高放废物处置系统地下水同位素特征

在高放废物处置库场地特性评价中,对于深地质处置方案而言,最有可能使放射性核素进入生物圈的机制是地下水的迁移,因此,水文地质研究是场址预选和评价中的一个重要内容.本文以甘肃北山预选区旧井地段为例,根据地下水同位素数据,结合所获得的地质、水文数据和信息,分析研究了研究区基岩地下水的起源、形成、演化和循环特征.研究表明,北山预选区旧井地段,深部地下水和浅部地下水均源自大气降水的补给,弱含水、低渗透、低流速是该区的主要水文地质特征.     

敦煌地块南缘石炭纪埃达克岩的发现及其地质意义

侵位于敦煌杂岩中的青石沟黑云母石英闪长岩,锆石LA ICP-MS U-Pb同位素测年研究结果表明其形成年龄为335±2Ma。岩石地球化学分析显示其具有高SiO2、高Al2O3和低MgO的主量元素地球化学特征,强烈富集Sr、亏损Yb和Y,具有较高的Sr/Y比值等特征,与埃达克质岩石具有一致的地球化学特征。青石沟黑云母石英闪长岩的Nd和Hf同位素值(εNd(t)=-9.39~-11.03,εHf(t)=-7.6~-16.6)显示其具有明显的壳源特征;Nd及Hf模式年龄值(Nd模式年龄t DM=1.83~1.98Ga,Hf二阶段模式年龄t DM2=1.53~1.95Ga)均表明其源区可能与元古代敦煌杂岩相关;结合较高的Mg#,低Cr和Ni含量,无Eu异常等特征,暗示该岩体为加厚下地壳部分熔融的产物。综合区域地质特征,初步认为敦煌地区早石炭世处于由陆陆俯冲(地壳加厚)作用向陆内伸展体制转化的构造环境。     

新疆柴窝堡铜矿带铜沟－庙儿沟铜矿田成矿地质特征

通过柴窝堡铜矿带区域沉积环境、构造环境及岩浆活动分析，认为矿带具备铜矿成矿地质条件．具体阐述了铜沟─庙儿沟铜矿田的成矿地质地球化学特征和矿化富集规律，认为铜沟─庙儿沟铜矿区的矿床属沉积─热液叠加改造型层控矿床．     

广东湛江湖光岩地区玄武岩风化壳Fe同位素研究

本文对广东湛江湖光岩地区厚度分别为4 m和7 m的两个不同喷发时代玄武岩形成的风化壳样品进行Fe同位素分析,分析结果显示:厚度4m风化壳样品Fe同位素组成δ57Fe范围为0.17‰～0.57‰;厚度7 m风化壳样品Fe同位素组成δ57Fe范围为0.20‰～0.68‰,相对于标准物质IRMM-014,不同深度风化壳样品均显示Fe的重同位素富集.两风化壳剖面自下而上,随风化程度增大,风化壳样品中Fe同位素分馏程度也呈现逐渐增大的趋势,表明风化壳样品中Fe的重同位素富集趋势与风化壳的发育程度正相关,风化壳土壤中Fe同位素组成是反映土壤风化程度的指标.另一方面,风化过程可将地球外部圈层(岩石圈、水圈、生物圈)有机结合起来,风化壳土壤Fe同位素组成变化是表生植物和水淋滤共同作用的结果,对化学风化过程中Fe同位素研究,将会极大地补充表生过程中同位素地球化学的知识,同时Fe同位素可作为表生过程中物质的循环、环境的变化等过程中有力的示踪/指示技术手段加以应用.     

Petrogenesis and geodynamic evolution of the Kajan Neogene subvolcanic rocks,Nain, Central Iran

Kajan subvolcanic rocks in the Urumieh–Dokhtar magmatic arc (UDMA), Central Iran, form a Late Miocene-Pliocene shallow-level intrusion. These subvolcanics correspond to a variety of intermediate and felsic rocks, comprising quartz diorite, quartz monzodiorite, tonalite and granite. These lithologies are medium-K calc-alkaline, with SiO₂ (wt.%) varying from 52% (wt.%) to 75 (wt.%). The major element chemical data also show that MgO, CaO, TiO₂, P₂O₅, MnO, Al₂O₃ and Fe₂O₃ define linear trends with negative slopes against SiO₂, whilst Na₂O and K₂O are positively correlated with silica. Contents of incompatible trace elements (e.g. Ba, Rb, Nb, La and Zr) become higher with increasing SiO₂, whereas Sr shows an opposite behaviour. Chondrite-normalized multi-element patterns show enrichment in LILE relative to HFSE and troughs in Nb, P and Ti. These observations are typical of subduction related magmas that formed in an active continental margin. The Kajan rocks show a strong affinity with calc-alkaline arc magmas, confirmed by REE fractionation (La_N/Yb_N = 4.5–6.4) with moderate HREE fractionation (Sm_N/Yb_N = 1.08–1.57). The negative Eu anomaly (Eu/Eu* <1), the low to moderate Sr content (< 400 ppm) and the Dy/Yb values reflect plagioclase and hornblende (+- clinopyroxene) fractionation from a calc-alkaline melt Whole–rock Sr and Nd isotope analyses show that the ⁸⁷Sr/⁸⁶Sr initial ratios vary from 0.704432 to 0.705989, and the ¹⁴³Nd/¹⁴⁴Nd initial ratios go from 0.512722 to 0.512813. All the studied samples have similar Sr-Nd isotopes, indicating an origin from a similar source, with granite samples that has more radiogenic Sr and low radiogenic Nd isotopes, suggesting a minor interaction with upper crust during magma ascent. The Kajan subvolcanic rocks plot within the depleted mantle quadrant of the conventional Sr-Nd isotope diagram, a compositional region corresponding to mantle-derived igneous rocks.     

安徽滁州琅琊山铜矿辉钼矿铼-锇同位素定年及其地质意义

首次运用铼-锇同位素方法对滁州琅琊山铜矿床中的辉钼矿进行定年。5件辉钼矿样品的模式年龄为(128.9±1.8)Ma～(130.3±1.9)Ma,187Re-187Os等时线年龄为(128.6±2.2)Ma,其加权平均方差(MSWD)为0.45,为滁州琅琊山铜矿床提供了准确的形成时限。分析结果表明,滁州琅琊山铜矿床是早白垩纪(燕山晚期)区域构造-岩浆活动的产物。琅琊山铜矿床辉钼矿中铼含量较高,推断成矿物质主要是壳幔混源,且主要是幔源。     

钱家店凹陷含铀岩系姚家组高岭土化特征及高岭石氢氧同位素的流体指示意义

钱家店凹陷姚家组高岭石的形成与铀成矿存在流体上的密切联系。通过岩心观察、孔渗测试、光谱扫描及电镜扫描等方法分析了姚家组砂岩高岭土化蚀变空间特征,并对高岭石进行H-O同位素测试,以查明形成高岭石的相关流体及其特征。研究发现:①高岭土化蚀变往往与砂岩的漂白和铀矿化关系密切,灰-灰白色砂岩渗透率明显高于红-红棕色砂岩,联井剖面反映姚家组砂岩的高岭土化与漂白程度总体呈现出沿NW-SE向逐渐减弱的趋势;②姚家组高岭石发育,含铀矿段及围岩砂岩的高岭石含量占黏土矿物的65%～90%,高岭石的δ¹⁸O_V-SMOW值为-1.03‰～8.82‰,δD_V-SMOW值为-115.87‰～-105.51‰,显示高岭石与水具有明显的O同位素分馏现象。以H-O同位素反演流体温度为切入点,从流体温度、流体性质与流向以及流体控制因素的角度探讨形成高岭石的相关流体特征,得到以下认识:①δD-δ¹⁸O特征表明形成高岭石的流体温度在40～120℃,且研究区西北部的姚家组砂岩高岭石形成的流体温度明显高于其他地区;②与高岭石形成相关的流体可能...     

澳大利亚布朗斯(Browns)Co-Cu-Ni多金属矿床地球化学特征及与中国南方黑色岩系金属矿床对比

黑色岩系中金属元素地球化学特征一直是矿床地质研究的重点.澳大利亚布朗斯Co-Cu-Ni多金属矿产于古元古代黑色岩系中,属典型的层控矿床;该矿床中主要成矿元素为Co、Cu、Ni和Pb,矿化分带不明显,蚀变微弱.δ34S均值范围为-5.21‰～14.78‰,估计生物成因的硫占一定比例,后期有细菌还原硫酸盐成因的高硫同位素组...     

贡嘎山现代植物叶蜡脂肪酸氢同位素组成及对海拔变化的响应

文章探讨了贡嘎山东坡不同海拔高度植物和土壤饱和脂肪酸的δDwax值,结果显示,土壤δDwax值与海拔显著负相关(R2=0.71),与前人报道的贡嘎山东坡土壤水、土壤正构烷烃δD值与海拔间的关系存在相同的趋势。植物δDwax值与海拔间的关系与土壤水及土壤相似,但相关性不明显(R2=0.11),然而,研究结果显示木本植物和草本植物的δDwax值随海拔变化存在明显的差异,总体上草本植物的氢同位素要更负。贡嘎山木本植物、草本植物和土壤的εwax-sw值随海拔的变化波动较小,但木本植物的加权平均δDwax值和εwax-sw值(土壤水和叶蜡之间的氢同位素分馏系数)比草本植物大约偏正38‰和43‰,表明它们各自对随海拔高度降水同位素变化有不同的响应。也即,沿海拔植物δDwax值同时受降水δD值和植物类型两个因素控制。因此,结果揭示土壤δDwax值随海拔的变化与木本植物和草本植物存在相同的趋势,木本植物的δD值比草本植物大约偏正了38‰,这个趋势显示植物类型的变化将不可避免的影响土壤饱和脂肪酸δDwax值与海拔间的关系。由于植物类型随海拔增加会有较大的变化,建议利用饱和脂肪酸δDwax值重建古海拔前需要对植物类型进行评估。     

Trace elements and stable isotopic geochemistry of an Early Cambrian chert-phosphorite unit from the lower Yurtus Formation of the Sugetbrak section in the Tarim Basin

A chert-phosphorite unit from the Sugetbrak section in the Tarim Basin was analyzed for rare earth elements (Ce, Eu), redox sensitive proxies, and carbon isotopic compositions (δ¹³C_carb and δ ¹³C_org) in the lower Yurtus Formation of the Early Cambrian period. Redox sensitive element ratios (Th/U, V/Cr, Ni/Co, and V/Sc) were employed to determine the palaeoenvironmental conditions during this period. The ratios indicated that the depositional environment of the chert-phosphorite-black shale unit ranged from suboxic to anoxic. Negative Ce and positive Eu anomalies in the chert-phosphorite assemblages of the studied Yurtus Formation indicated the existence of a redox-stratified ocean, similar to that of South China. Overturn or upward expansion of the deep water-mass probably reached the shallow marine zone after the formation of the Yurtus phosphorites. The characteristics of the negative Ce anomaly may be due to phosphoritic inheritance from the Ce-depleted signature of the overlying water column. Subsequent hydrothermal inputs and reduced detrital supplies of the deep water caused by the upwelling affected certain redox sensitive elements in the sedimentary basin. δ ¹³C_carb and δ¹³C_org negative excursions in the Yurtus chert-phosphorite unit may be related to a transgression phase when episodic basinal upwelling moved ¹²C- and P-rich waters from the pelagic basin floor to the continental shelf. Although carbon isotopic compositions in the Yurtus chert-phosphorite assemblages may have suffered from diagenetic alteration, they can be used to probe diagenetic conditions. Multi-proxy geochemical studies indicated that the δ ¹³C_carb values of the Yurtus chert-phosphorite assemblages might be considered reflections of a predominantly suboxic environment that was subsequently affected by hydrothermal inputs due to the upwelling.