地幔交代作用的微区微量元素证据——云南双沟蛇绿岩的质子探针研究

用质子探针技术对双沟地幔交代熔融物的微区微量元素进行了测定。研究表明,地幔橄榄岩中的残留矿物橄榄石和斜方辉石仅含Ni和Zn,而Ga、Ge、Sr、Rb、Zr、Y、As、Pb等微量元素主要集中在地幔部分熔融所产生的矿物(尤其是尖晶石和绿泥石)中。微区范围内微量元素的分布表明,尖晶石二辉橄榄岩地幔不均一性的尺度可达微米级,通常解释为尖晶石二辉橄榄岩在开放系统下地幔交代作用的结果。     

民和盆地上侏罗统湿型冲积扇沉积

本文通过岩相特征、粘土矿物分布、早期成岩矿物组合、微量元素等特征的综合分析，认为民和盆地上侏罗统下部为一较典型的湿型冲积扇沉积。冲积扇扇中发育河道冲刷充填和漫流沉积，而泥石流不发育。沉积层序与现代湿型冲积扇可对比。扇体中粘土岩及早期成岩矿物组合中富含高岭石，应与扇体发育时的潮湿气候和弱酸性流体的较强的淋滤有关。由粘土岩中微量元素因子分析进一步表明，该地层中富硼、钒的特征与相邻非扇相地层明显不同     

地震和测井资料联合反演储层物性参数的方法

为了充分利用测井资料较高的纵向分辨率及其反映井壁周围物性直接准确的特点和地震资料良好的横向可追踪性，针对厚储层和薄储层地震—地质模型分别提出了利用测井和地震资料联合反演纵横波速度和密度参数的方法。理论模型的计算结果表明，反演方法是切实可行的     

泌阳凹陷核桃园组微量元素演化特征及其古气候意义

泌阳凹陷下第三系核桃园组总体上表现为一个大的湖退体系，而其中的微量元素含量及有关元素比值却呈现出细微而明显的旋回变化特征。本文依据泥岩、页岩和碳酸盐岩中Ｔｉ、Ｓｒ、Ｂａ等十六种微量元素含量及Ｓｒ/Ｂａ、Ｆｅ/Ｍｎ、Ｓｒ/Ｃｕ等七种比值的变化特征，结合古盐度及岩相资料，对核桃园组沉积时的古气候作了系统的研究，基本上分出了温暖潮湿、干湿交替、炎热干旱、温热半干旱四类较为特征的古气候类型，以期为油气勘探提供依据。     

催化褪色光度法测定痕量锰的研究及应用

本研究了在ＰＨ＝４．０醋酸－醋酸钠缓冲溶液中，锰催化ＫＩＯ４氧化５－Ｂｒ－ＰＡＤＡＰ的褪色反应及其动力学条件，建立了一个痕量锰的高灵敏度新方法，方法灵敏度为１．３２×１０＾－１０ｇ／ｍｌ，测定范围Ｍｎ＾２＋浓度为０￣１．５μｇ／ｍｌ，用于测定人发，自来水，茶叶中痕量锰，结果满意。     

安徽铜陵矿集区海底喷流沉积体系的流体包裹体微量元素对比

铜陵矿集区与铜-金(多金属)矿床有关的热液活动主要有两大体系。即与海西期海底喷流沉积有关的热液体系和与矽卡岩矿化有关的燕山期岩浆热液体系。查明这两类热液体系的流体包裹体特征对区域找矿和矿床成因研究都有实际意义。在包裹体岩相学研究基础上，应用ICP-MS技术和热爆提取方法，研究了新桥、冬瓜山、峙门口、铜官山、朝山等矿床具代表性的热液石英中流体包裹体的微量元素、稀土元素特征。结果表明，两类热液体系在流体包裹体特征上有较大的区别，在流体的微量元素和稀土元素特征方面也很不相同。海底喷流沉积体系的热液石英中流体包裹体与岩浆热液体系的相比。稀土总量较高，LREE／HREE比值较大，δEu不明显。且Mo／(W Sn)比值较高，反映流体中成矿物质的深源特征；Ga／T1、Rb／Cs大。Zr／Hf低，也不同于岩浆热液体系。     

豫西济源谭庄组河流沉积中的Stipsellus遗迹组构

豫西济源盆地上三叠统谭庄组下段为曲流河沉积。本文通过描述和分析谭庄组河流沉积特征，划分了4种不同河流沉积组合类型，识别出Stipsellus遗迹组构，并发现该遗迹组构常与曲流河沉积物伴生，可作为此类沉积的典型生物遗迹标志。其中，Stipsellus sp．A代表发育在河漫滩较浅水体下或潮湿的软底细粒沉积物中的一种遗迹组构类型；Stipsellus sp．B则代表发育在曲流砂坝上部的男一种遗迹组构类型。     

Hydrothermal Mineralization on the Mesoproterozoic Passive Continental Margins of China： A Case Study of the Langshan-Zha＇ertaishan Belt, Inner Mongolia, China

Most ore-forming characteristics of the Langshan-Zha‘ertaishan hydrothermal exhalation belt, which consists of the Dongshengmiao, Huogeqi, Tanyaokou and Jiashengpan large-superlarge Zn-Pb-Cu-Fe sulfide deposits, are most similar to those of Mesoproterozoic SEDEX-type provinces of the world. The characteristics include: (1) All deposits of this type in the belt occur in third-order fault-basins in the Langshan-Zha‘ertaishan aulacogen along the northern margin of the North China Platform; (2) these deposits with all their orebodies hosted in the Mesoproterozoic impure dolomite-marble and carbonaceous phyllite (or schists) have an apparent stratabound nature; ores display laminated and banded structures, showing clear depositional features; (3) there is some evidence of syn-sedimentary faulting, which to a certain extent accounts for the temporal and spatial distribution and the size of the orebodies in all deposits and the formation of intrabed conglomerates and breccias; (4) they show lateral and vertical zonation of sulfides; (5) The Cu/(Pb Zn Cu) ratio of the large and thick Pb Zn Cu orebodies gradually decreases from bottom to top; and (6) barite is interbedded with pyrites and sometimes with sphalerite. However, some characteristics such as the Co/Ni radio of the pyrites, the volcanism, for example, of the Langshan-Zha‘ertalshan metallogenic belt, are different from those of the typical SEDEX deposits of the world. The meta-basic volcanic rock in Huogeqi, the sodic bimodal volcanic rocks in the Dongshengmiao and potassic bimodal-volcanic rocks with blastoporphyfitic and blasto-glomeroporphyritic texture as well as blasto-amygdaloidal structure in the Tanyaokou deposits have been discovered in the only ore-bearing second formation of the Langshan Group in the past 10 years. The metallogeny of some deposits hosted in the Langshan Group is closely related to syn-sedimentary volcanism based on the following facts: most of the lead isotopes in sphalerite, galena, pyrite, pyrrhotite and chalcopyrite plot on both sides of the line for the mantle or between the lines for the mantle and lower crust in the lead isotope composition diagram; cobalt content of some pyrites samples is much higher than the nickel content (Co/Ni= 11.91-12.19). Some volcanic blocks and debris have been picked out from some pyritic and pyrrhotitic ores. All Zn-Pb-Cu-Fe sulfide orebodies in these deposits occur in the strata overlying metamorphic volcanic rocks in the only ore-bearing second formation. In the Jiashengpan deposit that lacks syn-sedimentary volcanic rocks in the host succession only Pb and Zn ores occur without Cu ore, but in the Dongshengmiao, Tanyaokou and Huogeqi deposits with syn-sedimentary volcanic rocks in the host succession Cu ores occur. This indicates a relatively higher ore-forming temperature. The process of synsedimentary volcanic eruption directly supplied some ore-forming elements, and resulted in secular geothermal anomaly favorable for the circulation of a submarine convective hydrothermal system, which accounts for the precipitation of deep mineralizing fluids exhaling into anoxidic basins along the syn-sedimentary fault system in the Langshan-Zha‘ertai rift. The Dongshengmiao, Tanyaokou, and Huogeqi deposits hosted in the Langshan Group appear to be a transitional type of mineral deposit between SEDEX and VMS-types but with a bias towards SEDEX, while the Jiashengpan deposit hosted in the Zha‘ertai Group is of a characteristic SEDEX type. This evidence, together with other new discoveries of Mesoproterozoic volcanic rocks and the features of lithogeny and metallogeny of the Bayun Obo deposit in the neighborhood emphasize the diversity, complexity and uniqueness of the Mesoproterozoic Langshan-Zha‘ertal-Bayun Obo ore belt.     

Accurate U-Pb Age and Trace Element Determinations of Zircon by Laser Ablation-Inductively Coupled Plasma-Mass Spectrometry

Various zircons of Proterozoic to Oligocene ages (1060-31 Ma) were analysed by laser ablation-inductively coupled plasma-mass spectrometry. Calibration was performed using Harvard reference zircon 91500 or Australian National University reference zircon TEMORA 1 as external calibrant. The results agree with those obtained by SIMS within 2s error. Twenty-four trace and rare earth elements (P, Ti, Cr, Y, Nb, fourteen REE, Hf, Ta, Pb, Th and U) were analysed on four fragments of zircon 91500. NIST SRM 610 was used as the reference material and ²⁹Si was used as internal calibrant. Based on determinations of four fragments, this zircon shows significant intra-and inter-fragment variations in the range from 10% to 85% on a scale of 120 μm, with the variation of REE concentrations up to 38.7%, although the chondrite-normalised REE distributions are very similar. In contrast, the determined age values for zircon 91500 agree with TIMS data and are homogeneous within 8.7 Ma (2 s ). A two-stage ablation strategy was developed for optimising U-Pb age determinations with satisfactory trace element and REE results. The first cycle of ablation was used to collect data for age determination only, which was followed by continuous ablation on the same spot to determine REE and trace element concentrations. Based on this procedure, it was possible to measure zircon ages as low as 30.37 0.39 Ma (MSWD = 1.4; 2 s ). Other examples for older zircons are also given.