内蒙古东乌旗沙麦钨矿床的成矿时代

内蒙古东乌旗沙麦钨矿位于贺根山断裂带以北的兴蒙造山系二连-东乌旗弧盆带内,为岩浆期后高温热液黑钨矿石英脉型矿床。采用黑钨矿Sm-Nd同位素分析获得黑钨矿的形成年龄为137.9±1.7Ma,采用TIMS锆石U-Pb同位素定年获得赋矿黑云母花岗岩的形成年龄为139.1±0.93Ma,据此提出,沙麦钨矿床的形成时代为燕山晚期,这与区域上大兴安岭西坡主要金属矿床的形成年龄数据相吻合。黑钨矿的初始ε_(Nd)值为正值,与中亚造山带内大量花岗岩的εNd值均为正值的特点相一致,表明其来源于亏损地幔源。     

LA-ICP-MS测定锡石U-Pb同位素年龄时两种普通铅扣除方法的原理及适用性比较

根据近年来激光烧蚀电感耦合等离子体质谱仪锡石微区原位U-Pb同位素定年的实验结果,结合相关资料,对实验过程中普通铅扣除的2种主要方法,即谐和图法和等时线法的原理、效果、优点和局限性进行了深入的比较。研究成果表明,2种主要方法各有不同的优点及局限性。在实际工作中,要想获得比较准确的测试结果,需要根据具体矿物样品的年龄范围、总的U和Pb含量、普通铅相对含量、测年精度要求等因素,灵活地选择普通铅扣除的方法。     

Isotope Geochronologic and Geochemical Constraints on the Magmatic Associations of the Collisional Orogenic Zone in the West Kunlun Orogen,China

The Jiajiwaxi pluton in the southern portion of the West Kunlun Range can be divided into two collision–related intrusive rock series, i.e., a gabbro–quartz diorite–granodiorite series that formed at 224±2.0 Ma and a monzonitic granite–syenogranite series that formed at 222±2.0 Ma. The systematic analysis of zircon U-Pb geochronology and bulk geochemistry is used to discuss the magmatic origin(material source and thermal source), tectonic setting, genesis and geotectonic implications of these rocks. The results of this analysis indicate that the parent magma of the first series, representing a transition from I-type to S-type granites, formed from thermally triggered partial melting of deep crustal components in an early island–arc–type igneous complex, similar to an I-type granite, during the continental collision orogenic stage. The parent magma of the second series, corresponding to an S-type granite, formed from the partial melting of forearc accretionary wedge sediments in a subduction zone in the late Palaeozoic–Triassic. During continued collision, the second series magma was emplaced into the first series pluton along a central fault zone in the original island arc region, forming an immiscible puncture-type complex. The deep tectonothermal events associated with the continent–continent collision during the orogenic cycle are constrained by the compositions and origins of the two series. The new information provided by this paper will aid in future research into the dynamic mechanisms affecting magmatic evolution in the West Kunlun orogenic belt.     

Ore-forming Fluid and Mineral Source of the Hongshi Copper Deposit in the Kalatage Area, East Tianshan, Xinjiang, NW China

The Hongshi copper deposit is located in the middle of the Kalatage ore district in the northern segment of the Dananhu-Tousuquan island-arc belt in East Tianshan, Xinjiang, NW China. This study analyses the fluid inclusions and H, O, and S stable isotopic compositions of the deposit. The fluid-inclusion data indicate that aqueous fluid inclusions were trapped in chalcopyrite-bearing quartz veins in the gangue minerals. The homogenization temperatures range from 108°C to 299°C, and the salinities range from 0.5% to 11.8%, indicating medium to low temperatures and salinities. The trapping pressures range from 34.5 MPa to 56.8 MPa. The δ18OH2O values and δD values of the fluid range from ?6.94‰ to ?5.33‰ and from ?95.31‰ to ?48.20‰, respectively. The H and O isotopic data indicate that the ore-forming fluid derived from a mix of magmatic water and meteoric water and that meteoric water played a significant role. The S isotopic composition of pyrite ranges from 1.9‰ to 5.2‰, with an average value of 3.1‰, and the S isotopic composition of chalcopyrite ranges from ?0.9‰ to 4‰, with an average value of 1.36‰, implying that the S in the ore-forming materials was derived from the mantle. The introduction of meteoric water decreased the temperature, volatile content, and pressure, resulting in immiscibility. These factors may have been the major causes of the mineralization of the Hongshi copper deposit. Based on all the geologic and fluid characteristics, we conclude that the Hongshi copper deposit is an epithermal deposit.     

Comparative Study of Hydrogen and Carbon Isotopic Composition of Gases Generated from the Pyrolysis of a Peat under Saltwater and Freshwater Conditions

To understand the influence of the diagenetic water medium on the isotopic compositions of thermogenic coalbed gas, both hydrous and anhydrous closed-system pyrolyses were performed at temperatures of 250°C to 650°C on an herbaceous marsh peat. Compared to the results of anhydrous pyrolysis, the hydrocarbon gases generated from hydrous pyrolyses have very different hydrogen isotopic compositions. However, the carbon isotopic compositions of the hydrocarbon gases became only slightly heavier in hydrous pyrolysis, compared to that from anhydrous pyrolysis. With the progress of thermal evolution from peat to a more advanced thermal maturity of vitrinite reflectance values (Ro) of 5.5% during the pyrolysis, the difference in the average δD value increased from 52‰ to 64‰ between the hydrous pyrolysis with saltwater and anhydrous pyrolysis and increased from 18‰ to 29‰ between the hydrous pyrolysis with freshwater and anhydrous pyrolysis, respectively. The difference in the average δ13C value was only 1‰–2‰ between the hydrous and anhydrous pyrolysis. The relationships between the δD values of the generated hydrocarbon gases and Ro values as well as among δD values of the hydrocarbon gas species are established. The close relationships among these parameters suggest that the water medium had a significant effect on the hydrogen isotopic composition and a minimal effect on the carbon isotopic composition of the hydrocarbon gases. The results of these pyrolyses may provide information for the understanding of the genesis of coalbed gas from herbaceous marsh material with the participation of different diagenetic water media.     

高压超高压变泥质岩适用的地质温压计评述

高压超高压变泥质岩形成温压条件及p-T演化轨迹是高压超高压变质作用研究的重要内容。本文介绍了高压超高压变泥质岩适用的几种地质温压计,包括石榴子石-多硅白云母Fe~(2+)-Mg交换温度计、石榴子石-绿泥石Fe~(2+)-Mg交换温度计、硬绿泥石-绿泥石Fe~(2+)-Mg交换温度计、多硅白云母Si含量压力计、金红石Zr含量温度计、榍石Zr含量温压计、锆石Ti含量温度计、石英Ti含量温度计以及氧同位素温度计,并对上述温压计的适用条件及使用时的注意事项做了简要评述。     

桂东南永安岩体锆石U-Pb测年、Hf同位素特征及其地质意义

永安岩体位于钦杭结合带南部,属桂东南十万大山-大容山复式岩体的一部分,其岩石类型为斑状堇青黑云花岗闪长岩。对永安岩体斑状堇青黑云花岗闪长岩进行了LA-ICPMS锆石U-Pb测年,获得其年龄为252. 8±3. 3Ma,为晚二叠世花岗岩。对永安岩体花岗岩进行的全岩地球化学分析结果表明,岩石富Al、高K,铝饱和指数A/CNK均大于1. 1,标准矿物分子刚玉均大于1%;岩石富集轻稀土元素,亏损重稀土元素,轻重稀土元素分馏明显,稀土元素的球粒陨石标准化配分曲线为轻稀土元素富集的右倾型,具弱负铕异常;岩石富集大离子亲石元素(Rb、Ba、K、Sr),亏损高场强元素(Nb、P、Ti、Ta)和Ba、Sr。花岗岩的锆石εHf(t)=-14～-8,tDM2=2. 3～1. 8 Ga。通过本文工作,结合前人关于永安岩体矿物学、全岩地球化学、Hf同位素和锆石微量元素的分析资料,认为永安岩体岩石为强过铝质S型壳源花岗岩,地幔组分没有提供成岩物质,但地幔底侵作用为成岩提供了热能,花岗岩形成于后碰撞阶段的拉张环境中。     

塔里木陆块西北缘萨热克砂岩型铜矿床构造-流体演化对成矿的制约

塔里木陆块西北缘萨热克砂岩型铜矿床构造演化、流体演化与成矿之间具有密切关系,处于一个统一系统中。矿床成岩期方解石中包裹体水的δD值为-65.3‰~-99.2‰,改造成矿期石英包裹体水的δD值为-77.7‰~-96.3‰,成岩成矿期成矿流体δ~(18)OH_2O变化范围为-3.22‰~1.84‰,改造成矿期成矿流体δ~(18)OH_2O变化范围为-4.26‰~5.14‰,指示萨热克铜矿成岩期、改造期成矿流体主要为中生代大气降水及其经水岩作用而成的盆地卤水。矿石中辉铜矿δ~(34)S值为-24.7‰~-15.4‰,指示硫主要源自硫酸盐细菌与有机质还原,部分源于有机硫。构造与成矿流体演化对砂岩铜矿成矿起关键制约作用。盆地发展早期强烈的抬升运动使盆地周缘基底与古生界剥蚀,为富铜矿源层的形成提供了丰富物源,至晚侏罗世盆地发展晚期,长期演化积聚的巨量含矿流体在库孜贡苏组砾岩胶结物及裂隙中富集,在萨热克巴依盆地内形成具有经济意义的砂岩型铜矿床。     

内蒙古西乌旗罕乌拉地区下二叠统寿山沟组碎屑锆石LA-ICP-MS U-Pb年龄及其地质意义

中亚造山带南缘二叠纪的构造背景一直存在争议。以内蒙古西乌旗罕乌拉地区发育的寿山沟组为研究对象,开展了野外地质、岩石学、碎屑锆石LA-ICP-MS U-Pb年龄研究。2个样品锆石阴极发光图像和Th/U值指示,锆石为岩浆成因锆石。103颗碎屑锆石年龄测试结果显示,年龄信息可划分为5组:285~328Ma,峰期年龄302Ma;338~361Ma;455~490Ma;757Ma;1278Ma、2380Ma。最年轻的年龄为285Ma,结合侵入其中的花岗岩同位素年龄,指示西乌旗罕乌拉地区寿山沟组沉积时限介于285~280Ma之间,主体沉积时代应为早二叠世Sakmarian期—Artinskian期。寿山沟组碎屑锆石反映出近源、快速沉积的特点,沉积物源中含有较多的火山碎屑物,可能代表弧后盆地沉积,为早二叠世古亚洲洋闭合前洋壳俯冲消减作用的沉积响应。结合区域资料,寿山沟组碎屑锆石的年龄对应于东北地区的变质基底及其后的构造岩浆事件,物源区物质主要来自于苏尼特左旗—锡林浩特—西乌旗一带早石炭世末—晚石炭世岩浆弧及贺根山—东乌旗一带,并进一步限制了华北与西伯利亚两大板块的缝合线应位于寿山沟组发育地区的南部,即索伦缝合带,拼合时代最可能为晚二叠世—早三叠世。     

Porphyry Copper Deposit Prognosis in the Middle Region of the Bangonghu–Nujiang Metallogenic Belt,Tibet, Using ASTER Remote Sensing Data

The B angonghu–N ujiang metallogenic belt is considered to be T ibet’s third copper belt after the Y ulong and G angdese copper belts. The D uolong gold‐rich porphyry copper deposit, located in the western part of the B angonghu–N ujiang belt was recently recognized as a superlarge prospect. The A dvanced S paceborne T hermal E mission and R eflection R adiometer (ASTER ) was used to characterize the D uolong porphyry deposit alteration area, and three methods, color enhancement, band ratio transformation, and spectral angle mapping, were utilized to extract the phyllic and argillic alteration zones, which are typically considered the most important predictors of porphyry copper. Seven prospecting areas, which match mapped alteration zones, were delineated in the D uolong deposit. In addition, an ASTER image of the eastern region of the B angonghu–N ujiang belt in the X iongmei area was used to extract alteration information, and an area with image characteristics similar to the D uobuza and B olong ore deposits was identified as a prospecting area. Numerous malachite outcrops were identified in the field, and both laboratory analysis and isotopic dating confirmed that the deposit had formed concurrently with the D uobuza deposit (119 M a). Geologic mapping at the 1:5000 scale was conducted in the area, and three types of ore‐bearing rocks were identified, indicating that this area has significant potential to host ore deposits. The discovery of the X iongmei copper mining area is significant for the B angonghu–N ujiang belt.