内蒙古额济纳旗珠斯楞海尔罕北矿段锌铅金银铜矿矿床地质特征及其找矿潜力分析

内蒙古额济纳旗珠斯楞海尔罕矿区锌、铅、金、银、铜矿赋存于二叠纪花岗闪长岩、花岗斑岩与围岩的内接触带之中,属于中-低温热液矿床。二叠纪花岗闪长岩为矿体的形成提供了热源和物源,北西向的断裂构造则为花岗斑岩的侵入和成矿热液提供了通道。在珠斯楞海尔罕矿区及其邻区,发现类似的二叠纪岩浆活动以及断裂构造。因此,该地区可能发育类似成因的锌、铅、金、银、铜矿,具有良好的成矿潜力。     

Effects of heavy metals on the development and survival of abalone Haliotis midae larvae

Despite a growing abalone Haliotis midae industry in South Africa, few studies have measured the effects of heavy metals on larval survival and growth in the face of recent increases in marine pollution. The aim of this study was to quantify the effect of copper on survival and zinc on development of H. midae larvae. Larvae 24 hours old were exposed to either copper (0–30 μg l^–1) or zinc (0–200 μg l^–1) for 48 h before mortality or larval development respectively were quantified. Copper significantly reduced survival, with an LC₅₀ of 5.58 μg l^–1 (5.07–6.15, 95% CI). Although the concentrations of zinc used in the study did not have a significant effect on mortality, there was a significant effect on the incidence of abnormal larvae with an EC₅₀ of 102.25 μg l^–1 (96.68–105.94, 95% CI). At concentrations above the EC₅₀, more than 50% of the larvae showed severe developmental abnormalities. Results suggest that copper poses the greatest risk to abalone larvae as the LC₅₀ was similar to the target concentration for this metal for South African coastal waters. By contrast, zinc is potentially less problematic, with the EC₅₀ for larval development being four times the target concentration for this metal.     

饲料中铜离子对斑节对虾血细胞组成、活性和免疫功能的影响

以不同铜离子添加量(0, 10, 25, 40, 55 和110 mg/kg)的饲料喂养斑节对虾(Penaeus monodon)8 周,测定对虾的血细胞总数(THC), 并应用流式细胞术测定血细胞中含颗粒细胞(小颗粒细胞和大颗粒细胞)的比例、血细胞凋亡率、活性氧(ROS)含量和酯酶活性。结果显示, 当铜添加量为10～55 mg/kg 时, 与对照组相比, 对虾的THC、血细胞凋亡率、ROS 含量和酯酶活性均没有显著的变化(P>0.05); 铜添加量为25～110 mg/kg 时, 含颗粒细胞的比例显著提高(P<0.05); 铜添加量为110 mg/kg 时, ROS 含量显著高于其他组(P<0.05), 血细胞凋亡率高于25 和55 mg/kg 组(P<0.05), THC 低于55 mg/kg 组(P<0.05), 酯酶活性低于25mg/kg 组(P<0.05)。这些结果表明, 适宜的饲料铜含量有利于两类颗粒细胞的生成; 铜添加过量(110 mg/kg)会诱导血细胞ROS 的产生, 造成氧化损伤, 从而导致凋亡率上升和THC 下降。综上所述, 在本实验日粮条件下, 针对斑节对虾的血细胞功能, 其饲料中铜适宜添加含量范围为25～55mg/kg。     

Origin of ore-forming fluids in Qinggouzi stibnite deposit,NE China:Constraints from fluid inclusions and H-O-S isotopes

The Qinggouzi stibnite deposit is located in Huashan Town, Jilin Province, in the northeastern margin of North China Craton(NCC). It is controlled by fault structures, hosted within structurally controlled felsic dykes, predominantly surrounded by phyllite, schist and quartzite. This study presents the results of fluid inclusions studies, intending to determine the source of the fluid responsible for ore-formation, hence exploring its metallogenesis. The aqueous biphase inclusions are identified in the stibnite-bearing quartz veins of the deposit. Moreover, aqueous biphase inclusions are further classified into(1) biphase liquid-rich inclusions(1 a) and(2) biphase gas-rich inclusions(1 b) depending upon liquid to gas ratio trapped within the fluid inclusions. Homogenization temperatures for(1 a) and(1 b) range between 114.8℃ to 422℃ and 128.3℃ to 267.5℃, respectively. 1 a and 1 b have salinities of 0.18% to 16.14% NaCl_(eqv) and 1.22% to 12.88% NaCl_(eqv), and density range from 0.43 to 1.02 g/cm~3 and 0.81 to 0.98 g/cm~3, respectively. Sulfur isotopic analysis indicates δ~(34)S_(V-CDT) from 4.4×10~(-3) to 6.5×10~(-3), with an average of 5.2×10~(-3), whereas H isotopes values on δD_(V-SMOW) standard are-100.8×10~(-3) and-107.5×10~(-3), while O isotopes data on δ~(18)O_(V-SMOW) standard range between 20.1×10~(-3) and 20.4×10~(-3). Fluid inclusions study, combining with sulfur and H-O isotopic data reveal that the ore-forming fluids originated from deep source and were subsequently contaminated by meteoric water. Hydrostatic pressure calculation shows that the minimum and maximum pressures are 11.65 and 42.33 MPa, and relevant depths of deposit are estimated to be 1.16 and 4.23 km. Finally, we inferred that Qinggouzi stibnite deposit is a medium-low temperature, low salinity hydrothermal deposit, which is formed by deep source and later contaminated by meteoric water, and is classified as epizonal deposit in terms of orogenic series.     

安徽宣城地区中晚更新世风成堆积与环境变迁

通过对宣城向阳中晚更新世沉积剖面的综合研究,认为该剖面与中国北方同时代的黄土—古土壤剖面相比较,虽然长江下游以南地区中晚更新世多个冰期中风成堆积的单层厚度与累积厚度,亦即风成物质的沉积通量与沉积速率均比北方黄土区要小,但它们所反映的气候与环境的变化具有明显的可比性。     

Study on copper complexing ligand concentrations in several China’s coastal waters

Copper complexing ligand concentrations in the Daya Bay, Qingdao coast, Jiaozhou Bay, South China Sea and Huanghe Estuary waters were determined by the anodic stripping voltammetry technique. The distribution regularity and the relationship with other parameters were discussed. The results were as follows: Copper complexing ligand concentrations of the South China Sea were a little higher than those of other sea areas, and they were apparently higher than those of the ocean. Compared with the subsurface layer (SSL) in the sea surface microlayer copper complexing ligand concentrations showed an enrichment phenomenon, of which the mechanism is similar to dissolved organic matter. The metal complexing ligand concentration profiles of the South China Sea showed that the value in the sea surface was the highest, then it decreased with depth accruing, and a higher value appeared at the bottom. Copper complexing ligand concentrations were higher than those of cadmium and lead. Ligands in each sea area exhibited a complicated property. In short, the distribution regularity of copper complexing ligand concentrations in China' s coastal waters was consistent with that of other regions in the world. Meanwhile, the positive relationship between the copper complexing ligand concentrations and biological oxygen demand, chemical oxygen demand, dissolved organic carbon, and viscosity were found clearly.     

滇池螺蛳(Margarya melanioides)分布和底泥营养元素调查

研究了滇池螺蛳(Margarya melanioides)分布和底泥营养成分之间的关系。2013年在滇池87个采样点采集螺蛳和底泥样本,图示分析所有采样点的活的螺蛳数量,确定活螺在滇池中的分布位点及分布密度;选择8个采样点的底泥样本,进行16项营养元素(有机质、磷、氮、锌、铁、锰、镁、钙、铜、钠、钾、砷、汞、铅、镉、铬)含量测定,分析这些样本营养元素的差异。根据这8个采样点中有无螺蛳生长,将8个底泥样本分为两组,采用完全随机设计两样本比较的t检验,结果两组样本间仅铜的含量有统计学差异(P0.05),这可能是由于滇池螺蛳的生长有效富集了重金属铜元素,使有螺区域比无螺区域底泥中铜的含量明显减少。这在一定程度上说明了螺蛳生长与底泥的关系,可为滇池污染防治及螺蛳种群保护提供相关的科学依据。     

胶东玲珑矿田石英脉型金矿床中流体包裹体特征研究

玲珑矿田含有两种类型金矿床,一是蚀变岩型金矿床,二是石英脉型金矿床。该文重点研究玲珑金矿田西山矿区石英脉型金矿床中流体包裹体的特征。石英脉型金矿床分布在玲珑帚状构造之中,含金石英脉受"帚状构造"的断裂和节理控制,有300余条。流体包裹体显微观察研究表明,玲珑石英脉型金矿新鲜花岗岩和钾化花岗岩主要含有H2O包裹体,其次有少量H2O-CO2包裹体;(黄铁)绢英岩通常含较粗粒石英集合体,石英中有丰富的H2O,特别是H2O-CO2包裹体;金矿体(含金石英脉)含有明显数量的H2O-CO2包裹体;特别是存在较大的三相H2O-CO2包裹体。不同期次(世代)石英中H2O和H2O-CO2包裹体的大小、形态、相对含量和丰度变化较大。     

大功率激电测深法寻找焦家式深部金矿床的应用研究

大功率的激电测深法在寻找焦家式深部金矿中取得了大量的资料,由多次去除极化单元场的原理对导出大功率激电测深资料进行消除浅部强激电干扰异常,从而突出了深部矿床的激电异常,并利用处理后的激电测深曲线,定量求取了深部金矿蚀变矿化带的顶界面埋深。认为当供电极距达到一定值时,极化电场仍然会反映到地表,因此该方法可以寻找焦家式破碎带蚀变岩型的深部金矿床。     

黄河壶口段全新世古洪水事件及其水文学研究

通过对黄河中游晋陕峡谷段的考察,在多个地点发现全新世古洪水滞流沉积层。选择壶口段左岸岩棚内典型的古洪水滞流沉积剖面进行沉积学和水文学研究。对于采集的全新世地层剖面序列样品,进行粒度成分、磁化率、烧失量、CaCO₃含量等分析,从沉积学角度证明了研究剖面所夹洪水沉积物为典型的古洪水滞流沉积物,记录了全新世两个时期的特大洪水事件。通过地层学对比分析和OSL测年,确定其分别发生在全新世早期-中期转折阶段,和中期-晚期转折阶段。利用沉积学和水文学原理恢复古洪水水位,计算出第一组古洪水洪峰流量为27490m³/s、27830 m³/s、28570 m³/s,第二组为40920m³/s。本文的研究发现全新世特大洪水事件,并且恢复了其水文特征数据,对于揭示黄河水文过程对于全球变化的响应规律具有重要的科学意义,对于水利工程建设具有重要的现实意义。