralization potential.     

台风Chanchu(0601)变性过程中的强度变化及环境场分析

利用非静力中尺度WRF模式模拟的台风Chanchu(0601)的输出资料,探讨了Chanchu减弱变性过程的强度及结构变化。分析结果表明:在台风Chanchu北移过程中,高层的暖心被破坏,强度快速减弱,眼壁对流发展高度降低,眼壁对流由对称结构演变为非对称,内核对流减弱。此减弱变性过程与惯性稳定度减小、垂直风切变增强、低层锋生等环境要素有关。惯性稳定度与台风强度变化一致,随着惯性稳定度降低,最大切向风减弱并不断外扩,Rossby变形半径增大从而潜热释放不集中难以维持台风强度,台风减弱;同时,内核区的高层暖心更易径向频散,从而高层暖心难以维持;环境的垂直风切变增强使台风的斜压性增强,台风垂直结构的倾斜度增大,对流发展高度降低;低层冷空气侵入台风中心趋于填塞,也利于台风强度减弱;台风登陆以后冷暖空气对比导致的锋生使得不稳定能量释放从而重新加强了Chanchu环流内的中低层对流活动,但较台风最强时刻而言对流强度减弱。总体减少的对流和降低的对流高度,导致潜热能释放减小,其向心输送也减少,不足以维持强暖心结构,最终使得台风减弱并变性。      

南极伊利莎白公主地250年来雪芯累积、氧同位素与化学研究

1Introduction In the ongoing discussion of climate change,the mass balance of Antarctica has received increasing attention during recent decades,since its reaction to global warming will strongly influence sea-level change(Schlosser and Oerter,2002).Many …     

青藏高原不同时段气候变化的研究综述

1 Introduction The annual mean world temperature increased by about 0.6℃ from the late 1800s to the 1980s (Wang, 1994). The global environmental change is marked with “global warming” and its possible effects on the ecosystem as well as the production …     

内核地球自转动力学理论的研究进展(Ⅳ)——内核自转动力学方程

本文是序列文章的第四篇,其内容包括：基于连续介质力学的基本理论,给出了固体外核（SIC）自转的动力学方程,考虑了地球的自引力、液核对内核边界的压力和二阶外部引潮力位对SIC自转的影响,并在O(mε)的量级上给出了其实用的表达式.本文的理论推导更加严密和细致,改正了文献〔1〕在推导过程中的某些错误（例如：（B39）、（B44）和（B59c）式）.本文的工作是对文献〔1〕有关理论的扩展和改进,对进一步研究内核地球自转的动力学理论是非常重要的.