Stability at high-pressure,elastic behaviour and pressure-induced structural evolution of CsAlSi<Subscript>5</Subscript>O<Subscript>12</Subscript>, a potential host for nuclear waste

The elastic and structural behaviour of the synthetic zeolite CsAlSi₅O₁₂ (a = 16.753(4), b = 13.797(3) and c = 5.0235(17) Å, space group Ama2, Z = 2) were investigated up to 8.5 GPa by in situ single-crystal X-ray diffraction with a diamond anvil cell under hydrostatic conditions. No phase-transition occurs within the P-range investigated. Fitting the volume data with a third-order Birch–Murnaghan equation-of-state gives: V ₀ = 1,155(4) ų, K _T0 = 20(1) GPa and K′ = 6.5(7). The “axial moduli” were calculated with a third-order “linearized” BM-EoS, substituting the cube of the individual lattice parameter (a ³, b ³, c ³) for the volume. The refined axial-EoS parameters are: a ₀ = 16.701(44) Å, K _T0a = 14(2) GPa (β_a = 0.024(3) GPa^?1), K′ _a = 6.2(8) for the a-axis; b ₀ = 13.778(20) Å, K _T0b = 21(3) GPa (β_b = 0.016(2) GPa^?1), K′ _b = 10(2) for the b-axis; c ₀ = 5.018(7) Å, K _T0c = 33(3) GPa (β_c = 0.010(1) GPa^?1), K′ _c = 3.2(8) for the c-axis (K _T0a:K _T0b:K _T0c = 1:1.50:2.36). The HP-crystal structure evolution was studied on the basis of several structural refinements at different pressures: 0.0001 GPa (with crystal in DAC without any pressure medium), 1.58(3), 1.75(4), 1.94(6), 3.25(4), 4.69(5), 7.36(6), 8.45(5) and 0.0001 GPa (after decompression). The main deformation mechanisms at high-pressure are basically driven by tetrahedral tilting, the tetrahedra behaving as rigid-units. A change in the compressional mechanisms was observed at P ≤ 2 GPa. The P-induced structural rearrangement up to 8.5 GPa is completely reversible. The high thermo-elastic stability of CsAlSi₅O_12, the immobility of Cs at HT/HP-conditions, the preservation of crystallinity at least up to 8.5 GPa and 1,000°C in elastic regime and the extremely low leaching rate of Cs from CsAlSi₅O₁₂ allow to consider this open-framework silicate as functional material potentially usable for fixation and deposition of Cs radioisotopes.     

手掘式顶管在市政排水工程中的应用

从混凝土管材的选定、工作坑的设计及施工、顶管顶进中若干关键问题入手,介绍了手掘式顶管施工技术在成都市中心城水环境综合整治工程G标段管道排水工程中的应用。     

旋挖钻机与转盘钻机组合施工法的应用

对旋挖钻机、转盘钻机各自特点和施工成本进行对比分析,提出组合施工方法设想,并通过工程实例得到成功实践,为以后类似工程提供借鉴。客观地提出了旋挖钻机的使用条件和面临的问题。     

土壤聚合物对几种重金属离子固化效果的研究

土壤聚合物是一种新型的无机聚合物,其分子链由Si、O、Al等以共价键或离子键连接而成,形成网络结构,对重金属有较强的固定作用.本文试图利用土壤聚合物固化铜、锌、铅三种重金属离子,实现资源化利用.实验以固化体抗压强度和浸出毒性作为性能表征量,结果表明:土壤聚合物对不同重金属的固化有各自的极限浓度,Cu2 、Zn2 、Pb2 的理想固化量分别为0.9%、1%、2%;若固化过程中添加一定量的高炉矿渣,则可以提高固化体的抗压强度.本文通过土壤聚合物固化体SEM分析,从固化体微观结构的形态来阐述土壤聚合物宏观上的优越表现.     

矿物数字博物馆的建设构想与实现

在基于互联网的应用、信息数字化、多种技术发展较为成熟及适应公众需求的基础上,对矿物数字博物馆的建设做了简要的分析,将矿物按矿物一结晶学分类方案将馆藏矿物进行合理的分类,设计了七大功能结构和相应的子结构,并对矿物所要展示的内容设定了标准.建设矿物数字博物馆旨在利用三维技术、多媒体技术、文字信息等,将矿物从宏观的外形到抽象的晶体形态和微观的晶体结构及其最小单位结构通过网络的形式具体展现给观众.矿物数字博物馆的建设可以为人们认知整个矿物世界搭建一个良好的平台,在科研教学、推动国民科学普及教育、培养创新人才方面发挥重要作用.     

沿海地区城市发展及地面沉降的系统控制

本文运用系统工程原理,系统论述了地下水合理开发、管理和地面沉降系统控制,这对沿海地区地面沉降控制起到重要的作用。     

红色无硫细菌处理高浓度鱼品废水的研究

本文从城市生活污水的沉降污泥中分离出三株红色无硫细菌,经鉴定R1为胶质红假单胞菌(Rhodopscudomonas gelatinosa),R2为沼泽红假单胞菌(R palustris)、RS-1为红螺属(Rhodosprillum)的一种。R1与R2均为兼性需氧和兼性光能利用菌,RS-1为专性厌氧光合菌。作者提出了它们的主要生理、生化特性和最适生长条件,最后确定R1、R2是较有利用前途的优势种类。作者利用上述分离的菌株对高浓度的鱼品废水进行了净化处理试验,得出R1对CODcr的去除率约为65％,R2的去除率为74％以上。二者混合使用可提高至87％。作者还发现废水中的非光合性杂生菌有助于提高光合细菌的净化力。     

地质环境特征及工程适应性与选择性分析——青岛市城市地质环境研究

根据地形地貌、地质构造、水文地质条件将青岛市划分为６个工程地质亚区，论述了各亚区地质环境特征，结合不同城市建筑工程特点，进行了工程场地适应性和选择性分析评价，为充分合理利用城市地质环境提供良好依据     

广西沿岸海平面变化的关联维数研究

采用相空间重构和关联维数方法，研究了广西沿岸月平均海平面变化的分形特征，结果表明，相空间重构的延迟时间τ为3△t，当关联维数趋于饱和时，石头埠，北海和龙尾的相空间维数为7，而涠洲岛为9，它们的关联维数平均值平均值分别为6.6507,6.5414,6.7059.     

Risk-based decision-making for drilling waste discharges using a fuzzy synthetic evaluation technique

Offshore petroleum drilling wastes contain toxic substances that are potentially harmful to the marine ecosystem. Despite environmentally benign characteristics, wastes associated with synthetic-based fluids still contain a certain amount of pollutants due to contamination with formation oil and the presence of trace heavy metals in barite, which may pose risk when discharged into the marine environment. A framework is presented here for a decision support system for the selection of the best drilling waste discharge option. Uncertainties in the quantification of risk, cost and technical feasibility are expressed by fuzzy numbers. An analytical hierarchy process with a technique called fuzzy synthetic evaluation is employed to determine the best management alternative (discharge scenario).