内蒙古黄河吐西铜矿区地质特征及找矿远景

黄河吐西铜多金属矿位于内蒙古自治区通辽市扎鲁特旗北部,地处大兴安岭中南段多金属成矿带。近年来,笔者参与了该矿区的矿产普查工作,初步掌握了该矿区的地质及物化探特征,并发现有数条规模较大的矿化蚀变带及铜矿体,认为该区成矿条件较好,具有良好的找矿远景。     

Using amphibole phenocrysts to track vapor transfer during magma crystallization and transport: An example from Mount St. Helens,Washington

In order to evaluate and further constrain models for volatile movement and vapor enrichment of magma stored at shallow levels, amphibole phenocrysts from 2004–2005 Mount St. Helens dacite were analyzed for major and selected trace elements (Li, Cu, Zn, Mn, and REE) and Li isotopes. Several recent studies have examined fluid-mobile trace element abundances in phencryst phases and melt inclusions as a means of tracking volatile movement within subvolcanic magmatic systems, and high Li contents in plagioclase phenocrysts from 1980 and 2004 Mount St. Helens dacites have been interpreted as evidence that shallow magma was fluxed by a Li-bearing vapor phase prior to eruption.     

滇西北中甸地区的铜金找矿远景

滇西北中甸地区的铜,金矿产,分别以印支期和喜马拉雅期作为主要成矿期。铜矿分西矿带和东矿带。西矿带重点应加强欧赛拉－阿热－带的铜（多金属）矿勘查;东矿带的独哥－地苏嘎－欠虽一带是寻找斑岩型铜多金属矿最有远景的地区。寻找喜马拉雅期金矿床,重点应放在甭哥以东的富碱斑岩出露区。     

铜镍硫化物矿床的成冈——以诺里尔斯克（俄罗斯）和金川（中国）为例

与超基性岩浆作用有关的铜镍硫化物矿床主要有两种成矿建造,一种为含铬建造,另一种为含铂建造。尖晶石类矿物成分的变化清楚地反映了这两类建造的成矿属性,含铬建造的尖晶石属于铬铁矿－尖晶石系列,含铂建造中则为尖晶石－磁铁矿系列。从含铬建造向含铂建造转变的原因,可以解释为超基性岩艇中硫的作用增加,从而引起反应：４ＦｅＯ＋Ｓ＝ＦｅＳ＋Ｆｅ３Ｏ４（磁铁矿）,同时分散性铂族元素的专属性特征也发生相应变化（Ｒｕ＋Ｏｓ＋Ｉｒ）→（Ｐｔ＋Ｐｄ）。因此,含铬建造中主要富含Ｒｕ、Ｏｓ和Ｉｒ,而含铂建造中则富含Ｐｔ和Ｐｄ。超基性岩浆作用中硫的化学活动性增加与基碱度增加直接有关。因此,含铂的超基性岩大多数情况下与富碱的玄武岩形成共生组合,当富铁熔浆发生硫化作用时,将会导致硫化物与硅酸岩熔浆的不混融,从而形成矿浆,据此,金川含铂铜镍矿石不是矿     

The Rio Narcea gold belt intrusions: geology, petrology, geochemistry and timing

This paper discusses the petrographical, mineralogical and geochemical characteristics of the intrusive rocks located along the Rio Narcea Gold Belt, and the timing of formation of the El Valle-Boinás deposit. Rocks in the belt range from quartz-monzodiorites through quartz-monzogranites to monzogranites. The former are made up of pyroxene (clino and ortho), amphibole (magnesiohornblende), biotite, zoned plagioclase (An35-70), and to a lesser degree quartz and K-feldspar. The monzogranites consist of biotite, zoned plagioclase (An30-60), quartz and K-feldspar. All igneous rocks are characterized by the presence of ilmenite and the lack or scarce presence of magnetite indicating their formation under reducing conditions. The granitoids are calc-alkaline I type, potassium-rich and highly reducent with more ferrous than ferric iron. Their characteristics are like the plutons associated with gold and copper (zinc) skarns, but their characteristics reflect more reducent formation conditions, increasing their capacity to form gold skarns.The Boinas granitoid emplacement occurred at about 303±6 Ma and generated calcic and magnesic skarns at the contact with limestone and dolostones of the Láncara Formation. Skarns and granitoids were first altered to amphibole and sericite, respectively, and mineralized at 302±9 Ma. The intrusion of subvolcanic porphyritic dikes produced a second period of alteration at 285±4 Ma, characterized by carbonatization and sericitization of the monzogranites and chloritization and serpentinization of the skarns. The later intrusion of diabasic dikes at 255±6 Ma produced limited carbonatization, silicification and sericitization and hypogene oxidation of the previous stages. Supergene oxidation then occurred at the top of the ore and along fractures and breccias.     

铜（II）在高岭石表面的吸附

在天然天体系中,铜、铅、镉等重金属元素的形态分布、归宿和生物有放性强烈取决于重金属元素在水体颗粒物表面的分配趋势,本文对铜（ＩＩ）在常见的重要粘土矿物－高岭石表面的吸附进行了实难和模式研究,结果表明,在同时考虑自由水合离子Ｃｕ＾２＋和羟基金属郭子ＣｕＯＨ＾＋与高岭石表面络合的情况下,单一表面基团、无静电表面络合模式能很好地描述酮（ＩＩ）的吸附行为。拟合得到的ＣｕＯＨ＾＋的络合常数比Ｃｕ＾２＋的大得     

一种亟待重新认识的铜矿床——滇中土状铜矿

滇中土铜矿长期被认为是一种不可利用的铜矿床,新的湿法冶金技术应用使之成为了效益型铜资源。滇中土状铜矿产于中元古界昆阳群落雪组的土状风化壳内,分为面型和线型两种矿床类型。主要铜矿物为孔雀石、硅孔雀石、微粒状赤铜矿和黑铜矿、少量残余含铜硫化物。其矿石平均品位同于原生硫化矿。与原生矿石相比,土状氧化铜矿石ＳｉＯ２、Ａｌ２Ｏ３、Ｆｗ２Ｏ３、Ｍｎｏ明显富集,ＣａＯ与ＭｇＯ大量淋失,由碱性矿石变成了可酸浸的非     

钴矿石浸取液中Co、Cu、Fe的萃取分离

探讨了钴矿石浸出液中Co、Cu、Fe的萃取分离 ,以及不同萃取剂萃取上述元素时的影响因素。提取液用P2 0 4 、LIX984 和正辛酸分别萃取Fe、Cu和Co ,萃取率分别为 99.9%、99.4%和 98.1%。成功地实现了复杂钴矿石中Co、Cu、Fe的分离与提纯     

新疆巴音铜矿床硫同位素地球化学研究

采用硫同位素方法,对新疆巴音铜矿床硫化物和硫酸盐矿物进行硫同位素测定,获得硫化物和硫酸盐的δ34 S值在- 17. 5‰～ + 10. 0‰ ,硫同位素富集顺序为δ34 S重晶石> δ34 S黄铁矿> δ34 S辉铜矿> δ34 S黄铜矿。对矿床矿物包裹体测定及矿物稳定场进行物理化学计算,获得成矿温度约250℃ , log f O2为- 34. 37～- 38. 42;log f s2 为- 8. 59～-14. 0; log f CO2为-2. 3; pH值为3～6。对矿床δ34 S?S计算,获得δ34 S?S为+ 10‰ ,指示出矿石硫源来自岩浆与海水硫酸盐混合。      

甘肃北祁连山志留系沉积岩铜矿特征

甘肃北祁连山志留系沉积岩铜矿产于红绿交替碎屑岩系中 ,矿体产在志留系旱峡组灰绿色砂岩层的底部 ,具有明显的层控特征。地球化学特征表明 ,旱峡组碎屑岩中铜富集系数及其相关的矿物组合含量明显高于其它正常沉积岩。矿体宏观及微观特征表明主要控矿因素是沉积环境、沉积作用。