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411.
土壤中铅铜锌镉的吸附特性 总被引:5,自引:0,他引:5
以徐州王庄矿(WZK)、奎河(KH)、背景-1(BG-1)和背景-2(BG-2)等4个土壤样品为供试对象,加入不同浓度梯度的铅、铜、锌、镉离子,通过静态实验研究了铅、铜、锌、镉的吸附特性。结果表明,土壤对4个重金属的吸附量与加入到土壤中的重金属离子浓度呈正相关性,它们之间大部分满足线性相关关系。在4个土壤样品中加入铅、铜、锌、镉离子的初始浓度比为10:10:10:1时,平衡浓度为Czn〉Ccu〉CPh〉Ccd,吸附量为Scd〉SPh〉Scu〉Szn,4个土壤样品对铅、铜、锌、镉离子的吸附能力依次为WZK〉KH〉BG-2〉BG-1。在所选实验条件下,土壤对铅、铜、锌、镉的吸附能力受土壤中铅、铜、锌、镉的含量、土壤有机质含量、阳离子交换量、土壤饱和含水量和土壤的pH值影响较大。 相似文献
412.
火焰原子吸收光谱法测定铜精矿中银含量的测量不确定度评定 总被引:2,自引:0,他引:2
采用《测量不确定度评定与表示指南》,以火焰原子吸收光谱法测定铜精矿中的银含量为例,对测量结果进行不确定度评定。分析了不确定度的重要来源,包括称样质量、标准工作溶液、工作曲线拟合、试液定容体积及测量重复性等引入的不确定度分量组成。对各不确定度分量进行分析计算,求得标准不确定度为1.56,扩展不确定度为3.12。 相似文献
413.
By combining the carbon cycle model with the records of carbonate and organic (kerogen) carbon isotope, this paper presents
the calculation of the fraction of organic carbon burial (f
org) of beds 23–40 at the global boundary stratotype section and point (GSSP) of the Permian-Triassic boundary at Meishan, Zhejiang
Province. The resulting calculation produces two episodes of f
org maxima observed to occur at beds 23–24 and 27–29, which respectively corresponds to the two episodic anoxic events indicated
by the flourish of green sulfur bacteria. Two episodic f
org minima occurred at beds 25–26 and 32–34, generally coincident with the flourish of cyanobacteria (bed 26 and upper part of
beds 29 to 34) as shown by the high value of 2-melthyhopnoanes. It appears that the f
org is related to the redox conditions, with greater f
org values observed under the reductive condition. The relationship between f
org and the total organic carbon (TOC) content was complex. The f
org value was low at some beds with a high TOC content (such as bed 26), while high observed at some beds with a low TOC content
(e.g. bed 27). This association infers the important contribution of primary productivity to the TOC content. The original
organic burial could be thus calculated through the configuration of the function of the primary productivity and f
org, which can be used to correct the residual TOC measured today. This investigation indicates that compiling the organic-inorganic
carbon isotopes with the carbon cycle model favors to understand the fraction of organic carbon burial, providing information
for the reconstruction of the coupling among biota, environments and organic burial.
Journal of China University of Geosciences, 2007, 32(6): 767–773 [译自: 地球科学—中国地质大学学报] 相似文献
414.
V. N. Sergeev M. A. Semikhatov M. A. Fedonkin A. F. Veis N. G. Vorob’eva 《Stratigraphy and Geological Correlation》2007,15(2):141-160
Expounded in this work are the results of critical consideration of published and original data on biologic nature and appearance chronology of different groups of Archean and Lower Proterozoic (3.5–1.65 Ga) paleontological remains known from geological record. Conclusions are substantiated by morphological analysis of structurally preserved microfossils, their facies distribution, and by inferable genesis and principal evolutionary trends of Archean stromatolites. A special attention is paid to variations of organic and carbonate carbon isotope composition in sedimentary successions with paleontological remains and to recent information about discovered, most ancient biomarkers of large groups of organic world. As a result of this approach, a detailed model of Precambrian organic world evolution is suggested. 相似文献
415.
Wang Yong Hou Zengqian Mo Xuanxue Dong Fangliu Bi Xianmei Zeng Pusheng 《Frontiers of Earth Science》2007,1(3):322-332
More than 140 middle-small sized deposits or minerals are present in the Weishan-Yongping ore concentration area which is
located in the southern part of a typical Lanping strike-slip and pull-apart basin. It has plenty of mineral resources derived
from the collision between the Indian and Asian plates. The ore-forming fluid system in the Weishan-Yongping ore concentration
area can be divided into two subsystems, namely, the Zijinshan subsystem and Gonglang arc subsystem. The ore-forming fluids
of Cu, Co deposits in the Gonglang arc fluid subsystem have δD values between −83.8‰ and −69‰, δ18O values between 4.17‰ and 10.45‰, and δ13C values between −13.6‰ and 3.7‰, suggesting that the ore-forming fluids of Cu, Co deposits were derived mainly from magmatic
water and partly from formation water. The ore-forming fluids of Au, Pb, Zn, Fe deposits in the Zijinshan subsystem have δD
values between −117.4‰ and −76‰, δ18O values between 5.32‰ and 9.56‰, and Δ13C values between −10.07‰ and −1.5‰. The ore-forming fluids of Sb deposits have δD values between −95‰ and −78‰, δ18O values between 4.5‰ and 32.3‰, and Δ13C values between −26.4‰ and −1.9‰. Hence, the ore-forming fluids of the Zijinshan subsystem must have been derived mainly
from formation water and partly from magmatic water. Affected by the collision between the Indian and Asian plates, ore-forming
fluids in Weishan-Yongping basin migrated considerably from southwest to northeast. At first, the Gonglang arc subsystem with
high temperature and high salinity was formed. With the development of the ore-forming fluids, the Zijinshan subsystem with
lower temperature and lower salinity was subsequently formed.
Translated from Mineral Deposits, 2006, 25(1): 60–70 [译自: 矿床地质] 相似文献
416.
In order to investigate the distribution characteristics of stable carbon isotope ratios (δ
13C) in the desert plant Reaumuria soongorica, the δ
13C values of leaves were measured in 407 individuals of 21 populations. Soil physicochemical properties including soil water
content, soil total dissolved solids, soil total nitrogen, soil total phosphorus and soil organic content were also analyzed
in order to survey the major factors influencing δ
13C values on spatial variation. Leaves and soil samples were simultaneously collected from the ten major distribution areas
in Northwest China at altitudes from 394 m to 1 987 m above sea level, at latitudes from 36°10′N to 44°33′N, and at longitudes
from 81°43′E to 106°37′E. These ten areas include Shihezi, Baicheng, Yiwu areas in Xinjiang Uygur Autonomous Region; Anxi,
Zhangye, Baiyin, Lanzhou areas in Gansu Province; Shapotou, Yinchuan areas in Ningxia Hui Autonomous Region; and Alashan County
in Inner Mongolia Autonomous Region. The results show that the δ
13C value of R. soongorica ranges from −22.77‰ to −29.85‰ with an average of −26.52‰. Foliar d13C values in R. soongorica are not significantly correlated with altitude, latitude or longitude, and a spatial distribution trend of d13C values of
R. soongorica is not obvious on a large scale. However, when d13C values of two R. soongorica populations under the same climate conditions are compared, δ
13C values increase obviously from east to west and from north to south. As none of the soil total dissolved solids, soil total
nitrogen, soil total phosphorus, and soil organic content shows a uniform trend from east to west and from north to south,
we suppose that the small-scaled spatial distribution pattern of δ
13C values of R. soongorica is mainly controlled by the soil water content.
Translated from Quaternary Sciences, 2006, 26(6): 947–954 [译自: 第四纪研究] 相似文献
417.
Brent B. Wolfe Matthew D. Falcone Ken P. Clogg-Wright Cherie L. Mongeon Yi Yi Bronwyn E. Brock Natalie A. St. Amour William A. Mark Thomas W. D. Edwards 《Journal of Paleolimnology》2007,37(2):221-231
Recent advances in sample preparation techniques and mass spectrometry have fostered more routine oxygen isotope analysis
of aquatic cellulose in lake sediment cores, a proxy for lake water oxygen isotope history. These methodological developments
have significantly increased the feasibility of incorporating this approach into high-resolution, multi-site, and multi-proxy
studies, which are frequently necessary to answer complex hydrological, hydroecological and hydroclimatic questions requiring
a paleoenvironmental perspective. Direct translation of lake sediment aquatic cellulose oxygen isotope composition into lake
water oxygen isotope composition offers appreciable opportunity for quantitative paleohydrological reconstructions, as evidenced
by studies conducted over the past 15 years that span Holocene and pre-historical timescales. 相似文献
418.
K. W. Keatings I. Hawkes J. A. Holmes R. J. Flower M. J. Leng R. H. Abu-Zied A. R. Lord 《Journal of Paleolimnology》2007,38(2):261-283
The utility of ostracod-based palaeoenvironmental reconstruction was evaluated using instrumental data for Lake Qarun, Egypt.
The euryhaline ostracod Cyprideis torosa was the only species found in the lake’s recent sediment record. This species is known to tolerate salinity levels and water
solute compositions that may prevent colonisation by other species. Oxygen and carbon isotope ratios of ostracod carbonate
from lake sediments covary with changes in instrumental values for lake level and salinity for the period 1890–1974. δ13C-values correlate negatively with lake water salinity (r
2 = 0.87) and δ18O-values correlate negatively with measured lake level changes (r
2 = 0.41). Other ostracod proxy data provide qualitative information on lake level trends. Fossil assemblage data (juvenile/adult
and valve/carapace ratios and valve preservation) provide information on wave energy. Ecophenotypic variation of C. torosa valves provided some useful palaeolimnological information. Sr/Ca and Mg/Ca ratios in ostracods were not found to reflect
water composition, due to the uncoupling of these ratios with salinity in Lake Qarun. Overall, our results highlight the need
to calibrate ostracod proxy data in modern systems prior to their use for palaeoenvironmental reconstruction. 相似文献
419.
青海湖是我国内陆最大的闭流型水体,地处东亚季风和西风的交汇影响区,对区域降水的改变等气候变化反应敏感,其水位变化历史是研究区域季风环境演变极其宝贵和重要的环境档案。青海湖Q14B孔岩芯介壳δ18Oc变化曲线自1991年发表以来,受到国内外同行的广泛关注和继续探讨。依据近年来青海湖气候与环境演变研究的最新研究结果和个人对闭流型湖泊同位素地球化学的认识,对介壳δ18Oc变化曲线进行了重新判读并得出以下结论:14.5~10.5 ka B.P.,青海湖区气候已逐渐从干冷向温湿过渡,季风降水逐渐增加;10.8~10.5 ka B.P.,青海湖处于碳酸盐滩湖环境,湖水深度从几米演变到接近干涸;10.5~9.5 kaB.P.,季风降水增加;9.5~8 ka B.P,湖水位从此前的接近干涸演变到此间的2~8 m,δ18Oc值跌落到一个较低的位置;8~3.5ka B.P,气候条件相对稳定,湖水不断蒸发引起重同位素的富集;3.5~0ka B.P,湖水处于同位素稳定阶段。研究结果还显示,δ18Oc值的短期波动与湖泊水位短期变化关系密切且明显,即水位高低分别对应δ18Oc的低值与高值。δ18Oc值的长期变化与湖泊水位长期变化关系不明显,水位较浅时,二者几乎无关联;水位较深时,水位的长期缓慢下降自然会导致δ18Oc逐渐攀升,而水位的长期缓慢上升也可以伴随δ18Oc逐渐攀升。 相似文献
420.
High-resolution climate variability of southwest China during 57-70 ka reflected in a stalagmite δ18O record from Xinya Cave 总被引:1,自引:0,他引:1
Li TingYong Yuan DaoXian Li HongChun Yang Yan Wang JianLi Wang XinYa Li JunYun Qin JiaMing Zhang MeiLiang Lin YuShi 《中国科学D辑(英文版)》2007,50(8):1202-1208
A 26-cm-long stalagmite (XY2) from Xinya Cave in northeastern Chongqing of China has been ICP-MS 230Th/U dated, showing a depositional hiatus at 2.3 cm depth from the top. The growth of the 2.3–26 cm interval determined by
four dates was between 57 ka and 70 ka, with a linear growth rate of 0.023 mm/a. We have analyzed 190 samples for δ
18O and δ
13C, mostly in the 2.3–26 cm part. The δ
18O and δ
13C values between 57 ka and 70 ka reveal decadal-to-centennial climatic variability during the glacial interval of Marine Isotope
Stage 4 (MIS4), exhibiting much higher resolution than that of the published Hulu and Dongge records during this interval.
Speleothem δ
18O in eastern China, including our study area can be used as a proxy of summer monsoon strength, with lighter values pointing
to stronger summer monsoon and higher precipitation, and vice versa. Two decreases in the δ
18O signature of XY2 record around 59.5 and 64.5 Ka are argued to correspond to the Dansgaard-Oeschger (D-O) events 17 and 18
respectively. The Heinrich event 6 (H6) can be identified in the record as a heavy δ
18O peak around 60 ka, indicating significant weakening of the monsoon in Chongqing during the cold period. The XY2 δ
18O record shows very rapid change toward to the interstadial condition of the D-O event, but more gradual change toward to
the cold stadial condition. This phenomenon found in the Greenland ice core records is rarely observed so clearly in previously
published speleothem records. According to SPECMAP δ
18O record, the glacial maximum of MIS 4 was around 64.5 ka with the boundary of MIS 3/4 around 60 ka. Unlike the marine record,
the speleothem record of XY2, China, exhibits much high frequency variations without an apparent glacial maximum during MIS
4. However, the timing of MIS 3/4 boundary seems to be around 60 ka when the H6 terminated, in agreement with the marine chronology.
The growth period of sample XY2 during glacial times probably reflects a local karstic routing of water, rather than having
climatic significance.
Supported by the National Natural Science Foundation of China (Grant Nos. 40672165, 90511004, 40672202) and the Academician
Special Project of Chongqing Science Committee (Grant No. 2003-7835) 相似文献