蚌埠隆起区古元古代钾长花岗岩的成因:岩石地球化学、锆石U-Pb年代学与Hf同位素的制约

对蚌埠隆起区庄子里和磨盘山钾长花岗岩进行了系统的年代学和地球化学以及锆石Hf同位素的研究, 以便对其岩石成因进行约束.研究结果表明, 庄子里和磨盘山钾长花岗岩中锆石发育震荡生长环带, 且具有较高的Th/U比值(0.13~1.47), 反映了岩浆成因特征.对庄子里和磨盘山钾长花岗岩中岩浆锆石进行的LA-ICP-MSU-Pb定年结果(上交点年龄) 分别为2104±20Ma和2196±190Ma, 这表明蚌埠隆起区钾长花岗岩的形成时代为古元古代.钾长花岗岩的SiO₂和K₂O含量分别介于69.65%~77.95%和4.98%~5.17%之间; 该类岩石富集轻稀土元素和Zr、Hf、Rb、Th、U等元素, 明显亏损Ba、Sr、Eu、P和Ti等元素; 它们的ε_Nd(t) 值变化于-3.4~+3.2之间, Nd的模式年龄变化于2.31~2.79Ga之间; 钾长花岗岩中锆石的ε_Hf(t) 值和Hf同位素两阶段模式年龄分别介于-5.1~+7.8和2.26~2.83Ga之间.上述特征表明, 蚌埠隆起区钾长花岗岩的原始岩浆起源于有少量古老地壳物质涉入的新生下地壳的部分熔融.庄子里和磨盘山钾长花岗岩为A型花岗岩, 形成于伸展的构造背景.      

Smectite formation in metalliferous sediments near the East Pacific Rise at 13°N

A 43 cm long E271 sediment core collected near the East Pacific Rise(EPR) at 13°N were studied to investigate the origin of smectite for understanding better the geochemical behavior of hydrothermal material after deposition.E271 sediments are typical metalliferous sediments. After removal of organic matter, carbonate, biogenic opal,and Fe-Mn oxide by a series of chemical procedures, clay minerals(2 μm) were investigated by X-ray diffraction,chemical analysis and Si isotope analysis. Due to the influence of seafloor hydrothermal activity and close to continent, the sources of clay minerals are complex. Illite, chlorite and kaolinite are suggested to be transported from either North or Central America by rivers or winds, but smectite is authigenic. It is enriched in iron, and its contents are highest in clay minerals. Data show that smectite is most likely formed by the reaction of hydrothermal Fe-oxyhydroxide with silica and seawater in metalliferous sediments. The Si that participates in this reaction may be derived from siliceous microfossils(diatoms or radiolarians), hydrothermal fluids, or detrital mineral phases. And their δ30 Si values are higher than those of authigenic smectites, which implies that a Si isotope fractionation occurs during the formation because of the selective absorption of light Si isotopes onto Feoxyhydroxides. Sm/Fe mass ratios(a proxy for overall REE/Fe ratio) in E271 clay minerals are lower than those in metalliferous sediments, as well as distal hydrothermal plume particles and terrigenous clay minerals. This result suggests that some REE are lost during the smectite formation, perhaps because their large ionic radii of REE scavenged by Fe-oxyhydroxides preclude substitution in either tetrahedral or octahedral lattice sites of this mineral structure, which decreases the value of metalliferous sediments as a potential resource for REE.     

中国近海生态环境变化的同位素示踪研究

同位素在确定物质来源、指示生物地球化学循环路径、定量生物地球化学过程速率等方面具有独特的优势,本文以近海生态环境变化研究中常用的稳定同位素（13C、15N、18O）和放射性核素（14C、234Th、232Th、230Th、228Th、210Po、210Pb、137Cs、226Ra、228Ra、224Ra、223Ra）为对象,介绍它们在揭示海洋有机质来源、食物网结构、水体缺氧机制、氮循环过程、颗粒动力学、海底地下水输入、有机地球化学过程、沉积年代学等方面的应用,侧重于总结我国近海生态环境研究中同位素示踪取得的进展。伴随着我国经济的发展,近百年来我国近海生态环境也发生了明显的变化,基于同位素示踪揭示的近海富营养化和沉积环境的演变规律表明,我国近海生态环境自20世纪50年代起经历持续的变化,特别是在过去20~30年时间里,近海生态环境的变化尤为剧烈,反映出人类活动是我国近海生态环境变化的主要驱动力。未来需要通过发展新的同位素技术及拓展更广泛的应用,围绕近海海洋生态环境变化的突出问题,重点揭示近海生态环境变化的响应特征、变化速率和作用机制,从而系统地掌握近海生态环境的时空变化规律。     

浙江西沪港重金属铜的配位容量和形态分析

根据2000年6月10～14日在浙江省西沪港采集的海水样品,利用AA-800石墨炉原子吸收分光光度技术和阳极溶出伏安法测定样品中重金属铜的含量,获得铜在海水中受不同的有机配体控制.不同粒级的铜表观配位容量表明西沪港海水过孔径1.00μm微孔膜的(ACuCC)较高,为144.4nmol/dm3;过0.40和0.20μm滤膜的(ACuCC)分别为103.0和102nmol/dm3;铜的有机配体条件稳定常数的对数值在7.25～9.14之间.铜的总量为21.72nmol/dm3.铜全部为稳定溶解态,其中pH2酸溶态占95.0%,强有机结合态占5.0%.溶解态铜中有机结合态占过滤海水中总铜的61.6%.     

扬子陆块西缘古元古代基性侵入岩LA-ICP-MS锆石U-Pb年龄和Hf同位素及其地质意义

扬子陆块西缘康滇南北向构造带内发育大量古元古代基性岩脉（墙）,它们对于认识扬子陆块早期的构造演化具有重要意义。对四川会理地区侵入到元古界通安组内的辉长岩进行LA-ICP-MS锆石U-Th-Pb同位素测定,获得的207Pb/206Pb加权平均年龄为1694Ma±16Ma（MSWD=0.9）,代表了该辉长岩的形成和侵位时代,这一结果指示会理地区通安组应为古元古代地层。辉长岩全岩地球化学具有类似于N-MORB的特征。辉长岩锆石初始（176Hf/177Hf）i值为0.281881~0.281982,对应的εHf（t）为6.2~9.8,单阶段亏损地幔Hf模式年龄tDM1为1738~1883Ma,平均值为1803Ma。这些数据表明古元古代辉长岩来源于亏损地幔,指示古元古代晚期扬子西缘之下存在亏损地幔。结合扬子西缘大量古老的碎屑锆石,推测扬子陆块西缘存在太古宙—古元古代的结晶基底。与扬子陆块西缘古元古代晚期基性侵入岩形成有关的幔源岩浆事件明显晚于扬子陆块古元古代碰撞造山及造山后的伸展作用,记录了扬子陆块古元古代晚期一次伸展过程,可能是Columbia超大陆裂解作用在扬子陆块的响应。     

攀西宁南地区上震旦统灯影组麦地坪段C、O同位素特征和震旦系/寒武系界线的划分

对上震旦统灯影组麦地坪段的C、O同位素组成进行了分析,并根据δ13C值在剖面上的变化特征,讨论了该地区震旦系/寒武系的界线。结果表明,麦地坪段白云岩δ13C值在-3.19‰～2.86‰之间,平均值为0.10‰;δ18O值在-10.75‰～-5.17‰之间,平均值为-7.82‰。在剖面上δ13C值出现了有规律的变化,剖面下部2～21层,δ13C值均为正值,在0.04‰～1.68‰之间,平均值为0.92‰;上部23～32层,δ13C值均为负值,在-3.19‰～-1.42‰之间,平均值为-2.13‰,δ13C值存在一个显著的负漂移,变化高达4‰。麦地坪段白云岩δ13C值的变化特征与国内外同期地层非常相似,具有全球可对比性,可作为震旦系/寒武系划分的地球化学标志。     

南华砷铊矿床雄黄标型特征

雄黄是云南省南华砷铊矿床中最主要工业矿物。它不仅与铊矿物共生，而且本身含有较高的铊，可高达（n×10～n×100）×10-6。砷铊矿床雄黄与砷矿床雄黄相比较在产出条件，微量元素、硫同位素和晶面间距等方面均有不同程度差别。前者富铊，低氯、高氟和硼，富轻硫同位素，相对贫稀土元素；后春富氯，低铊，高碘，富重硫同位素，相对贫碱土族元素。这些标型特征不仅有助于南华砷铊矿床进一步开发，而且有助于含雄黄的热液矿床，特别是As、Hg、Tl、Sb、Au等矿床的找矿勘探。     

东秦岭(河南段)二郎坪群铜多金属成矿环境及成矿效应

二郎坪群位于北秦岭造山带中,在二郎坪群这套火山—沉积岩系中,含有在河南省占有重要地位的铜多金属矿。文章通过对二郎坪群的沉积建造特征、变基性火山岩的形成环境和岩浆来源特征的研究,认为二郎坪群形成于弧后盆地环境,其盆地规模和岩浆来源在盆地东西方向上存在差异,而铜多金属矿床成矿作用与二郎坪群的形成环境和变基性火山岩岩浆来源有着紧密的内在联系。二郎坪群弧后盆地在海底喷流作用下形成了不同成矿元素组合的铜-锌型和铅-锌型两种矿床类型。     

济阳坳陷CO0_2气藏同位素地球化学特征及成因

济阳坳陷CO2气藏主要发育在高青-平南深断裂中南段和阳信次级凹陷西北缘及商店火山岩穹隆构造内。气藏中CO2气体浓度为69%~97%,δ13CCO2值为-5.67‰~-3.35‰,CH4/3He值为(1.01~5.65)×108,3He/4He值为(2.80~4.49)×10-6,即R/Ra为2.00~3.21,40Ar/36Ar值为317~1791,CO2/3He值为(0.25~2.61)×109。以上地球化学数据表明,济阳坳陷气藏中CO2主要来源于地幔,且幔源CO2在成藏过程中有损失,或者有壳源CO2的加入,特别是部分碳酸盐岩变质成因CO2的加入。在对CO2气来源定性分析的基础上,还需要在各来源的定量区分和CO2气藏的成藏及其与岩浆活动的时空匹配关系等方面作进一步的研究。     

Isotope Tracing and Prospecting Assessment of Gold-Silver Deposits in Zhejiang Province

Three different types of gold and silver deposits in Zhejiang Province(Huangshan gold deposit, Zhilingtou gold-silver deposit and Haoshi silver deposit) showmarked differences in lead and strontium isotopic composition, suggesting three differentsources and geneses of these deposits. The Huangshan gold deposit features low initial Srisotope ratios and low μ values or low content of radiogenic Pb and its ore-forming materialscame primarily from the upper mantle; the Zhilingtou gold-silver deposit shows high initial Srisotope ratios and high μ values or high content of radiogenic Pb and the ore-forming materialswere derived mainly from the upper crust; and the Haoshi silver deposit has its Pb and Srisotope ratios between the above two cases with the ore-forming materials stemming from boththe mantle and the crust. The characteristic Pb isotopic composition may serve as an indicatorfor prospecting for different types of ore deposits.