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941.
The objective of this study was to describe the proton promoted disproportion of synthetic manganite (γ-MnOOH) and to characterise
the resulting phase transformations. The solution and remaining solid phase after disproportionation was analysed by techniques
including atomic absorbance spectroscopy, X-ray diffraction (XRD), atomic force microscopy (AFM) and scanning electron microscopy
(SEM). In suspensions with pH between 5 and 7, −log[H+] was monitored for 17 months and equilibrium constants were determined at 9, 12 and 17 months of reaction time for the following
reaction (25 °C, 0.1 M (Na)NO3):
The formed MnO2 ages with time and the equilibrium constant for a metastable phase (ramsdellite or nsutite) as well as the most stable phase,
pyrolusite (β-MnO2), was determined. Furthermore, combined pH and pe (Eh) measurements were performed to study the equilibrium;
Real-time AFM measurements of the dissolution showed shrinkage of the length of the manganite needles with time (2 hours).
After 1 week SEM images showed that this decreased length also was followed by a reduced thickness of the manganite needles.
From the SEM images the morphology of the formed Mn(IV) oxides was studied. At pH 2.6, pyrolusite (β-MnO2) and MnCl2 were found in the XRD patterns. Throughout the pH range there were indications of ramsdellite (MnO1.97) in the XRD patterns, which coincided with the existence of a fraction of needle shaped crystals with smaller dimensions
(compared to manganite) in the SEM images. These observations together with the long term dissolution experiments suggest
that the dissolution of manganite initially forms a ramsdellite or nsutite phase that over time rearranges to form pyrolusite. 相似文献
942.
基于小波变换的大安地区年降水量变化特征 总被引:3,自引:0,他引:3
基于小波分析的方法,对吉林省大安地区1959—2007年的年降水量序列的变化特征进行了分析。经分析表明,大安地区年降水量在其计算时域内各时间尺度分布不均匀,具有明显的局部化特征;其中4~6 a尺度主要发生在1959—1969年和1984年之后,10~12 a尺度主要发生在1965—1999年,20~25a尺度在整个计算时域内均有发生。不同时间尺度下,降水量偏多、偏少交替变化也不相同。此外,分析结果显示该地区年降水量具有4 a、10 a和21 a左右的主周期,其中4 a周期为第一主周期。 相似文献
943.
Abstract The outer parts of a number of small Late Jurassic sandy deep‐water fans in the northern North Sea are dominated by the stacked deposits of co‐genetic sandy and muddy gravity flows. Sharp‐based, structureless and dewatered sandstone beds are directly overlain by mudclast breccias that are often rich in terrestrial plant fragments and capped by thin laminated sandstones, pseudonodular siltstones and mudstones. The contacts between the clast‐rich breccias and the underlying sandstones are typically highly irregular with evidence for liquefaction and upward sand injection. The breccias contain fragments (up to metre scale) of exotic lithologies surrounded by a matrix that is extremely heterogeneous and strewn with multiphase and variably sheared sand injections and scattered coarse and very coarse sand grains (often coarser than in the immediately underlying sand bed). Markov chain analysis establishes that the breccias consistently overlie sandstones, and the character of the breccias and their external contacts rule out a post‐depositional origin via in situ liquefaction, intrastratal flowage or bed amalgamation and disruption. The breccias are interpreted as debrites that rode on a water‐rich sand bed just deposited by a co‐genetic concentrated gravity current. As such, they are referred to as ‘linked debrites’ to distinguish them from debrites emplaced in the absence of a precursor sand bed. The distinction is important, because these linked debris flows can achieve significant mobility through entrainment of both water and sediment from beneath, and they ride on a low‐friction carpet of liquefied sand. This explains the paradox presented by fan fringes in which there are common debrites, when conventional thinking might predict that deposits of low‐concentration gravity currents should be more important here. In fact, evidence for transport by low‐concentration turbidity currents is rare in these systems. Several possible mechanisms might explain the formation of linked flows, but the ultimate source of both sandy and clast‐rich flow components must be in shallower water on the basin margin (the debrites are not triggered from distal slopes). Flow partitioning may have occurred by upslope erosion and retardation of the mudclast‐charged portion of an erosional sandy density current, partial flow transformation of a precursor debris flow and/or hydraulic segregation and reconcentration of the flaky clasts and carbonaceous matter during transport. Linked debrites are not restricted to small sand‐rich fans, and similar mechanisms may be responsible for the long runout of debris flows in other systems. The recognition of a distinct class of linked debrites is of wider importance for facies prediction, reservoir heterogeneity and even carbon fluxes and sequestration on continental margins. 相似文献
944.
介绍了地理信息系统开发的技术路线,阐述了建立地理信息系统过程中,如何解决系统模型建立、系统的空间坐标系统、数据质量问题和系统的质量体系等重要问题。 相似文献
945.
用改进的佐迪反演方法进行二维电阻率图像重建 总被引:1,自引:0,他引:1
针对佐迪反演方法在二维拟断面应用中的缺陷进行了三个方面的改进:固定佐迪反演方法中用于转换电极距和深度关系的深度转换因子,可使绝大多数数字模型的反演过程稳定收敛;在调整视电阻率的公式中加入一个迭代系数,可使计算值快速趋向于观测值,减少了迭代次数;对于含有噪声的数据,加入滤波因子可以在一定程度上抑制噪声。通过数字模拟和野外实测数据对改进后的佐迪反演方法在二维电阻率反演应用中的可行性进行了验证。模拟研究包含了简单模型,也包含一些复合模型,二者均取得较理想的应用效果。 相似文献
946.
Wilfried Heller 《GeoJournal》2000,50(2-3):151-155
There is no standard model of transformation for post- socialist countries and each country encounters specific problems rooted
in the geographical characteristics of the areas concerned. The human resources are of the greatest importance because it
really matters how people (especially the decision-makers) perceive system change and continually reformulate their expectations
and strategies; so investigations into the views of people caught up in the transformation can provide a deeper understanding
of the background to structural change. Working the national, regional level and local levels in Romania, experts were asked
to consider the advantages and disadvantages arising out of the transformation, the most important problems and constraints
for future rural development and the policies needed. The paper examines the responses on demographic and social issues. It
emerges the most detailed responses were supplied by local-level representatives while respondents at the regional level steered
a middle course between the need to address local problems and the prime importance of stimulating the Romanian economy so
as to generate resources for welfare programmes (with the latter issue the overriding concern of interviewees at national
level). There was general agreement on the importance of foreign investment and European integration for economic development,
with local actors taking only small steps in line with the existing opportunities.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
947.
一种重磁特征线的自动提取方法 总被引:1,自引:0,他引:1
本文介绍一种最大梯度追踪和旋转变换方法,可用于重磁数字图像特征线自动提取。该方法分两步进行,首先用最大梯度追踪法产生二态像素图,然后用旋转变换方法将二态像素图的栅格特征线转换成矢量特征线。此方法生成的文件可以与GIS接口。 相似文献
948.
勘察设计企业向国际型工程公司战略转型的思考 总被引:1,自引:0,他引:1
向国际型工程公司转型已经成为国内大型勘察设计企业的战略性选择,文章分析了勘察设计企业的发展特点、现状及存在的问题,研究了战略转型的决定性条件,并结合实际提出了建议意见。 相似文献
949.
Large numbers of peatlands were developed in volcanic landform regions, which would provide valuable long-term records of lake–mire ecosystem shifts and act as significant carbon pool in regional carbon cycle. To investigate lake–mire ecosystem transformations and driving mechanisms in volcanic landform regions, the developmental history of Gushantun peatland in northeast China was reconstructed in this study. Results indicate that Gushantun peatland initiated in the deepest portions of the basin, and subsequently experienced expansions outward. Peat initiated from approximately 12 ka cal. bp to present. The developmental patterns of Gushantun peatland can be divided into four stages: the stable stage 1 (12–10 ka cal. bp ), maximum stage (10–7 ka cal. bp ), stable stage 2 (7–4 ka cal. bp ) and stable stage 3 (4–0 ka cal. bp ). The possible forcing mechanisms for the development of Gushantun peatland were different during different periods. From 12 ka cal. bp to 10 ka cal. bp , autogenic process was probably the major controlling factor for the expansion of this peatland. From 10 to 7 ka cal. bp , flat basin morphology was the major influence factor for fast expansion. However, the development of Gushantun peatland was probably controlled by the dual effects of high moisture and autogenic process during the period of 7 to 4 ka cal. bp . From 4 ka cal. bp to present, steep basin morphology was the major influence factor, while moisture might be the secondary factor for development of Gushantun peatland. These features indicate that lake–mire ecosystem transforms in volcanic landform regions of Changbai Mountains were probably triggered by the complex effects of autogenic process, hydroclimate and underlying basin morphology. © 2020 John Wiley & Sons, Ltd. 相似文献
950.
利用希尔伯特-黄变换方法,对成都、重庆、拉萨地磁台记录到的汶川MS 8.0地震、汶川地震余震地磁数据进行分析处理,发现在4级及以上中强度地震前3个月内地磁相对观测HHT频谱中能观测到一定程度的地震前兆异常,各分量的优势频率大部分在0.01 Hz,但并不是距震中300 km内的每个台站的地磁相对观测分量HHT频谱中都能明显地观测到异常,这可能与台站所处的构造位置有关。 相似文献