双频激电法在云南新发地区的应用

经过在测区进行双频中梯测量,圈定了4个激电异常,综合测区岩石的电性、物性特征,对异常进行了推断和解释。根据所测量的视幅频率和视电阻率结果分析,双频激电法完适应于云南地形起伏较大的地区,并能取得良好的地质效果。     

Long-Term Observations of Isotope Ratio Accuracy and Reproducibility Using Quadrupole ICP-MS

High precision isotope ratio and trace element determination can be achieved with modern quadrupole ICP-MS provided that short and long-term instrument performance is accurately monitored. Here we present results for the isotope ratios ⁶Li/⁷Li, ¹⁴⁷Sm/¹⁴⁹Sm, ¹⁶⁰Dy/¹⁶¹Dy, ²⁰⁷Pb/²⁰⁶Pb, ²⁰⁸Pb/²⁰⁶Pb, ²⁰⁶Pb/²⁰⁴Pb and ²³⁵U/²³⁸U with which we determined long-term isotope ratio stability of relevance to both trace element and isotope determination. With respect to trace element determination, we first present long-term observations regarding oxide formation rates of Ba and Nd on light REE and heavy REE, as well as Zr on Ag. These showed good correlations and could be used to correct effectively the interference. The efficacy of this correction was demonstrated with analyses of the rock reference material BHVO-2 at both low and high oxide formation rates. Next, we studied the long-term reproducibility of a Dy isotope ratio that was measured to correct for the isobaric interference on Gd. It was found that, regardless of tuning condition, the ratio reproduced very well (0.58% RSD, 1s) and that the estimate of the Gd concentration did not suffer from the large correction (> 10%) caused by the Dy isobar. Long-term reproducibilities of Li, Sm and U isotope ratios, required for accurate mass bias correction when isotopically enriched internal standards of these elements are employed, were measured in the rock reference materials AGV-2 and JA-3 over a time period of up to 3 years. As expected, the Li isotope ratio showed the largest variability (RSD = 7%), but the other two ratios had relative external reproducibilities of only 1.01% (1s, U) and 0.67% (Sm). The mass bias-induced scatter in measurements for Sm and U was so small that the internal standard correction was effective, even for samples with high concentrations of these elements. With regard to Pb-isotope ratio determination, we also present long-term reproducibility for NIST SRM 982, run as an unknown and two accuracy tests for Pb separated from granitoids and from meteorites. It is demonstrated that the obtained ratios, including those involving ²⁰⁴Pb, are accurate relative to MC-ICP-MS determinations and of comparable precision to conventional TIMS analysis. The excellent agreement between all data sets shows the potential of modern quadrupole ICP-MS instrumentation for Pb-isotope determination, particularly for samples with very low Pb content.     

Accurate and Precise Elemental Abundance of Zinc in Reference Materials by an Isotope Dilution Mass Spectrometry TIMS Technique

A thermal ionisation mass spectrometric technique enabled the abundance of Zn in geological and biological reference materials and water samples to be measured by double spiking isotope dilution mass spectrometry enriched in the ⁶⁷Zn and ⁷⁰Zn isotopes. In the past, thermal ionisation mass spectrometry proved to be difficult for low-level zinc isotopic measurements. The size of Zn samples used for isotopic determination, in particular the biological RMs, represents an important breakthrough. These results represent the most accurate and precise concentrations measured for Zn in these samples. The maximum fractional uncertainty was that for TILL-3 (2%), while the minimum fractional uncertainty was 0.7% for both BCR-1 and W-2. The inhomogeneity of Zn in HISS-1 was revealed while other reference materials appeared homogeneous at the 95% confidence uncertainty. The certified concentration of Zn in HISS-1 and IMEP-19 by their producers are 28% and 3.8% higher than the values measured in this work. These are the first Zn concentration measurements in these materials by the isotope dilution-TIMS technique, except for BCR-1, NIES N^o 9 and IMEP-19. Reducing the blank enabled accurate measurement in water at the ng g^-1 level demonstrating the applicability of the technique for low-level Zn samples.     

内蒙古西部额济纳旗地区X井油气显示特征与油气源探讨

根据内蒙古额济纳旗地区X井白垩系额济纳旗组、侏罗系麻木乌苏组、古生界顶面风化壳等不同层段的油气显示特征和钻井泥浆烃类气体组分、甲烷C同位素的分析结果,认为侏罗系和白垩系油气显示特征相同,为油与气显示,气体样品的干燥系数(C1/C总)为0.80~0.87,甲烷C同位素δ13C1为-48.19‰~-50.87‰,表现了低成熟热解气的特征;古生界风化壳为气显示,天然气干燥系数(C1/C总)为0.91~0.92,甲烷C同位素δ13C1为-21.56‰~-30.91‰,表现了高成熟热解气的特征。该井及邻区的中生界、古生界烃源岩干酪根类型及其演化程度具有显著的差别,中生界烃源岩以低成熟混合型干酪根为主,古生界烃源岩为成熟—高成熟(或过成熟)的混合型-腐泥型干酪根。表明该区存在以中生界侏罗系—白垩系低成熟烃源岩为油气源的油气系统和古生界高成熟(或过成熟)烃源岩为气源的油气系统,指示了古生界油气资源前景。     

运用H、O同位素资料分析地下热水的补给来源——以鲁西北阳谷-齐河凸起为例

通过对阳谷-齐河凸起地下热水的化学成分、同位素及其地热地质条件的分析,对这一地区的地下热水的补给来源进行了研究。本区地下热水的δD为-65‰～-80.67‰,δ18O为-9.2‰～-10.2‰,均分布在全球雨水线的附近,说明该区地下热水主要为大气降水成因。济南北地热田地下热水的补给高程为256m,此范围大致相当于济南南部山区及其以南的泰山北麓;聊城东地热田地下热水的补给高程为411m,此范围大致相当于泰山山脉及其周边的中山区。聊城东地热田地下热水的2H过量参数d明显低于济南北地热田,说明聊城东地热田地下热水的补给区比后者更远。     

中国西南地区铜矿资源现状及对地质勘查工作的几点建议

铜作为重要的战略性矿产资源,是中国当前最为突出的大宗性紧缺矿种之一。西南地区成矿地质背景优越,铜矿资源的找矿潜力巨大,国土资源大调查10年来的发现和进展已基本改变了中国铜矿资源新的战略分布格局。进一步加快西南地区铜矿资源的勘查工作进程,紧紧围绕重要成矿区带和主要的铜矿类型,不断提高工作程度,尽快实现新一轮找矿的重大突破,大幅度提高铜矿资源的储量,对全面提升国内铜矿资源的保证程度具有重要作用。     

内蒙古赤峰市鸭鸡山钼铜矿成矿流体特征及矿床成因

鸭鸡山钼铜矿床所处大地构造位置为蒙古—鄂霍次克造山带的温都尔庙—翁牛特旗褶皱带,该带是我国重要的有色金属成矿带之一。鸭鸡山钼铜矿床分布受控于区域EW向深断裂,矿体产于EW向主断裂F1上盘的二长花岗岩体中,严格受东西向F1断裂和北东向断裂控制。该矿床矿石自然类型为石英脉型和蚀变岩型,矿石中硫化物主要有黄铁矿、辉钼矿和黄铜矿。石英流体包裹体有气液两相、含子矿物三相和纯气相3种类型。流体盐度(w(NaCl))为2.06%～44.00%,集中在40%～44%和4%～8%;流体密度为0.85～1.25 g/cm3,集中在1.20～1.24 g/cm3和0.88～0.92 g/cm3;成矿温度为167～380℃,集中在320～360℃和200～220℃;流体盐度、密度、成矿温度在直方图上均表现为双峰特征。研究表明:成矿早阶段流体为高盐度、高密度和高温的岩浆流体,气相包裹体与含子晶三相包裹体共存,表明该阶段发生过强烈的沸腾或不混溶;成矿晚阶段为低盐度、低密度和中温的混合流体。通过等容线图解法估算成矿压力为274.7～368.5 MPa,用静岩压力梯度估算成矿深度为8.32～11.2 km。矿床成因类型为中成、中高温热液脉型...     

南沙珊瑚礁区波纹钩鳞鲀(Balistapus undulatus)食性和营养级分析

波纹钩鳞鲀(Balistapus undulatus)是一种在热带珊瑚礁海域中广泛分布的杂食性鱼类, 研究其自然环境中的食物组成有助于了解其食物来源及其在生态系统中的功能地位。但目前的认识仅限于他们是珊瑚礁区的海胆捕食者, 对其准确的食物组成和生态功能定位尚不清晰。本研究于2017年夏季在南沙珊瑚礁区采集了波纹钩鳞鲀样品, 通过特异性引物扩增波纹钩鳞鲀消化道中的线粒体细胞色素C氧化酶亚基Ⅰ(COⅠ)基因, 以高通量测序技术分析了其现场食物组成, 并测定了碳、氮稳定同位素以分析其营养级。研究结果显示, 波纹钩鳞鲀摄食的食物种类有13种, 分属于节肢动物门(Arthropoda)、脊索动物门(Chordata)和环节动物门(Annelida)。其中最主要的食物来源是节肢动物门扇蟹科的蟹类, 如滑面蟹(Etisus sp.)、Luniella pubescens、皱纹花瓣蟹(Liomera rugata)等, 分别占61.8%、6.7%和1.8%。鱼类也有一定的贡献, 占总食物序列的23.5%。同位素结果显示其营养级为3.71±0.07, 与分子检测的结果相符。研究结果表明波纹钩鳞鲀的主要食物是小型甲壳类动物以及植食性鹦嘴鱼, 这拓展了以往对波纹钩鳞鲀所扮演生态角色的认识。     

壳聚糖/纳米铜复合微球的制备及其对刚果红染料的脱色性能

以壳聚糖和CuCl₂·2H₂O为原料,分别采用直接负载法和吸附法成功制备了壳聚糖/纳米铜复合微球,运用傅里叶变换红外光谱(FT-IR)、X-射线衍射(XDR)和扫描电镜(SEM)对催化剂结构进行了表征。以刚果红(CR)染料为目标污染物,评价了催化剂的制备方法、制备条件及氢转移催化反应条件对其催化性能的影响。结果表明,由直接负载法(CS/CuNPs)和吸附法(CS/CuNPs-X)制备的壳聚糖/纳米铜复合微球在CR染料浓度为100 mg/L,催化剂投加量为0.05 g,供氢体浓度为0.05 mol/L的氢转移催化反应条件下,催化反应进行180和60 min时CR脱色率可分别达95.8%和96.8%。CS/CuNPs-X比CS/CuNPs表现了更高的对CR氢转移催化反应的催化速率。两种催化剂催化还原CR染料的反应均符合准一级动力学模型。在连续循环使用10次后,CS/CuNPs和CS/CuNPs-X对CR的脱色率分别为93.9%和89.4%,表明催化剂具有良好的重复使用性能。     

小秦岭地区太华群锆石U-Pb年龄及华北克拉通南缘地壳演化

以小秦岭地区太华群二长片麻岩为研究对象,分析其地球化学、锆石U-Pb年龄和Hf同位素特征。地球化学分析显示其原岩为高钾钙碱性花岗质岩石,稀土元素总含量较高(229×10-6),轻、重稀土元素分馏明显(w(La)N/w(Yb)N=45.39),有明显的Eu负异常(0.43)。原始地幔标准化微量元素蛛网图显示其富集Rb、Ba、Th、U等大离子亲石元素和亏损Nb、Ta、Sr、P、Ti等高场强元素。锆石U-Pb定年结果显示,其原岩的形成时代为古元古代早期(2.47Ga)。锆石Hf同位素分析结果显示:初始N(176 Hf)/N(177 Hf)值变化范围很小,为0.281 284~0.281 328,εHf(t)值均为正值(0.93~5.18);二阶段Hf模式年龄为2.70~2.89Ga,新生地壳(现代岛弧火山)Hf模式年龄为2.54~2.73Ga,接近于锆石结晶年龄(2.47Ga),指示华北克拉通南缘在这一时期有明显的新生地壳生长。华北克拉通南缘在新太古代早期(2.7~2.9Ga)、新太古代晚期—古元古代早期(2.2~2.5Ga)和古元古代中期(1.8~2.1Ga)有3期重要的构造热事件。新太古代早期及晚期有明显的新生地壳生长(εHf(t)0),新太古代晚期—古元古代早期和古元古代中期的岩浆活动有明显的新生地壳生长,同时还伴随有古老地壳物质的再循环和改造(εHf(t)0或εHf(t)0)。