Geology and geochemistry of Huanggangliang stratabound skarn deposit in Inner Mongolia, China

Over the recent three decades,exploration of a large-size Sn-Fe polymetallic ore deposit at the Huanggangliang, the Da Hinggan Mountains, Inner Mongolia, China, has been largely focused on the premise that the mineralization represents epigenetic magmatic hydrothermal ore deposit in genetic connection with the Mesozoic magmatism. The Huanggangliang Sn-Fe polymetallic ore deposits occurred in Permian strata, with siltstone/marble of the Zhesi Formation and spilite/andesite/tuff of the Dashizhai Formation. The characteristics of geological and geochemical data demonstrated that sedimentary hydrothermal mineralization occurred during the basin evolution at the Permian, rather than representing epigenetic magmatic hydrothermal genesis with the following evidences. The ore-bearing skarns are stratiform with underlying metasedimentary rocks and overlying volcanic sedimentary rocks. Sedimentary hydrothermal textures and structures are observed in the stratabound ore-bearing skarn such as bedded-laminated skarn and magnetite ores with small-size folding or soft deformation, synsedimentary breccia of skarn and magnetite ores and concentric shell structure of magnetite ores. So the stratabound ore-bearing skarns associated with magnetite ore and micro-disseminated tin, are peculiar examples of exhalite. The REE contents of the stratabound ore-bearing skarns display ΣLREE-rich (36.91×10-6) but ΣHREE-depletion (6.42×10-6), with positive Eu anomaly (Eu/ Eu 1.28) and negative Ce anomaly (Ce/Ce 0.88), which is totally different from REE pattern of the Huanggang magmatic rocks(with ΣREE 277.73×10-6, ΣLREE 220.24×10-6, ΣHREE 57.49×10-6, Eu/Eu 0.06, Ce/ Ce 1.52), which is comparable with modern sea-floor hydrothermal fluid,sedimentary hydrothermal ore deposit and associated hydrothermal sedimentary rocks. Calcite samples with δ13CPDB from -5.400 ‰ to -4.397 ‰ and δ18OSMOW from 9.095 ‰ to 9.364 ‰ in the stratabound ore-bearing skarns show sedimentary hydrothermal genesis of the Huanggangliang deposit. This proposition is useful not only for interpretation of the genesis of the Huanggangliang large Sn-Fe polymetallic ore deposit but also significant for mineral exploration in the area especially for finding large deposits caused by sedimentary exhalative mineralization processes.     

湖泊自生碳酸盐碳同位素在环境变化中的应用

湖泊自生碳酸盐碳同位素组成(δ13Cc)在区域气候与环境变化方面的应用研究近年来进展迅速,成果显著,保存在各类湖泊沉积物柱芯中的δ13Cc记录揭示了湖表水体与大气CO2的交换程度、暖季降水量的多少、流域C3和C4植被变化情况、水生生物光合作用或呼吸作用强弱、湖泊生产力大小、湖泊水体化学特征、湖水不同深度层的有机质变化过程等重要的气候和环境信息;对此进行归纳和述评。     

湖泊无机碳酸盐矿物氧同位素组成差值及其单矿物同位素组成的确定

湖积物中不同无机碳酸盐矿物常常混杂在一起,其氧同位素组成(δ18O)差异会影响碳酸盐δ18O环境信息提取的可靠性。不同矿物之间δ18O差值明显且幅度不一。20~25℃时生成的白云石比共生的方解石富集18O可能为0‰~9‰不等,亦或方解石比白云石可能更富集18O达0‰~12.3‰。常温状态,相同条件下形成的文石δ18O值较方解石高出0‰~1‰,或者方解石较文石δ18O值高出0‰~4.47‰。镁方解石中MgCO3的mol百分含量每增加1%,其δ18O值相对于纯方解石δ18O值增加0.06‰~0.17‰。在利用碳酸盐δ18O进行气候及环境研究时,不能根据某种差值进行校正,而应进行单矿物测试。由此,对不同无机碳酸盐矿物的分离及同位素测试、推算方法进行了归纳和述评。     

基于多参数指标的长江口滨岸多环芳烃来源辨析(英文)

Samples of suspended particulate matters(SPMs),surface sediment and road dust were collected from the Yangtze estuarine and nearby coastal areas,coastal rivers,and central Shanghai.The samples were analyzed for the presence of 16 polycyclic aromatic hydrocarbons(PAHs)in the USEPA priority-controlled list by GC-MS.The compound-specific stable carbon isotopes of the individual PAHs were also analyzed by GC-C-IRMS.The sources of PAHs in the SPMs and surface sediments in the Yangtze estuarine and nearby coastal...     

青海省扎日根结扎群火山岩形成时代及构造背景分析

青海扎日根结扎群火山岩中基性岩以贫硅、钾,高钛、钙,中性岩类以低硅、中钾、钛、钙,酸性岩类以高硅、钾,中钛,低钙为特征。根据Fe＊/MgO-TiO2图解上显示出本区火山岩绝大多数火山岩落在岛弧区。微量元素中Th/Nb=0.9〉0.11,Nb/Zr〉0.04显示出其构造背景为陆-陆碰撞形成的岛弧区。扎日根结扎群火山岩时代Rb-Sr同位素等时线给出的年龄为231±28Ma和225±8 Ma,属晚三叠世。另外Sr同位素的初始比值ISr=0.70522±0.00023,小于0.719,表明岩浆（原始）来源于上地幔,并且在上升的过程中受到地壳的混染。     

广东潮安四望坪铜矿区断裂控矿特征

广东潮安四望坪铜矿以岩浆期后热液交代充填成矿为特征,在其三位一体（岩浆岩、断裂/层间滑动破碎带、围岩）的控矿组合中,以流纹斑岩、晶屑凝灰岩的层间滑动破碎带为最佳。本文从矿区资料的综合研究入手,深入剖析了岩浆岩、断裂、围岩圈闭条件与矿体规模、富集程度的关系;旨在通过对矿区地质环境与矿床成因的深入分析,建立火山期后热液矿床的断裂控矿模式,为粤东火山岩地区该类矿床的发现提供理论上的启示。     

Stable carbon isotope composition of monoterpanes in essential oils and crude oils

Twenty-five monoterpanes from six types of essential oils and hydrogenated turpentine oil have been identified and their stable carbon isotope composition determined.Monoterpanes in essential oils sourced from terrestrial higher plants display a δ13C value in the range of-34‰-26‰,and mostly between-29‰ and-27‰.The δ13C value of any single monoterpane is very consistent in different essential oils.Acyclic monoterpanes show closer isotope composition between-28.6‰ and-26.2‰,with an average value of-27.7‰.In contrast,the isotope composition of cyclic monoterpanes is more scattered with an average value of-28.6‰.Isotopic fractionation with 13C enrichment has been observed during both artificial and geological hydrogenation of monoterpenoids to monoterpanes,and this is more obvious for the acyclic monoterpenoids.In addition to higher plants,acyclic monoterpane 2,6-dimethylheptane in crude oil can also be originated from other organic inputs.     

Geochemical evidence for strong ongoing methanogenesis in Sanhu region of Qaidam Basin

Sanhu depression of Qaidam Basin is the largest biogenic gas production region in China.Headspace samples were collected from two wells in this region,and hydrogen and propylene compounds were detected in these samples with a certain concentration.The stable hydrogen isotope ratio of H 2 is relatively light (-700‰--820‰).The stable carbon isotope ratio of propylene ranges from -27‰ to -40‰,which coincides with the rule of change of the stable carbon isotope of kerogen at the corresponding horizon.The charac...     

中全新世云南寻甸地区气候演化过程及其驱动机制初步研究

通过对云南寻甸仙人洞XR1石笋进行TIMS-U系测年、氧碳同位素、有机碳含量分析,重建了寻甸地区中全新世季风气候演化模式:(1)8.0～6.0kaB.P.为温暖湿润期;(2)6.0～5.1kaB.P.为气候突变期,气候由温湿变为冷干;(3)5.1～2.1kaB.P.为凉干期。通过石笋有机碳含量与石笋δ18O记录对比,认为石笋有机碳可以反映气候变化,但是存在滞后效应。最后,利用XR1石笋δ18O记录与北半球33°N太阳辐射量,本文初步分析了云南寻甸地区中全新世气候变化的驱动因素:寻甸地区中全新世气候的整体变化趋势受33°N太阳辐射量控制,同时受中全新世火山活动的影响。      

巴尔喀什成矿带奎干-玛依布拉克斑岩型铜矿区矿床地质特征与开发前景分析

哈萨克斯坦巴尔喀什湖南侧的奎干-玛依布拉克铜矿区位于巴尔喀什成矿带环巴尔喀什-准噶尔成矿省楚伊犁-北天山成矿亚省的西北部, 发育一系列中小型斑岩型铜矿床。本文概要介绍了奎干-玛依布拉克铜矿区矿床地质、围岩蚀变、成矿作用、矿石矿物组成与主要矿床特征, 并分析了铜矿床开发的前景。该铜矿区含矿岩石主要为花岗闪长斑岩, 成矿元素组合主要为Cu-Au-Mo, 具有与巴尔喀什湖北侧科翁腊德、阿克斗卡等超大型斑岩型铜矿床类似的地质特征, 说明了巴尔喀什成矿带斑岩型铜矿床的分布跨越了巴尔喀什湖, 在湖南侧也具有较好的斑岩铜矿成矿远景。