THE INTRINSIC ACIDITY CONSTANTS AND SPECIFIC SURFACE AREA OF MARINE SOLID PARTICLESII. THE RELATIONSHIP BETWEEN THE INTRINSIC ACIDITY CONSTANT AND THE TERNARY SURFACE COMPLEX

This paper deals with the infrared spectra of " amino acid- clay , calcium carbonate and y-AlOOH" and " Cu (II )-clay-amino acid" model systems, and shows that the model of the ternary surface complex is M-OHLCu (L = amino acid) for marine solid particle-Cu (II)-amino acid. Study of the formation mechanism of the ternary surface complex shows that the specific surface area , and especially the intrinsic acidity constant, determine whether the ternary surface complex is easily formed, and that factor, FTSC,quantifies the relationship between the promoting effect of organics on Mt-marine solid particle ion exchange and the intrinsic acidity constant and specific surface area.     

水平井含水率上升影响因素

利用塔里木油田塔中4油田(TZ4)底水油藏相关的地质、流体数据建立数值模型。在所建模型的基础上,应用数值模拟计算的累积产油、产水和产液量回归俞启泰水驱特征曲线,以反映水平井见水特征的参数b。以参数b为研究对象,采用正交试验的方法研究不同因素对b值的影响,筛选影响水平井见水特征的主要因素,认为原油粘度、油层厚度、非均质性及水平井水平段在油藏中的位置是影响水平井含水上升趋势的主要指标。最后建立主要因素与b值的关系式,结合俞启泰曲线b值图版,提出预测水平井见水规律的公式——图版法(F-b法)。应用F-b法对塔里木水平井含水率进行预测,并与其他相关方法及实际生产数据对比,认为F-b法可作为预测塔里木油田水平井含水率、估算可采储量的一种有效方法。     

土钉抗拔承载力的原位试验研究

根据土钉现场抗拔试验数据,分析了钉材、浆液龄期等因素对土钉抗拔承载力的影响,建议了合理的下层土钉开挖时间。最后通过试验土钉抗拔力反算土体与锚固体的极限粘结强度,并与规范推荐值进行了比较。     

Changes in hydrogeological properties of the River Choushui alluvial fan aquifer due to the 1999 Chi-Chi earthquake, Taiwan

Changes in hydrogeological properties of the River Choushui alluvial fan aquifer before and after the 1999 Chi-Chi earthquake, Taiwan, have been identified using pumping tests. Three wells, SH2, YL2 and SC2, located in a compressional zone with high coseismic groundwater levels, were tested. The threshold of the aquifer deformation with respect to transmissivity (T) is greater than that with respect to storage coefficient (S). Decreases in the post-earthquake S are approximately 60% at SH2 and SC2, indicating aquifer compression after the Chi-Chi earthquake. Changes in the post-earthquake T range from 61% increase to 0.8% decrease. Moreover, results from anisotropy analysis of T at SC2 further illustrate that normal stresses induced by the Chi-Chi earthquake have consolidated soil particles. Soil particles dilated laterally after the earthquake, resulting in an increase of the equivalent T. The changes in hydrogeological properties have a considerable influence on spatiotemporal fluid pressure and horizontal groundwater movement, resulting in different amounts of drawdown during post-earthquake pumping.     

菲降解菌的降解特性及酶促反应动力学研究

通过对取自MBR膜生物反应器中的活性污泥加入菲进行富集培养、驯化,分离、纯化出一株能以菲为唯一碳源和能源的短杆状革兰氏阴性菌J-1,细菌长2～5μm,宽1～3μm;研究了初始底物浓度、温度、pH对菌株J-1降解菲的影响,探讨了菌株J-1胞内酶对菲降解的底物抑制动力学。试验表明:菌株J-1在48h内能将不同浓度菲的水溶液中的菲完全降解;菲浓度增加,达到完全降解的时间延长。温度对细菌的降解能力影响较大,菌株J-1对菲降解的最佳温度为28℃。1.15mg·L-1的菲,28℃时48h内能完全降解,而相同时间内10℃时的降解率仅为36.65%。菌株J-1对pH的波动具有一定的适应性,pH在一定范围内(6.0～8.4)变化对菲降解的影响不大,降解反应的最佳pH为7.2。菌株J-1对菲的降解符合一级动力学反应方程。较高的底物浓度对酶促降解反应具有抑制作用,酶促反应的最大速率常数vm=1.17mg·L-1·h-1,米氏常数Km=61.70mg·L-1;底物抑制常数kS=49.60mg·L-1;最佳底物浓度[S]opt=55.32mg·L-1。     

Using Sequential Self-Calibration Method to Identify Conductivity Distribution: Conditioning on Tracer Test data

An iterative inverse method, the sequential self-calibration method, is developed for mapping spatial distribution of a hydraulic conductivity field by conditioning on nonreactive tracer breakthrough curves. A streamline-based, semi-analytical simulator is adopted to simulate solute transport in a heterogeneous aquifer. The simulation is used as the forward modeling step. In this study, the hydraulic conductivity is assumed to be a deterministic or random variable. Within the framework of the streamline-based simulator, the efficient semi-analytical method is used to calculate sensitivity coefficients of the solute concentration with respect to the hydraulic conductivity variation. The calculated sensitivities account for spatial correlations between the solute concentration and parameters. The performance of the inverse method is assessed by two synthetic tracer tests conducted in an aquifer with a distinct spatial pattern of heterogeneity. The study results indicate that the developed iterative inverse method is able to identify and reproduce the large-scale heterogeneity pattern of the aquifer given appropriate observation wells in these synthetic cases.     

地震学定量预报指标的一种提取方法——对比筛选法

鉴于目前地震学综合定量预报指标的缺乏和预报工作的急需,尝试使用“对比筛选法(简称CSM方法)”进行地震学定量预报指标的提取试验。较之以往作法的进展在于:1.同时使用“有震”和“无震”两类样本对比筛选;2.对不同地区的地震学参数进行了归一化处理。这样做的显著优点是:1.可以较有效地提取“有震异常”和“正常变化”指标;2.提取的异常和预报指标具有定量化和普适性特点。 试验研究使用大华北地震区资料,研究对象取中强地震。经内符和外推检验,证明该方法提取的异常和预报指标有效性和实用性较高。     

Integrability of the Yang-Mills Hamiltonian system

This paper considers the integrability of generalized Yang-Mills system with the HamiltonianH _a (p, q)=1/2(p ₁ ² +p ₂ ² +a ₁ q ₁ ² +a ₂ q ₂ ² )+1/4q ₁ ⁴ +1/4a ₃ q ₂ ⁴ + 1/2a ₄ q ₁ ² q ₂ ² . We prove that the system is integrable for the cases: (A)a ₁=a ₂,a ₃=a ₄=1; (b)a ₁=a ₂,a ₃=1,a ₄=3; (C)a ₁=a ₂/4,a ₃=16,a ₄=6. Our main result is the presentation of these integrals. Only for cases A and B does the Yang-Mills Hamiltonian possess the Painlevé property. Therefore the Painlevé test does not take account of the integrability for the case C.     

Paleomagnetism of the Esterel rocks: a revisit 22 years after the thesis of Hans Zijderveld

For his PhD. thesis, Zijderveld (1975) studied the paleomagnetism of the Permian Esterel rocks (southern France). High-quality thermal and alternating-field demagnetization diagrams were interpreted to determine the direction of the characteristic natural magnetization. For the Esterel volcanics, a mean direction of Dec = 206.5°, Inc = –23°, ₉₅ = 5.7°, k = 112 was found for this magnetization. The dispersion in this mean is remarkably low. Only the declination of the Reyran Rhyolite in the Reyran River quarry clearly deviated from this mean. This deviating direction is not found in our samples, taken at the same site. As many faults occur in this quarry, it is suggested that Zijderveld sampled this rhyolite on a small rotated block. To verify whether the small dispersion in the mean paleomagnetic direction of the Esterel rocks has a geomagnetic or a rock-magnetic origin, two conglomerate tests were carried out. One of these might be interpreted as positive. The results of the other conglomerate test (Agay Formation) are ambiguous: four of the six measured boulders show directions close to the mean paleomagnetic direction of the Esterel rocks. Rock-magnetic measurements show that the remanence is carried by a magnetite and a hematite fraction. The low dispersion in the paleomagnetic directions, the conglomerate tests, and hematite as remanence carrier suggest that the characteristic remanence in the Esterel volcanics was not instantaneously acquired during cooling, but might be affected by remagnetization due to weathering.