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61.
Potential hyperaccumulation of Pb, Zn, Cu and Cd in endurant plants distributed in an old smeltery, northeast China 总被引:1,自引:0,他引:1
The absorption and accumulation of Pb, Zn, Cu and Cd in some endurant weed plant species that survived in an old smeltery
in Liaoning, China, were systematically investigated. Potential hyperaccumulative characteristics of these species were also
discussed. The results showed that metal accumulation in plants differed with species, tissues and metals. Endurant weed plants
growing in this contaminated site exhibited high metal adaptability. Both the metal exclusion and detoxification tolerance
strategies were involved in the species studied. Seven species for Pb and four species for Cd were satisfied for the concentration
time level standard for hyperaccumulator. Considering translocation factor (TF) values, one species for Pb, seven species
for Zn, two species for Cu and five species for Cd possessed the characteristic of hyperaccumulator. Particularly, Abutilon theophrasti Medic, exhibited strong accumulative ability to four heavy metals. Although enrichment coefficients of all samples were lesser
than 1 and the absolute concentrations didn’t reach the standard, species mentioned above were primarily believed to be potential
hyperaccumulators. 相似文献
62.
Enis Morkoc Legovic Tarzan Oya Okay Huseyin Tufekci Vildan Tufekci Leyla Tolun Fatma Karakoc 《Environmental Geology》2007,53(1):103-112
The Izmit Bay is an elongated semi-enclosed bay in the Marmara Sea. It is being increasingly polluted by both domestic and
industrial waste discharge since 1970’s. A monitoring program was conducted between 1999-2000 to document the state of pollution
in the bay. This includes the effect of Marmara (Izmit) earthquake (magnitude 7.4) that occurred in August 1999. A stable
two-layer ecosystem exists in the bay throughout the year due to continuous inflows of the saltier Mediterranean and brackish
Black Sea waters to the Marmara basin. Therefore, the principal biochemical characteristics of the bay are governed by the
two-layer flow system over the basin. Dissolved oxygen (DO) is generally at a saturated levels in the surface layer which
is 10 to 15 m thick, but it is depleted to 60–70 μM in the lower layer, exhibiting a steep gradient in the sharp halocline.
When the earthquake occurred, great loads of industrial wastes were released into the bay surface waters, which enhanced primary
production in the upper layer and thus large export of particulate organic matter to lower layer and eventually to the bottom.
Accordingly, DO was consumed and anoxic condition was established even in the upper layer/halocline interface, the halocline
and bottom waters of the eastern and central bay. In this period, concurrent increases were observed in phosphate and ammonia
contents at the halocline and in deep waters whilst the nitrate was almost consumed via denitrification processes in the anoxic
water. Recently, the industrial C, N and P loads increased by as much as 8 fold within five years (1995–2000) whilst domestic
inputs increased by 50%. Total organic matter discharged to the bay increased more than double within the last 15 years. Besides,
most factories in the region release toxic wastes into the bay after only partial treatment. 相似文献
63.
64.
Generation of Deccan Trap magmas 总被引:1,自引:0,他引:1
Gautam Sen 《Journal of Earth System Science》2001,110(4):409-431
Deccan Trap magmas may have erupted through multiple centers, the most prominent of which may have been a shield volcano-like
structure in the Western Ghats area. The lavas are predominantly tholeiitic; alkalic mafic lavas and carbonatites are rare.
Radioisotope dating, magnetic chronology, and age constraints from paleontology indicate that although the eruption started
some 68 Ma, the bulk of lavas erupted at around 65–66 Ma. Paleomagnetic constraints indicate an uncertainty of ± 500,000 years
for peak volcanic activity at 65 m.y. in the type section of the Western Ghats. Maximum magma residence times were calculated
in this study based on growth rates of “giant plagioclase” crystals in lavas that marked the end phase of volcanic activity
of different magma chambers. These calculations suggest that the > 1.7 km thick Western Ghats section might have erupted within
a much shorter time interval of ∼ 55,000 years, implying phenomenal eruption rates that are orders of magnitude larger than
any present-day eruption rate from any tectonic environment. Other significant observations/conclusions are as follows: (1)
Deccan lavas can be grouped into stratigraphic subdivisions based on their geochemistry; (2) While some formations are relatively
uncontaminated others are strongly contaminated by the continental crust; (3) Deccan magmas were produced by 15–30% melting
of a Fe-rich lherzolitic source at ∼ 3–2 GPa; (4) Parent magmas of the relatively uncontaminated Ambenali formation had a
primitive composition with 16%MgO, 47%SiO2; (5) Deccan magmas were generated much deeper and by significantly more melting than other continental flood basalt provinces;
(6) The erupted Deccan tholeiitic lavas underwent fractionation and magma mixing at ∼ 0.2 GPa. The composition and origin
of the crust and crust/mantle boundary beneath the Deccan are discussed with respect to the influence of Deccan magmatic episode. 相似文献
65.
Pollution vulnerability of the Quaternary aquifer near Cairo, Egypt, as indicated by isotopes and hydrochemistry 总被引:2,自引:1,他引:2
The present study was conducted to delineate the pollution vulnerability of the Quaternary aquifer in two areas, Imbaba and
Shobra El-Khima, near Cairo, Egypt. Environmental isotopes combined with hydrochemistry were used for this purpose. The groundwater
in the Imbaba area (average total dissolved solids about 900 mg/L; sodium/chloride, sulfate, and bicarbonate water types)
is more mineralized than groundwater in the Shobra El-Khima area (average total dissolved solids 500 mg/L; calcium and sodium/bicarbonate
water type). A high nitrate content and significant mineralization in the groundwater are probably due to contamination of
recharge to the aquifer by irrigation drainage, deteriorated sewage networks, and septic tanks. The deuterium and oxygen-18
compositions of the groundwater are depleted compared to Nile River water, which is the main source of aquifer recharge. This
less isotopically enriched water probably represents older Nile water recharge that flooded the region before construction
of the Aswan High Dam in 1963, or it is a mixture of a young water and originally deposited paleowater that was in deeper
horizons at a time of cooler and more humid climate. Intensive pumping has moved the paleowater higher in the aquifer. Groundwater
in the Shobra El-Khima area has higher residence time, based on the tritium concentration, than groundwater in the Imbaba
area. The percentage of the isotopically depleted water equals 75% in the Shobra El-Khima and 35% in Imbaba, and the thickness
of the clay cap above the aquifer is 38 m in Shobra El-Khima and 20 m in Imbaba. These factors are indicative of the rate
of recharge to the aquifer and were used to evaluate the pollution vulnerability in the two areas.
Electronic Publication 相似文献
66.
Groundwater samples collected from both open and bore wells in an area of about 270 km2 from Madras City, India, have been analyzed for major ions (HCO3, Cl, Si, Na, Ca, and Mg) and trace elements (As, Se, B, V, Cr, Fe, Co, Pb, Cu, Zn, Cd, Mn, Ni, Mo, and Ba). The study reveals that the quality of potable water has deteriorated to a large extent. Seawater intrusion into the aquifer has been observed in nearly 50 percent of the study area. The toxic elements (As and Se) have already exceeded the maximum permissible limits of drinking water in almost the entire city. A positive correlation of As and Se with other toxic metals such as V, Cr, Fe, B, etc., indicates that all these elements are anthropogenic in origin. Applying multivariate analysis, the source for trace elements in groundwater has been grouped into two major factors: pollution and mobilization factors. The groundwater in the study area is largely contaminated by organic effluents and reflects the intensity of pollution caused by the overlying soil sediment and rapid infiltration of the pollutants. 相似文献
67.
R. Mackay J.A. Morakinyo 《Stochastic Environmental Research and Risk Assessment (SERRA)》2006,20(3):213-222
An industrial site is usually contaminated by accidental (and occasionally intentional) releases of pollutants to the environment
from various operations carried out on that site. Consequently, the pattern of contamination created during the life of the
site depends in part, at least, on the pattern of operations. Thus, the assessment of the pattern of contamination over the
site should be improved: if it is possible to identify the pattern of operations on the site, the duration of the different
activities and the perceived likelihood of releases from the different operations. A stochastic model has been developed that
can be used to simulate alternative realizations of contaminant releases (duration, extent and timing). The model employs
release zones associated with particular activities or groups of activities on the site and the areas of each of the zones
may be independent or overlapping. The period of activity in each zone is obtained from the site records, while the likelihood
and extent of contamination in each zone is inferred from an analysis of the contamination data obtained by point sampling.
The form of the model, the method of inference of the model parameter values from the site data and the application of the
model to the study site are presented. The release model has been developed as part of a suite of stochastic models for site
ground contamination analysis. The stochastic soil and transport models and the application of the integrated modelling system
are described in separate papers. 相似文献
68.
I. González M. M. Jordán T. Sanfeliu M. Quiroz C. de la Fuente 《Environmental Geology》2007,52(7):1243-1251
In southern Chile, with a mild and rainy climate, high levels of heavy metals have been detected in many gold placer deposits.
Many of the contaminants pose risks to human life, and consequently damage the trofic chain in this environment. The study
zones selected correspond to the handicraft gold-bearing sands of Rio Gato (Los Muermos), Carelmapu and Cucao. These are all
located in the X Region of “Los Lagos” in Chile. The type of methodology used in the characterization of the associated mineralization
consists of testing each representative sample with a grain size distribution, statistical parameter analysis and a mineralogical
analysis, using a binocular magnifying glass, a petrographic microscope, XRD and SEM/EDX. The chemical composition was defined
by means of X ray fluorescence and micro-chemical analysis. The results of the study about sediments in southern Chile are
presented. The major concentrations of heavy minerals are generally located in areas of dynamic river energy. In the samples,
more than 70% of the heavy minerals were distributed among grain sizes corresponding to thin sand with good grain selection
(meshes of 0.25–0.06 mm). The main mineral phases present in the analysed samples were gold, zircon, olivine, ilmenite, hornblende,
hypersthene, hematite, garnet, chromite, chlorite, augite, amphibolitic-epidote, etc. The main heavy metals found as a result
of the study were mercury, lead, cadmium, chrome, tellurium, indium, zinc, cobalt, copper, platinum, gold, etc., and as well
some less common elements like cerium, praseodymium, gadolinium, neodymium, samarium and lanthanum. This research work is
only a starting point for carrying out a risk probability mapping of heavy metals and the mineralogy of the Cucao, Carelmapu
and Rio Gato gold-bearing sands. 相似文献
69.
Magmatic History of Somma-Vesuvius on the Basis of New Geochemical and Isotopic Data from a Deep Borehole (Camaldoli della Torre) 总被引:3,自引:0,他引:3
Di Renzo V.; Di Vito M. A.; Arienzo I.; Carandente A.; Civetta L.; D'antonio M.; Giordano F.; Orsi G.; Tonarini S. 《Journal of Petrology》2007,48(4):753-784
A continuous-coring borehole recently drilled at Camaldoli dellaTorre on the southern slopes of SommaVesuvius providesconstraints on the volcanic and magmatic history of the Vesuvianvolcanic area since c. 126 ka BP. The cored sequence includesvolcanic units, defined on stratigraphical, sedimentological,petrological and geochemical grounds, emitted from both localand distal vents. Some of these units are of known age, suchas one Phlegraean pre-Campanian Ignimbrite, Campanian Ignimbrite(39 ka), Neapolitan Yellow Tuff (14· 9 ka) and VesuvianPlinian deposits, which helps to constrain the relative ageof the other units. The main rock types encountered are shoshonite,phonotephrite, latite, trachyte and phonolite. The sequenceincludes, from the base upwards: a thick succession of pyroclasticunits emplaced between 126 and 39 ka, most of them attributedto eruptions that occurred in the Phlegraean area; the CampanianIgnimbrite; the products of a local tuff cone formed between39 ka and the deposition of the products of the earliest activityof the Mt. Somma volcano; the products of the SommaVesuviusvolcano, which include from the base upwards a thick sequenceof lavas, pyroclastic rocks and the products of a local spattercone dated between 3· 7 ka and AD 79. The data obtainedfrom the study of the borehole show that, before the CampanianIgnimbrite eruption, low-energy explosive volcanism took placein the Vesuvian area, whereas mostly high-energy explosive eruptionscharacterized the Campi Flegrei activity. In the Vesuvian area,Campanian Ignimbrite deposition was followed by the eruptionof a local tuff cone and a long repose time, which predatedthe formation of the Mt. Somma edifice. Since 18· 3 ka(Pomici di Base eruption) the activity of SommaVesuviusbecame mostly explosive with rare lava effusions. The shallowestcored deposits belong to the Camaldoli della Torre cone, formedbetween the Pomici di Avellino and Pomici di Pompei eruptions(3· 7 kaAD 79). New geochemical and SrNdPbB-isotopicdata on samples from the drilled core, together with those availablefrom the literature, allow us to further distinguish the volcanicrocks as a function of both their provenance (i.e. Phlegraeanor Vesuvian areas) and age, and to identify different magmaticprocesses acting through time in the Vesuvian mantle source(s)and during magma ascent towards the surface. Isotopically distinctmagmas, rising from a mantle source variably contaminated byslab-derived components, stagnated at mid-crustal depths (810km below sea level) where magmas differentiated and were probablycontaminated. Contamination occurred either with Hercynian continentalcrust, mostly during the oldest stages of Vesuvian activity(from 39 to 16 ka), or with Mesozoic limestone, mostly duringrecent Vesuvian activity. Energy constrained assimilation andfractional crystallization (EC-AFC) modelling results show thatcontamination with Hercynian crust probably occurred duringdifferentiation from shoshonite to latite. Contamination withlimestone, which is not well constrained with the availabledata, might have occurred only during the transition from shoshoniteto tephrite. From the deep reservoir, magmas rosetowards a series of shallow reservoirs, in which they differentiatedfurther, mixed, and fed volcanic activity. KEY WORDS: SommaVesuvius; crustal contamination; source heterogeneity; radiogenic and stable isotopes; magmatic system 相似文献
70.
Early-indicator signals of groundwater contamination: the case of seawater encroachment 总被引:4,自引:0,他引:4
An early indication of groundwater contamination occurs when pollutant concentrations start to fluctuate and exceed background
values of ambient fresh groundwater. An analysis of a characteristic situation of this type uses data from Israel's coastal
phreatic granular aquifer. The pollutant is generally seawater, and the contamination process involves replacement of freshwater
by encroaching sea- or other saltwater, a process augmented by human activity. The contamination process involves three stages:
(1) groundwater composition remains relatively stable with small salinity content; (2) small salinity changes are perceptible
with reversible fluctuations; and (3) salinity concentration increases at a sharply higher rate. The second stage is a useful
early-indicator signal of contamination. Early-indicator signals of groundwater pollutant concentrations involve "minor" fluctuations
in water chemistry at the advent of the contamination process. The intensity and magnitude of such a salinization/pollution
process at any given location depends upon lithologic matrix, aquifer heterogeneity, and resultant flow domain characteristics,
as well as contaminant properties. If such "signs" are detected at a sufficiently early stage, appropriate management steps
may be taken to rectify further seawater and/or saltwater encroachment.
Received: 23 July 1996 · Accepted: 25 June 1997 相似文献