镉和汞两种重金属离子对四角蛤蜊的急性毒性

采用毒理学实验方法,比较研究了Cd~(2+)和Hg~(2+)对四角蛤蜊(Mactra veneriformis Reeve)急性毒性效应的差异,以期为进一步评价重金属离子对四角蛤蜊的毒性效应和作用机理等提供理论依据.死亡概率单位和实验液浓度对数的线性回归分析表明,Cd~(2+)对四角蛤蜊在24、48和96 h的半致死浓度(LC_(50))分别为15.961、5.149和2.383 mg/L,Hg~(2+)的LC_(50)分别为3.714、0.607和0.207 mg/L;Cd~(2+) 和Hg~(2+) 对四角蛤蜊的安全质量浓度分别为0.023 8 mg/L和0.002 1 mg/L,分别是我国渔业水质标准(GB11607-89)限定量的4.76倍和4.02倍.     

A VERTICAL DISTRIBUTION MODEL OF NUTRIENTS AND DISSOLVED OXYGEN IN THE SOUTHERN TAIWAN STRAIT

Sinoe vertical transport of nutrients and dissolved oxygen are quite important in the water col-umn and have drawn serious attention these recent years, a one-dmension numerical model is tried to simulate the vertical distribution of nutrients and dissolved oxygen in June at two research sites in the southemTaiwan Strait. Physical transport parameters are calibrated by temperature simulation, and thenare used to simulate the profiles of NO_3, PO_4 and dissolved oxygen. The simulation was generally success-ful for both stations. The importance of various factors, such as upwelling tidal current andbiogeochemical activities, which influence the vertical distribution of nutrients and dissolved oxygen, is revealed by analysis of the modeling results. Some important rates, fluxes and ratios are also estimated anddiscussed on the basis of simulation.     

无定河流域不同地貌区水沙过程对比

为了查明人为影响程度较低时期无定河流域内不同地貌区的水沙过程及其变化规律,选取1970年以前一段时期该流域内风沙区和黄土丘陵沟壑区河流的有关水文站的水文泥沙实测数据进行对比分析。结果表明,风沙区河流的流量变率较黄土丘陵沟壑区的小;风沙区河流的含沙量远小于黄土丘陵沟壑区河流的含沙量。黄土丘陵沟壑区河流具有极高的输沙率,而风沙区河流的输沙率微不足道。风沙区和黄土丘陵沟壑区河流的产流模数基本相近,但产沙模数非常悬殊,前者的产沙模数很小,为118.58~725.38t /km² · a,而后者的达到1879.36~25112.15t /km² · a。显然,无定河流域黄土丘陵沟壑区的河流是侵蚀产沙的主要来源区,因而是水土保持工作的重点区域。     

中国制造业的地理集聚与形成机制

基于第一次经济普查资料,深入探讨了中国制造业的地理格局。通过计算不同地理尺度下的制造业产业分布基尼系数和Moran's I 系数,发现中国制造业高度聚集在珠三角、长三 角以及环渤海地区,在华北、东北、四川以及两湖地区有一些连片分布;空间尺度越小,产业划分越细,制造业在空间上越集中,省市县尺度的产业地理集中程度显著相关。基于比较 优势、全球化和制度分权以及集聚经济等相关理论,本文构建了考察影响产业地理集聚因素 的计量模型。统计分析表明,由于接近资源优势,农产品投入较多的产业较分散,金属矿物投入较多的产业较为集中,非金属矿物依赖性产业在四位数层次集中,在三位数层级显著分散。利用外资和参与国际贸易有利于产业地理集聚,区域分权促使制造业分散布局,在省级 层次尤为显著。集聚经济显著推动制造业地理集聚,但在县级层次更为重要。高技能劳动力比重较高和外部科研力量依赖性产业则较为分散,产业联系没能促进中国产业的地理集聚, 可能与地方保护和模仿政策等反市场力量有关。研究表明,空间尺度和经济转轨引致的制度变化对于理解中国制造业地理格局非常重要。     

珠穆朗玛峰地区雪冰中重金属浓度与季节变化

对2005 年9 月采自珠穆朗玛峰北坡海拔6523 m 的东绒布冰川积累区一批雪坑样品中重金属Ba, Co, Cu, Zn 和Pb 的浓度利用电感耦合等离子体质谱仪进行了测试, 重金属浓度范围分别为(pg/ml); Ba2~227、Co2.8~15.7、Cu 10~120、Zn29~4948、Pb14~142。并利用气体稳 定同位素质谱仪MAT-252 对样品稳定氧同位素比率(δ¹⁸O) 进行了测试, 雪坑样品对应的时间为2004 年夏到2005 年秋, δ¹⁸O和重金属元素的浓度都存在着季节变化特征。在夏季风期间δ¹⁸O 值和重金属元素的浓度都很低,而在非夏季风期间δ¹⁸O值和重金属元素浓度升高,反映了不同的水汽来源对重金属浓度季节变化的影响及其环境意义。Co, Cu, Pb, Zn 的地壳富集系数(EF_c) 分别为: 3.6、27、33、180, 表明该地区Pb, Cu, Zn 已经受到了人类活动的污染, 其中Zn 受到的污染最大。     

基于集中度与集中期的径流年内分配研究

借鉴年降水量年内分配的向量法,描述径流年内分配的径流集中度和集中期,尝试提出一种计算河川径流年内分配不均匀性的定量新方法。实例研究表明,用月径流量计算的集中度比径流年内不均匀系数有更高的分辨能力和敏感性,用月径流量计算的集中期对应的月份与月径流最大值出现的实际月份完全一致,径流集中度、集中期能够充分定量地表征径流在年内分配的非均匀性。     

风尘堆积常见的同沉积和沉积后改造特征及其环境意义

黄土堆积作为气下沉积,任何一个深度都曾经暴露于地表,因而必然受到相关地表过程的作用.由于这些过程均发生于特定的环境条件下,形成的特征多数具有明确的环境意义;而黄土在沉积后也可能受到各种地质过程的改造,从而对研究中常用的气候代用指标有一定影响.文章基于野外、微形态等分析,结合前人成果,对我国北方新近纪风尘堆积中常见的同沉积和沉积后改造特征、形成过程及环境意义进行研究.由于一些特征在黄土堆积中具有普遍性,可作为识别风成堆积的标志和环境事件研究的指标,并有助于全面理解常用的替代指标的环境意义.     

河北沧州市臭氧质量浓度与气象因子的关系分析

利用2014—2020年河北沧州逐小时气象与环境监测数据,对沧州市臭氧(O₃)污染加剧现状及其与气象因子的关系进行分析。结果表明：(1)沧州地区O₃污染呈加剧态势,且O₃已上升为该地区首要污染物;O₃污染集中出现在5—9月,O₃质量浓度日变化呈单峰单谷型,最大浓度出现在16:00前后;(2)5—9月O₃日最大8 h平均质量浓度(简称“O₃-8 h”)所处时段,平均气温、最高气温、相对湿度、总辐射辐照度与O₃质量浓度的相关性较好,本站气压、水汽压和平均风速与O₃质量浓度的相关性未通过显著性检验;(3)5—9月O₃-8 h时段,当同时满足8 h平均气温高于30.9℃、最高气温高于32.7℃、平均相对湿度低于42.1%、平均总辐射辐照度高于505.8 W·m^-2时,出现O₃污染的概率达84%;(4)气象因子不是O₃     

Spatial patterns of groundwater‐lake exchange – implications for acid neutralization processes in an acid mine lake

Exchange of groundwater and lake water with typically quite different chemical composition is an important driver for biogeochemical processes at the groundwater‐lake interface, which can affect the water quality of lakes. This is of particular relevance in mine lakes where anoxic and slightly acidic groundwater mixes with oxic and acidic lake water (pH < 3). To identify links between groundwater‐lake exchange rates and acid neutralization processes in the sediments, exchange rates were quantified and related to pore‐water pH, sulfate and iron concentrations as well as sulfate reduction rates within the sediment. Seepage rates measured with seepage meters (?2.5 to 5.8 L m^‐2 d^‐1) were in reasonable agreement with rates inverted from modeled chloride profiles (?1.8 to 8.1 L m^‐2 d^‐1). Large‐scale exchange patterns were defined by the (hydro)geologic setting but superimposed by smaller scale variations caused by variability in sediment texture. Sites characterized by groundwater upwelling (flow into the lake) and sites where flow alternated between upwelling and downwelling were identified. Observed chloride profiles at the alternating sites reflected the transient flow regime. Seepage direction, as well as seepage rate, were found to influence pH, sulfate and iron profiles and the associated sulfate reduction rates. Under alternating conditions proton‐consuming processes, for example, sulfate reduction, were slowed. In the uppermost layer of the sediment (max. 5 cm), sulfate reduction rates were significantly higher at upwelling (>330 nmol g^‐1 d^‐1) compared to alternating sites (<220 nmol g^‐1 d^‐1). Although differences in sulfate reduction rates could not be explained solely by different flux rates, they were clearly related to the prevailing groundwater‐lake exchange patterns and the associated pH conditions. Our findings strongly suggest that groundwater‐lake exchange has significant effects on the biogeochemical processes that are coupled to sulfate reduction such as acidity retention and precipitation of iron sulfides. Copyright © 2012 John Wiley & Sons, Ltd.     

Raindrop‐impact‐induced erosion processes and prediction: a review

Raindrop‐impact‐induced erosion is initiated when detachment of soil particles from the surface of the soil results from an expenditure of raindrop energy. Once detachment by raindrop impact has taken place, particles are transported away from the site of the impact by one or more of the following transport processes: drop splash, raindrop‐induced flow transport, or transport by flow without stimulation by drop impact. These transport processes exhibit varying efficiencies. Particles that fall back to the surface as a result of gravity produce a layer of pre‐detached particles that provides a degree of protection against the detachment of particles from the underlying soil. This, in turn, influences the erodibility of the eroding surface. Good understanding of rainfall erosion processes is necessary if the results of erosion experiments are to be properly interpreted. Current process‐based erosion prediction models do not deal with the issue of temporal variations in erodibility during a rainfall event or variabilities in erodibility associated with spatial changes in dominance of the transport processes that follow detachment by drop impact. Although more complex erosion models may deal with issues like this, their complexity and high data requirement may make them unsuitable for use as general prediction tools. Copyright © 2005 John Wiley & Sons, Ltd.