煤储层渗透率动态变化效应研究

基于现代测试技术和煤层气井实测排采数据,采用物理模拟和数值模拟研究方法,探讨了开采过程中煤储层渗透率动态变化效应。研究结果表明,试验模拟和数值模拟渗透率数值相差较大,可达1～2个数量级;煤储层渗透率动态变化效应呈现出两种相反的规律,即数值模拟渗透率随流体压力降低而衰减,试验模拟渗透率随流体压力降低而增大,两种模拟渗透率动态变化特征看似相互矛盾,实则相互衔接,预示煤储层渗透率在排采过程中会逐渐得以改善。根据分析,揭示了二者差异性的根本原因。提出在整个排采过程中,应采用动态渗透率指标,不断调整和优化工作制度     

Inter‐laboratory Characterisation of Apatite Reference Materials for Chlorine Isotope Analysis

Here we report on a set of six apatite reference materials (chlorapatites MGMH#133648, TUBAF#38 and fluorapatites MGMH#128441A, TUBAF#37, 40, 50) which we have characterised for their chlorine isotope ratios; these RMs span a range of Cl mass fractions within the apatite Ca₁₀(PO₄)₆(F,Cl,OH)₂ solid solution series. Numerous apatite specimens, obtained from mineralogical collections, were initially screened for ³⁷Cl/³⁵Cl homogeneity using SIMS followed by δ³⁷Cl characterisation by gas source mass spectrometry using both dual‐inlet and continuous‐flow modes. We also report major and key trace element compositions as determined by EPMA. The repeatability of our SIMS results was better than ± 0.10‰ (1s) for the five samples with > 0.5 % m/m Cl and ± 0.19‰ (1s) for the low Cl abundance material (0.27% m/m). We also observed a small, but significant crystal orientation effect of 0.38‰ between the mean ³⁷Cl/³⁵Cl ratios measured on three oriented apatite fragments. Furthermore, the results of GS‐IRMS analyses show small but systematic offset of δ³⁷Cl_SMOC values between the three laboratories. Nonetheless, all studied samples have comparable chlorine isotope compositions, with mean 10³δ³⁷Cl_SMOC values between +0.09 and +0.42 and in all cases with 1s ≤ ± 0.25.     

塔北油区岩石声发射全过程曲线类型及特征

本文讨论了岩石试样在加载全过程中的声发射特征、不同岩石声发射全过程曲线的分类以及类型的确定方法;对新疆塔里木盆地北部油区井下和地表试样进行了统计、分类,确定出该油区泥岩、砂岩声发射全过程曲线存在Ⅰ、Ⅲ两种类型;白云岩、灰岩、玄武岩声发射全过程曲线具有Ⅰ型特征。      

岩溶发育对温室气体CO2的调节能力研究

温室效应是当今世界上许多国家及其政府关注的重要问题之一。从地质角度研究全球最大碳库－－碳酸盐岩在其岩溶发育过程中对温室气体ＣＯ２的调节能力,从而为更全面,定量地考察温室气体ＣＯ２循环提供新思路及依据。     

红柱石微粉对高铝矾土熟料制品的补强作用

高铝矾土熟料制品是除粘土制品之外使用范围最广、用量最大的耐火材料,在各种工业窑炉中都有广泛应用。生产铝矾土熟料制品一般采用不同粒级的铝矾土熟料与塑性粘土为原料,用倒焰窑烧成时,烧成温度为１４３０～１４５０℃,保温４０ｈ;用隧道窑烧成时,烧成温度为１５５０～１５６０℃。其工艺关键是控制二次莫来石化产生的体积效应。当制品的Ａｌ２Ｏ３含量在７０％以下时,铝矾土熟料制品的高温性能取决于莫来石晶相与液相间的数量比例。Ａｌ２Ｏ３含量越高,制品中莫来石含量越高,玻璃相相应减少,制品的高温性能越好。在生产中提高…     

武当山地块基性岩墙群地球化学研究及其大地构造意义

武当山地块基性岩墙群的地球化学特征表明,它们为具大陆拉斑玄武央珠大陆板内岸 浆侵入的产物,是古陆块裂并保存在造山带内基底岩块的重要证据,这表明南秦岭和扬子板块曾存在晋宁期固结的统一古陆块,该古陆块在新元古代早期发生了一次重要的裂解作用。     

Lawsonite- and glaucophane-bearing blueschists from NW Qiangtang,northern Tibet,China: mineralogy,geochemistry, geochronology,and tectonic implications

The occurrence of high-pressure (HP) blueschists within the central Qiangtang terrane of northern Tibet has a significant bearing on plate-suturing processes. In order to contribute to the ongoing debate on whether the central Qiangtang metamorphic belt represents an in situ suture within the Qiangtang terrane, we examined lawsonite- and glaucophane-bearing blueschists from the northwest Qiangtang area (84° 10′–85° 30′ E, 34°10′–34° 45′ N). All studied rocks are metapelites, metasandstones, or metabasalts, characterized by lawsonite + glaucophane + phengite, lawsonite + glaucophane + epidote + albite + quartz, or glaucophane + phengite + quartz assemblages. The meta-mafic rocks contain very high TiO₂ and low Al₂O₃ contents. They are typified by abundant ferromagnesian trace elements, and an absence of Eu anomalies and Nb–Ta deletions; all the above features indicate that these mafic rocks represent oceanic island basalt (OIB) protoliths. Most of the metasediments contain high SiO₂, moderate Al₂O₃ + K₂O, and low TiO₂ + Na₂O. They display high CIA (chemical index of alteration) values (74% ± 5%) and distinctly negative Eu anomalies (Eu/Eu* = 0.64 ± 0.05). This, along with their high field strength elemental characteristics, indicates that they were deposited in a passive continental margin environment, intercalated with OIB-type basalts. We estimate the peak metamorphic conditions for these blueschists as T = 330–415°C and P = 9–11.5 kbar. This HP event occurred at ca. 242 Ma, indicated by a well-defined ⁴⁰Ar/³⁹Ar plateau age for glaucophane. Retrograde metamorphism occurred at T = 280–370°C, P = 6.5–9.5 kbar, t = ca. 207 Ma (⁴⁰Ar/³⁹Ar dating of phengite). Therefore, a cold subduction (geotherm ～8°C/km) attended the passive continental margin during the Triassic when the eastern Qiangtang collided with the western Qiangtang. The northwest Qiangtang HP metamorphic belt is an extension of the central Qiangtang metamorphic belt that defines the suture between eastern and western Qiangtang, and indicates an anticlockwise, diachronous closure of the Shuanghu Palaeo-Tethys.     

郑州市地下水源热泵应用适宜性与环境影响分析

本文在分析郑州市现有地温空调系统应用的基础上,从水文地质条件、浅层地温场特征、经济效益等方面分析了郑州市地下水源热泵应用的适宜性,研究了热泵运行对地下水环境的影响,认为地下水源热泵应用效果较好,经济社会效益明显,适宜推广应用,为城市地下水源热泵发展应用提供了依据。     

矿山固体废弃物对地质环境的影响分析

在山西省重点地区固体废弃物现状调查研究的基础上,通过试样试验,分析研究了固体废弃物对土壤、大气、水环境的污染,探讨了对固体废弃物的治理及利用,为研究矿山生态环境地质研究提供参考,同时积累工作经验。