Measurements of atmospheric dimethyl sulfide and carbon disulfide in the western Atlantic boundary layer

Shipboard measurements of atmospheric dimethyl sulfide were made during two transects along the east coast of the United States and at several stations in the Gulf of Maine. Limited measurements of carbon disulfide and hydrogen sulfide are also reported. The mean DMS mixing ratio was 29 pptv (=25, n=84, median 19 pptv) during the Atlantic transects, and 101 pptv (=67, n=77, median 79 pptv) in the Gulf of Maine. Distinct diurnal variations were found in the DMS data from the transects. The meteorology of the study area appears to control day-to-day differences in the magnitude of these diurnal variations, although rapid daytime oxidation is suggested in some cases. Diurnal variations were also evident in near-shore stations in the Gulf of Maine due to nocturnal boundary-layer inversion. Diurnal variation was not evident at other sites in the Gulf due to large scale changes in the atmospheric circulation pattern, which effectively masked any effects due to oxidation processes. Model simulations confirm that the DMS levels and diurnal variation found during the transects are not consistent with atmospheric oxidation processes alone. Atmospheric CS₂ and H₂S mixing ratios were less than 3 pptv during the transects, except for a single period of higher CS₂ mixing ratios (reaching 11 pptv) during advection of continental air. Calculations of the flux of oceanic sulfur to the eastern United States show that the contribution of natural sulfur to the North American sulfur budget is small compared to anthropogenic sources.     

华北地区三维地壳上地幔结构

本文用均等显示滤波频时分析方法分析了长周期瑞利面波资料,获得了路经中国大陆及邻区的238条混合路径的面波群速度频散,其周期范围为10.5-113s.用改进的分格反演方法从混合路径频散中提取出位于华北地区的12个4°×4°网格单元的纯路径频散并反演其地壳上地幔结构.所得结果表明,华北地区地壳上地幔结构横向变化显著;从东向西地壳逐渐变厚;位于华北东部的分格在地壳中20km深处普遍存在低速层,整个华北地区上地幔低速层埋藏较浅,一般为55-100km之间.各个网格上地幔低速层的速度不尽相同.     

Hydrochemical and sedimentary responses of paired High Arctic watersheds to unusual climate and permafrost disturbance,Cape Bounty,Melville Island,Canada

High Arctic river responses to changing hydroclimatic and landscape processes are poorly understood. In non‐glacierized basins, snowmelt and rainfall generate river discharge, which provides first order control over fluxes. Further factors include the seasonality of precipitation, seasonal active layer development, and permafrost disturbance. These controls were evaluated in terms of sedimentary and biogeochemical fluxes from paired catchments at Cape Bounty, Melville Island, Nunavut during 2006–2009. Results indicate that the source of runoff can be more important than the amount of runoff for sediment, solutes, and organic yields. Although the snowmelt period is typically the most important time for these yields, heavy late summer precipitation events can create disproportionately large yields. Rainfall increases yields because it hydrologically connects areas otherwise isolated. Inorganic solute yields from late summer rainfall are higher because the thick active layer maximizes hydrologic interactions with mineral soils and generates high solute concentrations. Results also indicate that while the catchments are broadly similar, subtle topographic differences result in important inter‐catchment differences in runoff and suspended and dissolved loads. The East watershed, which had less extensive permafrost disturbance, consistently had higher concentrations of dissolved solids. These higher dissolved fluxes cannot therefore be explained by thermokarst features, but rather by deeper active layer development, due to a greater proportion of south‐facing slopes. Although warm temperatures in 2007 led to extensive active layer disturbance in the West watershed, because the disturbances were largely hydrologically disconnected, the total disturbed area was small, and inter‐annual variability in discharge was high, there was no detectable response in dissolved loads to disturbances. Sediment availability increased after 2007, but yields have largely returned to pre‐disturbance levels. Results indicate that seasonality and frequency‐magnitude characteristics of projected increases in precipitation must be considered along with active layer changes to predict the fluvial sedimentary and biogeochemical response to regional climate change. Copyright © 2011 John Wiley & Sons, Ltd.     

Turbulent mixing in a rotating,stratified fluid

Abstract

An experimental study was carried out to investigate the effect of rotation on turbulent mixing in a stratified fluid when the turbulence in the mixed layer is generated by an oscillating grid. Two types of experiments were carried out: one of them is concerned with the deepening of the upper mixed layer in a stable, two-fluid system, and the other deals with the interaction between a stabilizing buoyancy flux and turbulence.

In the first type of experiments, it was found that rotation suppresses entrainment at larger Rossby numbers. As the Rossby number becomes smaller (Ro 0.1), the entrainment rate increases with rotation—the onset of this phenomenon, however, was found to coincide with the appearance of coherent vortices within the mixed layer. The radiation of energy from the mixed layer to the lower non-turbulent layer was found to occur and the magnitude of the energy flux was found to be increased with the rotational frequency. It was also observed that vortices are generated, rather abruptly, in the lower layer as the mixed layer deepens.

In the second set of experiments a quasi-steady mixed layer was found to develop of which the thickness varies with rotation in a fashion that is consistent with the result of the first experiment. Also the rotation was found to delay the formation of a pycnocline.     

A stream tracer technique employing ionic tracers and specific conductance data applied to the Maimai catchment,New Zealand

The stream tracer technique and transient storage models (TSMs) have become common tools in stream solute and hyporheic exchange studies. The expense and logistics associated with water sample collection and analysis often results in limited temporal resolution of stream tracer breakthrough curves (BTCs). Samples are often collected without a priori or real‐time knowledge of BTC information, which can result in poor sample coverage of the critical shoulder (initial rise) and tail (post‐steady state fall) of the BTC. We illustrate the use of specific conductance (SC) measurements as a surrogate for conservative dissolved tracer (Br⁻) samples. The advantages of collecting SC data for use in the TSM are (1) cost, (2) ease of data collection, and (3) well‐defined breakthrough curves, which strengthen TSM parameter optimization. This method is based on developing an ion concentration (IC)–SC relationship from limited discrete tracer solute samples. SC data can be collected on a more frequent basis at no additional analysis cost. TSM simulations can then be run for the conservative tracer data derived from SC breakthrough curves and the IC–SC relationship. This technique was tested in a 120 m reach of stream (2–60 m subreaches) in the Maimai M15 catchment, New Zealand during baseflow recession. Dissolved LiBr was injected for 12·92 h, with Br⁻ as the conservative ion of interest. Four TSM simulations using the OTIS model are optimized using UCODE to fit (1) Br⁻ data derived from the Br⁻–SC relationship (n = 1307 observations at each of two stream sampling sites), (2) all stream Br⁻ data collected (n = 58 in upper reach, n = 60 in lower reach), (3) half of the stream Br⁻ data collected, and (4) 20 stream Br⁻ samples from each site. No two simulations resulted in the same optimal parameter values. Results suggest that the greater the frequency of observations, the greater the confidence in estimated parameter values. Br⁻–SC simulations resulted in the best overall model fits to the data, with the lowest calculated error variance of 6·37, narrowest 95% parameter estimate confidence intervals, and the highest correlation coefficient of 0·99 942, among the four simulations. This is largely due to the improved representation of the shoulder and tail of the BTC with this method. The IC–SC correlation method is robust in situations in which (1) changes in background SC data can be accounted for, and (2) the data used to define the IC–SC relationship are representative of the range of data collected. This method provides more efficient sample analysis, improved data resolution, and improved model results compared to the alternative stream tracer data gathering methods presented. Additionally, we describe a new parameterization of the cross‐sectional area of the stream during flow recession, as a function of discharge, based on a stream hydraulic geometry relationship. This variant of the OTIS model provides a more realistic representation of stream dynamics during unsteady discharge. Copyright © 2005 John Wiley & Sons, Ltd.     

渤南凹陷渤深6块潜山储层描述技术

渤深6块潜山储层位于沾化拗陷渤南凹陷北部,埋藏深度4100~4900 m,储层发育及成藏规律复杂。为了高效开发渤深6块,必须引进和优化潜山油藏描述技术,然后根据自身特点选择优化并创新使用。采用地震资料目标处理、叠前深度偏移、高精度三维地震采集处理解释等基础资料处理技术;用多井地震合成记录综合标定、变速成图等技术准确描述潜山形态。多井采用了斯伦贝谢成相、核磁共振测井、多尺度边缘检测平面预测等先进技术,最后根据录井、测井等多项信息进行综合判识并量化。应用结果表明,渤深6块15口新井全部钻遇设计油层,且均自喷生产,投产平均产油能力84 t/d,产气5×104m3/d,油藏开发效果好。     

基于多源数据的北疆一次持续性浓雾天气过程的演变特征

利用常规高空地面、机场跑道自动观测系统(AWOS)、微波辐射计及FY4A新一代静止气象卫星等资料对2019年12月9～13日发生于北疆沿天山一带的一次持续性浓雾天气进行观测特征及演变分析，结果表明：（1）此次大雾天气过程是发生在500 hPa高空脊区控制，低层不断有暖平流东伸，地面位于蒙古冷高压后部均压场的大尺度环流背景下。（2）大雾发生前，地面明显升温有利于地表融雪、水汽蒸发，这为浓雾的形成和维持提供有利的水汽条件。浓雾维持期间，地面风速维持1 m.s-1左右的弱风场，温度露点差≤2℃，空气接近饱和，准噶尔盆地低洼地形均为浓雾维持提供有力环境条件。浓雾消散期间，风速增大，急剧降温，快速增湿，有利于雾滴凝结为米雪，使得浓雾消散。（3）Brunt-Vaisala（布伦特-维萨拉）指数能较好的反映浓雾期间边界层稳定度，并能提炼出相关稳定度阈值。浓雾期间相对湿度≥85%高度层主要集中在100米以下的贴地层，持续深厚的湿度层为浓雾形成和持续提供较好水汽条件，大雾期间强逆温层顶主要维持在600 m高度，当逆温层顶高度抬升时，有利于雾滴粒子、水汽粒子向上扩散，能见度好转。（4）FY4A卫星的多通道可见光及红外通道差图像能较好的监视白天及夜间大雾的形成、维持及生消变化，对于业务中短时临近预报有较好的帮助。     

E24 profile slope stability analysis in Haizhou Opencast Coal Mine of Fuxin

The E24 profile slope analyzed belongs to a series of excavated slopes of the Haizhou Opencast Coal Mine. It seems to be divided into Downslope Part and Upslope Part. Its profile comprises two noticeable coal seams, called the 8# and 9# weak layers, considered as the potential failure surfaces. In consideration of the actual configuration as in the perspective of any modification, assessing the stability of this slope with various profile forms under given conditions, and assessing the risk of instability and quantifying the influence of earthworks or other modifications to the stability of this slope, have constituted the primordial objectives carried out. From assumed potential failure surfaces, any specific profiles and specified slip surfaces are defined. A factor of safety (FoS) is computed for each specified slip surface; the smallest FoS found corresponds to the least favorable slip surface. The safety factor values obtained are compared to the suggested safety factor. Limit equilibrium methods of vertical slices implemented in Slope/W, computer program for slope stability analyses, have been adopted to perform the E24 slope stability analysis. The safety factor values computed with 9# weak layer are lower than for 8#; the factors of safety obtained with Sarma's method are the smallest; more, without groundwater (long term) overall values are greater than those determined under groundwater condition (short term). The lowest safety factor value is found for a profile depending on an adopted earthwork sequence. The E24 profile slope stability analysis shows the instability risk for the deepest weak layer, and also shows the short and long term stability of this slope for the envisaged earth movements. However it demonstrates the existence of instability risk for any earthwork firstly affecting the downslope part.     

Effects of the undecomposed layer and semi-decomposed layer of Quercus variabilis litter on the soil erosion process and the eroded sediment particle size distribution

Simulated rainfall experiments were performed on bare, undecomposed litter layer and semi-decomposed litter layer slopes with litter biomasses of 0, 50, 100 and 150 g m⁻², respectively, to evaluate the effect of the undecomposed layer and semi-decomposed layer of Quercus variabilis litter on the soil erosion process and the particle size distribution of eroded sediment. The undecomposed layer and semi-decomposed layer of litter reduced the runoff rate by 10.91–27.04% and 12.91–36.05%, respectively, and the erosion rate by 13.35–40.98% and 17.16–59.46%, respectively. The percentage of smaller particles (clay and fine silt particles) decreased and the percentage of larger particles (coarse silt and sand particles) increased with an increased rainfall duration on all treated slopes, while the extent of the eroded sediment particle content varied among the treated slopes with the rainfall duration, with bare slopes exhibiting the largest variability, followed by undecomposed litter layer slopes and finally semi-decomposed litter layer slopes. The clay and sand particles were transported as aggregates, and fine silt and coarse silt particles were transported as primary particles. Compared with the original soil, sediment eroded from all treated slopes was mainly enriched in smaller particles. Furthermore, the loss of the smaller particles from the undecomposed litter layer slopes was lower than that from the semi-decomposed litter layer slopes, indicating that the undecomposed litter layer alleviated soil coarsening to some extent. The findings from this study improve our understanding of how litter regulates slope erosion and provide a reference for effectively controlling soil erosion.     

Downstream fining in contrasting reaches of the sand‐bedded Yellow River

Compared to downstream fining of a gravel‐bedded river, little field evidence exists to support the process of downstream fining in large, fine sand‐bedded rivers. In fact, the typically unimodal bed sediments of these rivers are thought to produce equal mobility of coarse and fine grains that may discourage downstream fining. To investigate this topic, we drilled 200 sediment cores in the channel beds of two fine‐grained sand‐bedded reaches of the Yellow River (a desert reach and a lower reach) and identified a fine surface layer (FSL) developed over a coarse subsurface layer (CSL) in the 3‐m‐thick bed deposits. In both reaches downstream, the thickness of the FSL increased, while that of the CSL decreased. Comparison of the depth‐averaged median grain sizes of the CSL and the FSL separately in both reaches shows a distinct downstream fining dependence to the median grain size, which indicates that at a large scale of 600‐800 km, the CSL shows a significant downstream fining, but the FSL shows no significant trends in downstream variations in grain size. This result shows that fine sediment supply (<0·08 mm median grain size) from upstream, combined with lateral fine sediment inputs from tributaries and bank erosion, can cause a rapid fining of the downstream channel bed surface and can develop the FSL layer. However, in the desert reach, lateral coarse sediment supply (>0·08 mm median grain size) from wind‐borne sediments and cross‐desert tributaries can interrupt the FSL and coarsen the channel bed surface locally. Copyright © 2011 John Wiley & Sons, Ltd.